Identification

Namepiperitenone
IUPAC2-methyl-6-propan-2-ylidenecyclohex-2-en-1-one
CAS Number491-09-8
EINECS207-729-5
FDA UNIIIKR841W74D
Molecular FormulaC10 H14 O
Molecular Weight150.22078000
Nikkaji NumberJ2.113.085K
CoE Number11189

Regulatory

JECFA Food Flavoring757 p-menth-1,4(8)-dien-3-one
DG SANTE Food Flavourings07.127 p-menth-1,4(8)-dien-3-one
FEMA Number3560
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)491-09-8 ; PIPERITENONE
FDA RegulationFDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION

Physical Properties

Appearance yellow to amber clear liquid (est)
Assay 95.00 to 100.00 sum of isomers
Food Chemicals Codex Listed No
Specific Gravity 0.97600 to 0.98300 @ 25.00 °C.
Pounds per Gallon - (est). 8.121 to 8.180
Refractive Index 1.47200 to 1.47800 @ 20.00 °C.
Boiling Point 106.00 to 107.00 °C. @ 10.00 mm Hg, 92.00 °C. @ 1.80 mm Hg
Vapor Pressure 0.040000 mmHg @ 25.00 °C. (est)
Flash Point 200.00 °F. TCC ( 93.33 °C. )
logP (o/w) 1.766 (est)
Soluble in alcohol
Insoluble in water

Organoleptic Properties

Odor Description at 10.00 % in dipropylene glycol.

Safety Information

Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for piperitenone usage levels up to0.5000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)0.012 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)0.01 (μg/capita/day)
Structure ClassII
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FR herbal FR mint FL/FR pennyroyal

Natural Occurrence

calamintha nepeta (l.) savi subsp. glandulosa oil greece @ 7.00% Data cornmint leaf cornmint plant foeniculum vulgare piperitum oil @ 0.80% Data grapefruit juice horsemint shoot lemon fruit juice lemon verbena oil turkey @ 0.07% Data lippia alnifolia schau. leaf oil brazil @ 1.70% Data mastic fruit oil @ 2.30% Data mentha longifolia (l.) huds. oil jordan @ 0.20% Data mint orange fruit juice pennyroyal pennyroyal oil @ 1.80% Data pennyroyal oil cuba @ 2.39% Data peppermint oil plectranthus glandulosus hook f. leaf oil cameroon @ 1.30% Data rosemary leaf rosemary oil egypt @ 0.27% Data satureja viminea l. oil costa rica @ 0.70% Data spearmint oil water mint leaf

