(Z)-3-hexen-1-yl phenyl acetate

3-hexenyl phenylacetate

CAS: 42436-07-7 C14 H18 O2 MW: 218.29586000 green green

Identification

Name(Z)-3-hexen-1-yl phenyl acetate
IUPAC[(Z)-hex-3-enyl] 2-phenylacetate
CAS Number42436-07-7
EINECS255-826-6
FDA UNII8XZ0MZ4575
Molecular FormulaC14 H18 O2
Molecular Weight218.29586000
MDL NumberMFCD00036531
Nikkaji NumberJ73.248F
Beilstein3266406
CoE Number10682
XlogP33.70 (est)

Regulatory

JECFA Food Flavoring1016 3-hexenyl phenylacetate
DG SANTE Food Flavourings09.805 3-hexenyl phenylacetate
FEMA Number3633
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)42436-07-7 ; 3-HEXENYL PHENYLACETATE
FDA RegulationFDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION

Physical Properties

Appearance colorless clear viscous liquid (est)
Assay 95.00 to 100.00 sum of isomers
Food Chemicals Codex Listed No
Specific Gravity 0.99600 to 1.00400 @ 25.00 °C.
Pounds per Gallon - (est). 8.288 to 8.354
Refractive Index 1.49700 to 1.50400 @ 20.00 °C.
Boiling Point 297.00 to 299.00 °C. @ 760.00 mm Hg, 133.00 to 134.00 °C. @ 4.00 mm Hg
Vapor Pressure 0.001000 mmHg @ 25.00 °C. (est)
Vapor Density >1 ( Air = 1 )
Flash Point 220.00 °F. TCC ( 104.44 °C. )
logP (o/w) 4.035 (est)
Soluble in alcohol
Insoluble in water
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Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength medium
Substantivity 171 hour(s) at 100.00 %
Odor Description
at 100.00 %.
Green, floral, vegetable, tropical and melon-like nuances
Floral, honey, green
Sweet green-rosy odor, woody undertone
Sweet green-rosy odor with a woody undertone
Odor sample from Bedoukian Research, Inc.
Taste Description
at 15.00 ppm.
waxy green

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral Toxicityoral-rat LD50 > 5000 mg/kg
Dermal Toxicityskin-rabbit LD50 > 5000 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for (Z)-3-hexen-1-yl phenyl acetate usage levels up to12.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)0.73 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)0.05 (μg/capita/day)
Structure ClassI
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FR apple FL cabbage FR cucumber FR floral FR green FR honey FR honeysuckle FR melon FR mint FL onion FR pear FR rose FL vegetable

Natural Occurrence

cornmint oil linden flower peppermint oil spearmint oil scotch tea

Synonyms

benzene acetic acid (3Z)-3-hexen-1-yl ester (Z)- benzene acetic acid 3-hexen-1-yl ester benzeneacetic acid, (3Z)-3-hexen-1-yl ester benzeneacetic acid, (3Z)-3-hexenyl ester benzeneacetic acid, 3-hexenyl ester, (Z)- (3Z)- hex-3-en-1-yl phenylacetate (Z)- hex-3-enyl phenyl acetate cis- hex-3-enyl phenyl acetate (Z)- hex-3-enyl phenylacetate [(Z)- hex-3-enyl] 2-phenylacetate 3- hexen-1-yl alpha-toluate beta,gamma- hexen-1-yl alpha-toluate (Z)-3- hexen-1-yl benzene acetate (Z)-3- hexen-1-yl phenyl acetate 3- hexen-1-yl phenyl acetate cis-3- hexen-1-yl phenyl acetate cis-3- hexen-1-yl phenylacetate 3- hexenyl benzeneacetate, (Z)- 3- hexenyl benzeneacetate, cis- (Z)-3- hexenyl phenyl acetate C3 hexenyl phenyl acetate cis-3- hexenyl phenyl acetate (Z)-3- hexenyl phenylacetate cis-3- hexenyl phenylacetate phenylacetic acid cis-3-hexen-1-yl ester Try the PubMed Search.