fenpyroximate

tert-butyl (E)-a-(1,3-dimethyl-5-phenoxypyrazol-4-ylmethyleneaminooxy)-p-toluate

CAS: 134098-61-6 C24 H27 N3 O4 MW: 421.49699000

Identification

Namefenpyroximate
CAS Number134098-61-6
FDA UNII9W557V4RYA
Molecular FormulaC24 H27 N3 O4
Molecular Weight421.49699000
MDL NumberMFCD00274596
Nikkaji NumberJ1.160.369F
Beilstein8352707

Regulatory

Physical Properties

Appearance white crystalline powder (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Boiling Point 546.22 °C. @ 760.00 mm Hg (est)
Flash Point 543.00 °F. TCC ( 284.10 °C. ) (est)
logP (o/w) 6.443 (est)
Soluble in water, 0.1185 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Oral/Parenteral Toxicityoral-mouse LD50 440 mg/kg
Dermal Toxicityskin-rat LD50 > 2000 mg/kg
Inhalation Toxicityinhalation-rat LC50 330 mg/m3/4H

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryherbicides / pesticides
Recommendation for fenpyroximate usage levels up tonot for fragrance use.
Recommendation for fenpyroximate flavor usage levels up tonot for flavor use.

No supplier data available

Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

benzoic acid, 4-((((E)-((1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene)amino)oxy)methyl)-, 1,1-dimethylethyl ester benzoic acid, 4-[[[[(1E)-(1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino]oxy]methyl]-, 1,1-dimethylethyl ester tert- butyl (E)-a-(1,3-dimethyl-5-phenoxypyrazol-4-ylmethyleneaminooxy)-p-toluate t- butyl (E)-alpha-(1,3-dimethyl-5-phenoxypyrazol-4-ylmethyleneaminooxy)-p-toluate tert- butyl 4-[({[(1E)-(1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino}oxy)methyl]benzoate tert- butyl 4-[({[(1E)-(1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylidene]amino}oxy)methyl]benzoate tert- butyl 4-[({[(E)-(1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino}oxy)methyl]benzoate tert- butyl 4-[({[(E)-(1,3-dimethyl-5-phenoxy-1Hh-pyrazol-4-yl)methylidene]amino}oxy)methyl]benzoate tert- butyl 4-[[(E)-(1,3-dimethyl-5-phenoxy-pyrazol-4-yl)methylideneamino]oxymethyl]benzoate tert- butyl4-[[(E)-(1,3-dimethyl-5-phenoxypyrazol-4-yl)methylideneamino]oxymethyl]benzoate danitron (E)-4-[[[[(1,3- dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino]oxy]methyl]benzoic acid 1,1-dimethylethyl ester 4-[[(E)-(1,3- dimethyl-5-phenoxy-4-pyrazolyl)methylideneamino]oxymethyl]benzoic acid tert-butyl ester 1,1- dimethylethyl 4-[[[[(1E)-(1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino]oxy]methyl]benzoate fujimite 2- methyl-2-propanyl 4-[({[(E)-(1,3-dimethyl-5-phenoxy-1H-pyrazol-4-yl)methylene]amino}oxy)methyl]benzoate PubMed: Development of a methodology and evaluation of pesticides against Aceria litchii and its predator Phytoseius intermedius (Acari: Eriophyidae, Phytoseiidae). PubMed: Ionic liquid-based totally organic solvent-free emulsification microextraction coupled with high performance liquid chromatography for the determination of three acaricides in fruit juice. PubMed: [Determination of ten pesticides of pyrazoles and pyrroles in tea by accelerated solvent extraction coupled with gas chromatography-tandem mass spectrometry]. PubMed: Acaricide, fungicide and drug interactions in honey bees (Apis mellifera). PubMed: Comparative toxicity of acaricides to honey bee (Hymenoptera: Apidae) workers and queens. PubMed: Toxicity of acaricides to Raoiella indica and their selectivity for its predator, Amblyseius largoensis (Acari: Tenuipalpidae: Phytoseiidae). PubMed: Survival and behavioural response to acaricides of the coconut mite predator Neoseiulus baraki. PubMed: A case of near-fatal fenpyroximate intoxication: the role of percutaneous cardiopulmonary support and therapeutic hypothermia. PubMed: Residual bioassay to assess the toxicity of Acaricides against Aceria guerreronis (Acari: Eriophyidae) under laboratory conditions. PubMed: Evidence of the in vitro genotoxicity of methyl-pyrazole pesticides in human cells. PubMed: Risk assessment of selected insecticides on Tamarixia triozae (Hymenoptera: Eulophidae), a parasitoid of Bactericera cockerelli (Hemiptera: Trizoidae). PubMed: Acute toxic effects of fenpyroximate acaricide on Guppy (Poecilia reticulata Peters, 1859). PubMed: Toxicity assessment of 45 