(Z)-3-hexen-1-yl anthranilate

cis-3-hexenyl anthranilate

CAS: 65405-76-7 C13 H17 N O2 MW: 219.28389000 fruity floral

Identification

Name(Z)-3-hexen-1-yl anthranilate
IUPAC[(Z)-hex-3-enyl] 2-aminobenzoate
CAS Number65405-76-7
EINECS265-744-2
FDA UNIIPQO7MXY1IA
Molecular FormulaC13 H17 N O2
Molecular Weight219.28389000
Nikkaji NumberJ59.826G
Beilstein2807994
CoE Number10676
XlogP34.00 (est)

Regulatory

JECFA Food Flavoring1538 cis-3-hexenyl anthranilate
DG SANTE Food Flavourings09.561 hex-3(cis)-enyl anthranilate
FEMA Number3925
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)65405-76-7 ; (Z)-3-HEXENYL ANTHRANILATE

Physical Properties

Appearance colorless to pale amber clear liquid (est)
Assay 95.00 to 100.00 sum of isomers
Food Chemicals Codex Listed No
Specific Gravity 1.04700 to 1.05400 @ 25.00 °C.
Pounds per Gallon - (est). 8.712 to 8.770
Refractive Index 1.54500 to 1.55400 @ 20.00 °C.
Boiling Point 160.00 °C. @ 5.00 mm Hg
Acid Value 2.00 max. KOH/g
Vapor Pressure 0.000089 mmHg @ 25.00 °C.
Vapor Density >1 ( Air = 1 )
Flash Point 220.00 °F. TCC ( 104.44 °C. )
logP (o/w) 4.370
Soluble in alcohol
Insoluble in water

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength medium
Substantivity 24 hour(s) at 100.00 %
Odor Description
at 100.00 %.
at 1.00 %.
Very fine fruity concord grape character
Odor sample from Bedoukian Research, Inc.
Taste Description
at 10.00 - 100.00 ppm.
floral

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral Toxicityoral-rat LD50 > 5000 mg/kg
Dermal Toxicityskin-rabbit LD50 > 5000 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for (Z)-3-hexen-1-yl anthranilate usage levels up to10.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)0.012 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)53.00 (μg/capita/day)
Threshold of Concern1800 (μg/person/day)
Structure ClassI
baked goods16.00000
beverages(nonalcoholic)-
beverages(alcoholic)4.00000
breakfast cereal-
cheese-
chewing gum0.10000
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy7.00000
fruit ices-
gelatins / puddings4.00000
granulated sugar-
gravies-
hard candy0.20000
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FR apple FR apricot FR berry FR cherry FR grape FR grape concord grape FR green jam FR neroli FR peach FR petitgrain FR pineapple FR plum ripe FR strawberry

Natural Occurrence

not found in nature

Synonyms

anthranilic acid cis-3-hexenyl ester (3Z)- hex-3-en-1-yl 2-aminobenzoate (Z)- hex-3-enyl 2-aminobenzoate (Z)- hex-3-enyl anthranilate cis- hex-3-enyl anthranilate [(Z)- hex-3-enyl] 2-aminobenzoate hex-3(cis)-enyl anthranilate (3Z)-3- hexen-1-ol 2-aminobenzoate (Z)-3- hexen-1-ol 2-aminobenzoate 3- hexen-1-ol, 2-aminobenzoate, (3Z)- 3- hexen-1-ol, 2-aminobenzoate, (Z)- (Z)-3- hexen-1-yl 2-aminobenzoate (Z)-3- hexen-1-yl anthranilate cis-3- hexen-1-yl anthranilate 3- hexen-ol, 2-aminobenzoate, (Z)- (Z)-3- hexenyl 2-aminobenzoate (Z)-3- hexenyl anthranilate C3 hexenyl anthranilate cis-3- hexenyl anthranilate Info: anthranilate derivatives