Synonyms

p- menth-1,4(8)-dien-3-one para- menth-1,4(8)-dien-3-one p- mentha-1,4(8)-dien-3-one para- mentha-1,4(8)-dien-3-one 1,4(8)-p- menthadien-3-one 1,4(8)-para- menthadien-3-one 1- methyl-4-isopropylidene-1-cyclohexen-3-one 3- methyl-6-(1-methyl ethylidene) cyclohex-2-en-1-one 3- methyl-6-(1-methylethylidene)cyclohex-2-en-1-one 2- methyl-6-propan-2-ylidenecyclohex-2-en-1-one pulespenone PubMed: Curcuma ecalcarata - new natural source of pinocembrin and piperitenone. PubMed: Comparative analysis of antioxidant activities of fourteen mentha essential oils and their components. PubMed: Pharmacological and therapeutic effects of Mentha Longifolia L. and its main constituent, menthol. PubMed: A new source of (R)-limonene and rotundifolone from leaves of Lippia pedunculosa (verbenaceae) and their trypanocidal properties. PubMed: Chemical composition and antimicrobial activity of the essential oil of Plectranthus mollis (Lamiaceae) from Western Ghats Region, Karnataka, India. PubMed: Isolation and characterization of isopiperitenol dehydrogenase from piperitenone-type Perilla. PubMed: Repellent Activities of Essential Oils of Some Plants Used Traditionally to Control the Brown Ear Tick, Rhipicephalus appendiculatus. PubMed: Discrimination of fennel chemotypes applying IR and Raman spectroscopy: discovery of a new γ-asarone chemotype. PubMed: In vitro inhibition of herpes simplex virus type 1 replication by Mentha suaveolens essential oil and its main component piperitenone oxide. PubMed: Antioxidant Activity and Volatile and Phenolic Profiles of Essential Oil and Different Extracts of Wild Mint (Mentha longifolia) from the Pakistani Flora. PubMed: Antifungal impact of volatile fractions of Peumus boldus and Lippia turbinata on Aspergillus section Flavi and residual levels of these oils in irradiated peanut. PubMed: Essential oils of Micromeria dalmatica Benth., a Balkan endemic species of section Pseudomelissa. PubMed: Volatile constituents, phenolic compounds, and antioxidant activity of Calamintha glandulosa (Req.) Bentham. PubMed: Comparative study of the chemical composition of essential oils of five Tagetes species collected in Venezuela. PubMed: Biological activities of Eremostachys laevigata Bunge. grown in Iran. PubMed: In vitro production of M. × piperita not containing pulegone and menthofuran. PubMed: Essential-oil diversity of three Calamintha species from Greece. PubMed: Volatile secondary metabolites of Micromeria dalmatica Benth. (Lamiaceae): biosynthetical and chemotaxonomical aspects. PubMed: Intraspecific variability of the essential oil of Calamintha nepeta subsp. nepeta from Southern Italy (Apulia). PubMed: Mode of action of pulegone on the urinary bladder of F344 rats. PubMed: Chemical and morphological diversity in wild populations of Mentha longifolia in Israel. PubMed: Composition of the essential oil of Origanum tyttanthum from Tajikistan. PubMed: Mentha longifolia in vitro cultures as safe source of flavouring ingredients. PubMed: HS-SPME-GC×GC-qMS volatile metabolite profiling of Chrysolina herbacea frass and Mentha spp. leaves. PubMed: Larvicidal activity of Tagetes erecta against Aedes aegypti. PubMed: Comparative study of volatile oil compositions of two Plectranthus species from northern India. PubMed: Chemical diversity of Ziziphora clinopodioides: composition of the essential oil of Z. clinopodioides from Tajikistan. PubMed: Chemical composition and biological assays of essential oils of Calamintha nepeta (L.) Savi subsp. nepeta (Lamiaceae). PubMed: Antimicrobial activity and volatile constituents of the essential oil of Pulsatilla albana from Iran. PubMed: Intraspecific variability of the essential oil of Ziziphora clinopodioides ssp. rigida from Iran. PubMed: Seasonal variation in content, chemical composition and antimicrobial and cytotoxic activities of essential oils from four Mentha species. PubMed: Chemical composition and larvicidal evaluation of Mentha, Salvia, and Melissa essential oils against the West Nile virus mosquito Culex pipiens. PubMed: Composition and chemical variability of Mentha suaveolens ssp. suaveolens and M. suaveolens ssp. insularis from Corsica. PubMed: Chemical composition and antimicrobial and antioxidant activities of Mentha (longifolia L. and viridis) essential oils. PubMed: Crude extracts of, and purified compounds from, Pterocarpus angolensis, and the essential oil of Lippia javanica: their in-vitro cytotoxicities and activities against selected bacteria and Entamoeba histolytica. PubMed: Antinociceptive effects of the essential oil of Mentha x villosa leaf and its major constituent piperitenone oxide in mice. PubMed: Influence of growth phase on the essential oil composition of Ziziphora clinopodioides Lam. PubMed: Supercritical carbon dioxide extraction of Mentha pulegium L. essential oil. PubMed: Bioactive compounds from Lippia javanica and Hoslundia opposita. PubMed: Antimicrobial activity and chemical composition of Mentha pulegium L. essential oil. PubMed: Perilla frutescens var. frutescens in northern Laos. PubMed: Highly Enantio- and s-trans C=C bond selective catalytic hydrogenation of cyclic enones: alternative synthesis of (-)-menthol. PubMed: Comparative analysis of the oil and supercritical CO2 extract of Ridolfia segetum (L.) Moris. PubMed: Antibacterial activity and composition of the essential oil of Ziziphora clinopodioides subsp. bungeana (Juz.) Rech. f. from Iran. PubMed: The chemical composition of essential oil and in vitro antibacterial activities of essential oil and methanol extract of Ziziphora persica Bunge. PubMed: Essential oil composition, antibacterial and antioxidant activity of the oil and various extracts of Ziziphora clinopodioides subsp. rigida (BOISS.) RECH. f. from Iran. PubMed: Transformation of a monoterpene ketone, piperitenone, and related terpenoids using Mucor piriformis. PubMed: Chemical characterization and antifungal activity of essential oil of capitula from wild Indian Tagetes patula L. PubMed: The composition, geographical variation and antimicrobial activity of Lippia javanica (Verbenaceae) leaf essential oils. PubMed: Piperitenone oxide as toxic, repellent, and reproduction retardant toward malarial vector Anopheles stephensi (Diptera: Anophelinae). PubMed: Comparison of different extraction methods for the analysis of volatile secondary metabolites of Lippia alba (Mill.) N.E. Brown, grown in Colombia, and evaluation of its in vitro antioxidant activity. PubMed: Composition of the essential oil of Mentha microphylla from the Gennargentu Mountains (Sardinia, Italy). PubMed: Essential oil composition and antioxidant activity of endemic Ziziphora taurica subsp. cleonioides. PubMed: Antibacterial and antifungal activity of essential oils of Mentha suaveolens. PubMed: Activity of essential oils of three Micromeria species (Lamiaceae) against micromycetes and bacteria. PubMed: Menthone and isomenthone biosynthesis in Pelargonium tomentosum Jacq. PubMed: Cardiovascular effects of the essential oil of Mentha x villosa and its main constituent, piperitenone oxide, in normotensive anaesthetised rats: role of the autonomic nervous system. PubMed: Phytochemical study of Mentha longifolia of Morocco. PubMed: Suppression of the furylfuramide-induced SOS response by monoterpenoids with a p-menthane skeleton using the Salmonella typhimurium TA1535/pSK1002 Umu test. PubMed: Transformation of a monoterpene ketone, (R)-(+)-pulegone, a potent hepatotoxin, in Mucor piriformis. PubMed: The essential oil of Senecio graveolens (Compositae): chemical composition and antimicrobial activity tests. PubMed: Metabolic disposition of a monoterpene ketone, piperitenone, in rats: evidence for the formation of a known toxin, p-cresol. PubMed: Metabolic fate of S-(-)-pulegone in rat. PubMed: Effects of piperitenone oxide on the intestinal smooth muscle of the guinea pig. PubMed: Studies on the metabolism of a monoterpene ketone, R-(+)-pulegone--a hepatotoxin in rat: isolation and characterization of new metabolites. PubMed: Devil's-claw (Proboscidea louisianica), essential oil and its components : Potential allelochemical agents on cotton and wheat. PubMed: Metabolism of monoterpenes: demonstration that (+)-cis-isopulegone, not piperitenone, is the key intermediate in the conversion of (-)-isopiperitenone to (+)-pulegone in peppermint (Mentha piperita). PubMed: Metabolism of monoterpenes: oxidation of isopiperitenol to isopiperitenone, and subsequent isomerization to piperitenone by soluble enzyme preparations from peppermint (Mentha piperita) leaves. PubMed: [Immediate toxicity of carvomenthone, carvone, piperitone and piperitenone].