pesticides to the epigeic earthworm Eisenia fetida. PubMed: Resistance to acaricides in Italian strains of Tetranychus urticae: toxicological and enzymatic assays. PubMed: Fenpyroximate binds to the interface between PSST and 49 kDa subunits in mitochondrial NADH-ubiquinone oxidoreductase. PubMed: Acute and population level toxicity of imidacloprid and fenpyroximate on an important egg parasitoid, Trichogramma cacoeciae (Hymenoptera: Trichogrammatidae). PubMed: Pyrethroid resistance in the tomato red spider mite, Tetranychus evansi, is associated with mutation of the para-type sodium channel. PubMed: Sublethal effects of fenpyroximate and pyridaben on two predatory mite species, Neoseiulus womersleyi and Phytoseiulus persimilis (Acari, Phytoseiidae). PubMed: DJ-1 deficiency in astrocytes selectively enhances mitochondrial Complex I inhibitor-induced neurotoxicity. PubMed: Residue analysis of multi-class pesticides in watermelon by LC-MS/MS. PubMed: A review: oxidative stress in fish induced by pesticides. PubMed: In vitro and in vivo acute toxicity of fenpyroximate to flounder Paralichthys olivaceus and its gill cell line FG. PubMed: Characterization of the inhibitor binding site in mitochondrial NADH-ubiquinone oxidoreductase by photoaffinity labeling using a quinazoline-type inhibitor. PubMed: Resistance mechanisms to mitochondrial electron transport inhibitors in a field-collected strain of Tetranychus urticae Koch (Acari: Tetranychidae). PubMed: Mechanism of toxicity of pesticides acting at complex I: relevance to environmental etiologies of Parkinson's disease. PubMed: tert-Butyl 4-({[(E)-1,3-dimethyl-5-phen-oxy-pyrazol-4-yl]meth-yl}amino-oxymeth-yl)benzoate. PubMed: Complete maternal inheritance of bifenazate resistance in Tetranychus urticae Koch (Acari: Tetranychidae) and its implications in mode of action considerations. PubMed: Multiple resistance and biochemical mechanisms of pyridaben resistance in Tetranychus urticae (Acari: Tetranychidae). PubMed: Side effects of five new acaricides on the predator Galendromus occidentalis (Acari, Phytoseiidae). PubMed: Evaluation of resistance pattern to fenpyroximate and pyridaben in Tetranychus urticae collected from greenhouses and apple orchards using lethal concentration-slope relationship. PubMed: Similar patterns of mitochondrial vulnerability and rescue induced by genetic modification of alpha-synuclein, parkin, and DJ-1 in Caenorhabditis elegans. PubMed: Significance of habitat type for the genetic population structure of Panonychus citri (Acari: Tetranychidae). PubMed: Fenpyroximate resistance in Tetranychus urticae (Acari: Tetranychidae): cross-resistance and biochemical resistance mechanisms. PubMed: Application of liquid chromatography with electrospray tandem mass spectrometry to the determination of a new generation of pesticides in processed fruits and vegetables. PubMed: Potentiation of a propargite and fenpyroximate mixture against two-spotted spider mite, Tetranychus urticae (Acari: Tetranychidae). PubMed: Amiloride inhibition of the proton-translocating NADH-quinone oxidoreductase of mammals and bacteria. PubMed: The ND5 subunit was labeled by a photoaffinity analogue of fenpyroximate in bovine mitochondrial complex I. PubMed: Cross-resistance, inheritance, and biochemistry of mitochondrial electron transport inhibitor-acaricide resistance in Tetranychus urticae (Acari: Tetranychidae). PubMed: Acaricide toxicity and resistance in larvae of different strains of Tetranychus urticae and Panonychus ulmi (Acari: Tetranychidae). PubMed: Incidence and inheritance of resistance to METI-acaricides in European strains of the two-spotted spider mite (Tetranychus urticae) (Acari: Tetranychidae). PubMed: Determination of fenpyroximate in apples by supercritical fluid extraction and packed capillary liquid chromatography with UV detection. PubMed: A laboratory-based method to measure relative pesticide and spray oil efficacy against broad mite, Polyphagotarsonemus latus (Banks)(Acari: Tarsonemidae). PubMed: Two binding sites of inhibitors in NADH: ubiquinone oxidoreductase (complex I). Relationship of one site with the ubiquinone-binding site of bacterial glucose:ubiquinone oxidoreductase.