longiborneol

1,4-methanoazulen-9-ol, decahydro-1,5,5,8a-tetramethyl-, (9R)-

CAS: 465-24-7 C15 H26 O MW: 222.37142000 mossy

Identification

Name	longiborneol
CAS Number	465-24-7
FDA UNII	Search
Molecular Formula	C15 H26 O
Molecular Weight	222.37142000

Regulatory

Physical Properties

Appearance	white to pale yellow crystals (est)
Assay	95.00 to 100.00
Food Chemicals Codex Listed	No
Melting Point	106.00 to 107.00 °C. @ 760.00 mm Hg
Boiling Point	130.00 to 150.00 °C. @ 760.00 mm Hg
Vapor Pressure	0.000278 mmHg @ 25.00 °C. (est)
Flash Point	248.00 °F. TCC ( 120.00 °C. )
logP (o/w)	4.732 (est)
Soluble in	alcohol
Insoluble in	water

Organoleptic Properties

Odor Description

at 100.00 %.

Safety Information

Oral/Parenteral Toxicity	Not determined
Dermal Toxicity	Not determined
Inhalation Toxicity	Not determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Category	natural substances and extractives
Recommendation for longiborneol usage levels up to	not for fragrance use.
Recommendation for longiborneol flavor usage levels up to	not for flavor use.

No supplier data available

Potential Uses

FR moss FR woody

Natural Occurrence

cedarwood oil lebanon @ 0.80% Data cedrus deodara oil cupressus macrocarpa juniper tree bark

Synonyms

(1R,3aR,4S,8aS,9S)- decahydro-1,5,5,8a-tetramethyl-1,4-methanoazulen-9-ol (1R- (1alpha,3abeta, 4alpha,8abeta,9S*))- decahydro-1,5,5,8a-tetramethyl-1,4-methanoazulen-9-ol juniperol macrocarpol 1,4- methanoazulen-9-ol, decahydro-1,5,5,8a-tetramethyl-, (9R)- PubMed: Chemical composition and antibacterial activity of the essential oil of Drimys granadensis L.f. leaves from Colombia. PubMed: CLM1 of Fusarium graminearum encodes a longiborneol synthase required for culmorin production. PubMed: Syntheses of biologically active natural products and leading compounds for new pharmaceuticals employing effective construction of a polycyclic skeleton. PubMed: [Development of boomerang-type intramolecular cascade reactions and application to natural product synthesis]. PubMed: Total synthesis of (+/-)-culmorin and (+/-)-longiborneol: an efficient construction of Tricyclo[6.3.0.0(3,9)]undecan-10-one by intramolecular double Michael addition. PubMed: Stereoselective Construction of Copaborneol and Longiborneol Frameworks by Intramolecular Double Michael Reaction. PubMed: (+)-Juniperol and (+)-pimaral: Attractants for the cerambycid beetle,Monochamus alternatus Hope.