4,5-dimethyl thiazole

4,5-dimethylthiazole

CAS: 3581-91-7 C5 H7 N S MW: 113.18279000 fishy fishy

Identification

Name4,5-dimethyl thiazole
IUPAC4,5-dimethyl-1,3-thiazole
CAS Number3581-91-7
EINECS222-703-3
FDA UNIIU3RP5I088G
Molecular FormulaC5 H7 N S
Molecular Weight113.18279000
MDL NumberMFCD00005336
Nikkaji NumberJ45.577F
Beilstein0105694
CoE Number11606

Regulatory

JECFA Food Flavoring1035 4,5-dimethylthiazole
DG SANTE Food Flavourings15.017 4,5-dimethylthiazole
FEMA Number3274
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)3581-91-7 ; 4,5-DIMETHYLTHIAZOLE

Physical Properties

Appearance colorless to yellow clear liquid (est)
Assay 97.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 1.05500 to 1.08500 @ 25.00 °C., 1.06700 to 1.07200 @ 25.00 °C.
Pounds per Gallon - (est). 8.779 to 9.028
Pounds per Gallon - est. 8.879 to 8.920
Refractive Index 1.51000 to 1.53000 @ 20.00 °C., 1.51600 to 1.52400 @ 20.00 °C.
Melting Point 83.00 to 84.00 °C. @ 760.00 mm Hg
Boiling Point 157.00 to 159.00 °C. @ 760.00 mm Hg, 158.00 °C. @ 742.00 mm Hg
Vapor Pressure 3.456000 mmHg @ 25.00 °C. (est)
Vapor Density 3.8 ( Air = 1 )
Flash Point 125.00 °F. TCC ( 51.67 °C. )
logP (o/w) 1.184 (est)
Soluble in alcohol
Insoluble in water

Organoleptic Properties

Odor Description
at 0.10 % in dipropylene glycol.
Fishy, amine and pyridine-like with shrimp and savory nuances
Nutty, green, roasted, meaty, boiled poultry
Roast, Nutty, Green, Fish
Taste Description
at 5.00 ppm.
nutty

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral Toxicitygavage-rat LD50 [sex: M,F] 964.90 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavoring agents
Recommendation for 4,5-dimethyl thiazole usage levels up tonot for fragrance use.
Maximised Survey-derived Daily Intakes (MSDI-EU)0.18 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)0.40 (μg/capita/day)
Structure ClassII
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FL bakery FL chocolate cocoa FL coffee condiment confection FL crab FL green FL peanut FL scallop FL prawn FL soup

Natural Occurrence

coffee PMC krill PMC peach fruit peanut roasted peanut pork PMC scallop PMC shrimp PMC

Synonyms

4,5- dimethyl thiazole, kosher 4,5- dimethyl-1,3-thiazole dimethyl-4,5 thiazole 4,5- dimethylthiazole 4,5- dimethythiazole shrimp thiazole thiazole, 4,5-dimethyl- Try the PubMed Search.