(E)-3-hexenoic acid

trans-3-hexenoic acid

CAS: 1577-18-0 C6 H10 O2 MW: 114.14410000 cheesy green

Identification

Name(E)-3-hexenoic acid
CAS Number1577-18-0
EINECS216-417-8
FDA UNII9B3N069EDG
Molecular FormulaC6 H10 O2
Molecular Weight114.14410000
MDL NumberMFCD00002786
Nikkaji NumberJ98.004H
Beilstein1700862
CoE Number2256

Regulatory

FEMA Number3170
FDANo longer provide for the use of these seven synthetic flavoring substances

Physical Properties

Appearance colorless to pale yellow clear liquid (est)
Assay 97.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 0.89900 to 0.97000 @ 25.00 °C.
Pounds per Gallon - (est). 7.481 to 8.071
Refractive Index 1.43000 to 1.45000 @ 20.00 °C.
Melting Point 11.00 to 12.00 °C. @ 760.00 mm Hg
Boiling Point 118.00 to 119.00 °C. @ 22.00 mm Hg, 81.00 to 92.00 °C. @ 2.00 mm Hg
Vapor Pressure 0.083000 mmHg @ 25.00 °C. (est)
Vapor Density >1 ( Air = 1 )
Flash Point 230.00 °F. TCC ( 110.00 °C. )
logP (o/w) 1.344 (est)
Soluble in alcohol
Insoluble in water

Organoleptic Properties

Odor Strength high ,
Substantivity 228 hour(s) at 100.00 %
Odor Description
at 1.00 % in dipropylene glycol.
Cheesy, green, dairy-like with a waxy fruity nuance
A diffusive cheese odor; somewhat fruity
Honey hay
Taste Description
at 50.00 ppm.
Strong acidic, cheesy character, with honey backnotes
Acidic honey taste of excellent tenacity

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavoring agents
Recommendation for (E)-3-hexenoic acid usage levels up tonot for fragrance use.
Maximised Survey-derived Daily Intakes (MSDI-EU)9.40 (μg/capita/day)
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FL banana FL berry mixed berry FL cheese FR fruit FL green FR melon FR passion fruit FL raspberry FL tomato FL wine sherry wine

Natural Occurrence

banana fruit beer PMC passion fruit pork cooked pork PMC raspberry red raspberry fruit sherry PMC tea black tea

Synonyms

(3E)- hex-3-enoic acid (E)- hex-3-enoic acid trans- hex-3-enoic acid trans- hex-3-ensaeure (3E)-3- hexenoic acid 3-trans- hexenoic acid T3 hexenoic acid trans-3- hexenoic acid 3- hexenoic acid, (3E)- 3- hexenoic acid, (E)- trans-3- hexenoicacid PubMed: Use of long-chain fatty acid-CoA ligase (AMP-forming) from Pseudomonas fragi for the 'in vitro' synthesis of natural penicillins.