methyl ((4-aminophenyl)sulfonyl)carbamate

CAS: 3337-71-1 C8 H10 N2 O4 S MW: 230.24350000

Identification

Nameasulam
CAS Number3337-71-1
EINECS222-077-1
FDA UNII0Y5ASM7P5S
Molecular FormulaC8 H10 N2 O4 S
Molecular Weight230.24350000
MDL NumberMFCD00055534
Nikkaji NumberJ3.401K
Beilstein2697523
XlogP3-0.30 (est)

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Melting Point 144.00 °C. @ 760.00 mm Hg
Flash Point 32.00 °F. TCC ( 0.00 °C. ) (est)
logP (o/w) -0.270
Soluble in water, 5000 mg/L @ 22 °C (exp)

No sensory data available

Safety Information

Oral/Parenteral Toxicityoral-chicken LD50 > 2000 mg/kg
Dermal Toxicityskin-rat LD50 > 10000 mg/kg
Inhalation Toxicityinhalation-rat LC50 > 18900 mg/m3

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryherbicides / pesticides
Recommendation for asulam usage levels up tonot for fragrance use.
Recommendation for asulam flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

asulox 40 asulox F carbamic acid, ((4-aminophenyl)sulfonyl)-, methyl ester (9CI) carbamic acid, [(4-aminophenyl)sulfonyl]-, methyl ester carbamic acid, N-[(4-aminophenyl)sulfonyl]-, methyl ester carbamic acid, sulfanilyl-, methyl ester (7CI)(8CI) methyl ((4-aminophenyl)sulfonyl)carbamate methyl [(4-aminophenyl)sulfonyl]carbamate methyl 4-aminobenzenesulfonyl carbamate methyl 4-aminobenzenesulphonyl carbamate methyl 4-aminobenzenesulphonylcarbamate methyl 4-aminophenylsulphonyl carbamate methyl 4-aminophenylsulphonylcarbamate methyl N-(4-aminobenzenesulfonyl)carbamate methyl N-(4-aminophenyl)sulfonylcarbamate methyl N-(4-aminophenylsulfonyl)carbamate methyl sulfanilyl carbamate methyl sulfanilylcarbamate methyl sulphanilylcarbamate PubMed: Ipso-hydroxylation and subsequent fragmentation: a novel microbial strategy to eliminate sulfonamide antibiotics. PubMed: Combined theoretical and experimental study of the photophysics of asulam. PubMed: Reversed phase liquid chromatography trace analysis of pesticides in soil by on-column sample pumping large volume injection and UV detection. PubMed: Automated determination of asulam by enhanced chemiluminescence using luminol/peroxidase system. PubMed: In-capillary microextraction using monolithic polymers: application to preconcentration of carbamate pesticides prior to their separation by MEKC. PubMed: Crops with target-site herbicide resistance for Orobanche and Striga control. PubMed: Electrocatalytic behaviour of carbon paste electrode modified with iron(II) phthalocyanine (FePc) nanoparticles towards the detection of amitrole. PubMed: Herbicide Effects on Sugarcane Growth, Pythium Root Rot, and Pythium arrhenomanes. PubMed: Determination of asulam by fast stopped-flow chemiluminescence inhibition of luminol/peroxidase. PubMed: Comparative study of multi walled carbon nanotubes-based electrodes in micellar media and their application to micellar electrokinetic capillary chromatography. PubMed: The effectiveness of asulam for bracken (Pteridium aquilinum) control in the United Kingdom: a meta-analysis. PubMed: The effectiveness of management interventions used to control ragwort species. PubMed: Fluorescence determination of the pesticide asulam by flow injection analysis. PubMed: Validation of a fast and easy method for the determination of residues from 229 pesticides in fruits and vegetables using gas and liquid chromatography and mass spectrometric detection. PubMed: Aquatic risk assessment of a realistic exposure to pesticides used in bulb crops: a microcosm study. PubMed: Contamination of honey by the herbicide asulam and its antibacterial active metabolite sulfanilamide. PubMed: Dose-response relationships between herbicides with different modes of action and growth of Lemna paucicostata: an improved ecotoxicological method. PubMed: The effects of a pesticide mixture on aquatic ecosystems differing in trophic status: responses of the macrophyte Myriophyllum spicatum and the periphytic algal community. PubMed: Effect of natural organic matter on powdered activated carbon adsorption of trace contaminants: characteristics and mechanism of competitive adsorption. PubMed: Exposure to Asulox inhibits the growth of mosses. PubMed: Soil photolysis of herbicides in a moisture- and temperature-controlled environment. PubMed: Capillary zone electrophoresis in wide bore capillary tubes with fiber-coupled diode array detection. PubMed: Identification of a novel mannose-capped lipoarabinomannan from Amycolatopsis sulphurea. PubMed: The first monoclonal antibody-based, matrix-resistant immunoassay for the carbamate herbicide asulam, in water. PubMed: Iron (III) aquacomplexes as effective photocatalysts for the degradation of pesticides in homogeneous aqueous solutions. PubMed: Pesticide adsorption by granular activated carbon adsorbers. 2. Effects of pesticide and natural organic matter characteristics on pesticide breakthrough curves. PubMed: Pesticide adsorption by granular activated carbon adsorbers. 1. Effect of natural organic matter preloading on removal rates and model simplification. PubMed: In vitro pesticide degradation in turfgrass soil incubated under open and sealed conditions. PubMed: Determination of carbamate herbicide asulam in peaches following fluorescamine fluorigenic labelling. PubMed: [The toxicity of herbicide Asulam]. PubMed: Assessment of the effects of herbicide spray drift on a range of plant species of conservation interest. PubMed: Metabolism of the carbamate herbicide, asulam, in the rat. PubMed: An h.p.l.c. method for the quantitative determination of asulam, acetylasulam and sulphanilamide in peaches. PubMed: Identification and determination of asulam and related degradation products in soil. PubMed: Direct analysis of the wild oat herbicide, asulam, in wheat samples by reversed-phase liquid chromatography at selected ultraviolet wavelengths. PubMed: Effects of asulam on some microbial activities of three soils. PubMed: Sensitive gas-liquid chromatographic method for asulam residues in peaches. PubMed: The microbial degradation of a sulphanilamide-based herbicide (Asulam) [proceedings]. PubMed: A soil Flavobacterium sp. that degrades sulphanilamide and asulam. PubMed: [Determination of asulam in air by the thin-layer chromatography method]. PubMed: Some patterns of herbicide and growth regulator intake, persistence, and distribution in sugarcane. PubMed: Effect of asulam in wildlife specie residues and toxicity in bobwhite quail after prolonged exposure. PubMed: Effect of asulam in wildlife species acute toxicity to birds and fish.