thiacloprid

cyanamide, N-[(2Z)-3-[(6-chloro-3-pyridinyl)methyl]-2-thiazolidinylidene]-

CAS: 111988-49-9 C10 H9 Cl N4 S MW: 252.72673000

Identification

Namethiacloprid
CAS Number111988-49-9
FDA UNIIDSV3A944A4
Molecular FormulaC10 H9 Cl N4 S
Molecular Weight252.72673000
MDL NumberMFCD02101042
Nikkaji NumberJ1.459.101J
Beilstein8983861

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Melting Point 136.00 °C. @ 760.00 mm Hg (est)
Boiling Point 423.10 °C. @ 760.00 mm Hg (est)
Vapor Pressure 6.000000 mmHg @ 20.00 °C. (est)
Flash Point 409.00 °F. TCC ( 209.70 °C. ) (est)
logP (o/w) 0.550 (est)
Soluble in water, 231.9 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Oral/Parenteral Toxicityoral-rat LD50 444 mg/kg
Dermal ToxicityNot determined
Inhalation Toxicityinhalation-rat LC50 1223 mg/m3/4H

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryherbicides / pesticides
Recommendation for thiacloprid usage levels up tonot for fragrance use.
Recommendation for thiacloprid flavor usage levels up tonot for flavor use.

BOC Sciences

Best of Chemicals Supplier

Quality supplier of research chemicals and biochemicals including inhibitors, building blocks, GMP Products, impurities and metabolites, APIs for Veterinary, Natural Compounds, ADCs, Stem Cell Molecul...

View All Website 1-631-485-4226 account@bocsci.com

Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

{(2Z)-3-[(6- chlor-3-pyridinyl)methyl]-1,3-thiazolidin-2-yliden}cyanamid [3-[(6- chloranylpyridin-3-yl)methyl]-1,3-thiazolidin-2-ylidene]cyanamide (3-((6- chloro-3-pyridinyl)methyl)-2-thiazolidinylidene)cyanamide {(2Z)-3-[(6- chloro-3-pyridinyl)methyl]-1,3-thiazolidin-2-ylidene}cyanamide (Z)-[3-[(6- chloro-3-pyridinyl)methyl]-2-thiazolidinylidene]cyanamide [3-[(6- chloro-3-pyridinyl)methyl]-2-thiazolidinylidene]cyanamide [3-[(6- chloropyridin-3-yl)methyl]-1,3-thiazolidin-2-ylidene]cyanamide {(2Z)-3-[(6- chloropyridin-3-yl)methyl]-1,3-thiazolidin-2-ylidene}cyanamide {(2Z)-3-[(6- chlorpyridin-3-yl)methyl]-1,3-thiazolidin-2-yliden}cyanamid cyanamide, (3-((6-chloro-3-pyridinyl)methyl)-2-thiazolidinylidene)- cyanamide, N-[(2Z)-3-[(6-chloro-3-pyridinyl)methyl]-2-thiazolidinylidene]- (Z)- thiacloprid PubMed: Protecting effect of recycled urban wastes (sewage sludge and wastewater) on ryegrass against the toxicity of pesticides at high concentrations. PubMed: Susceptibility in field populations of codling moth, Cydia pomonella (L.) (Lepidoptera: Tortricidae), in Ontario and Quebec apple orchards to a selection of insecticides. PubMed: Neonicotinoids interfere with specific components of navigation in honeybees. PubMed: Enrichment of neonicotinoid insecticides from lemon juice sample with magnetic three-dimensional graphene as the adsorbent followed by determination with high-performance liquid chromatography. PubMed: Thiacloprid-Nosema ceranae interactions in honey bees: Host survivorship but not parasite reproduction is dependent on pesticide dose. PubMed: [Population dynamics and control techniques of aphids on honeysuckle]. PubMed: [Simultaneous determination of 6 neonicotinoid residues in soil using DLLME-HPLC and UV]. PubMed: Effective extraction method for determination of neonicotinoid residues in tea. PubMed: Detection and analysis of neonicotinoids in river waters - development of a passive sampler for three commonly used insecticides. PubMed: Dissipation rate of thiacloprid and its control effect against Bemisia tabaci in greenhouse tomato after soil application. PubMed: Lethal and behavioral effects of pesticides on the insect predator Macrolophus pygmaeus. PubMed: Trace level determination of pyrethroid and neonicotinoid insecticides in beebread using acetonitrile-based extraction followed by analysis with ultra-high-performance liquid chromatography-tandem mass spectrometry. PubMed: The impact of insecticides applied in apple orchards on the predatory mite Kampimodromus aberrans (Acari: Phytoseiidae). PubMed: Simultaneous determination of residues in pollen and high-fructose corn syrup from eight neonicotinoid insecticides by liquid chromatography-tandem mass spectrometry. PubMed: Detection of resistance, cross-resistance, and stability of resistance to new chemistry insecticides in Bemisia tabaci (Homoptera: Aleyrodidae). PubMed: Culmination of low-dose pesticide effects. PubMed: Evaluation of cytochrome P450 activity in field populations of Cydia pomonella (Lepidoptera: Tortricidae) resistant to azinphosmethyl, acetamiprid, and thiacloprid. PubMed: Development of an oligopeptide functionalized surface plasmon resonance biosensor for online detection of glyphosate. PubMed: Determination of neonicotinoid insecticides residues in eels using subcritical water extraction and ultra-performance liquid chromatography-tandem mass spectrometry. PubMed: Multi-residue method for determination of selected neonicotinoid insecticides in honey using optimized dispersive liquid-liquid microextraction combined with liquid chromatography-tandem mass spectrometry. PubMed: Development of a chemiluminescence enzyme-linked immunosorbent assay for the simultaneous detection of imidaclothiz and thiacloprid in agricultural samples. PubMed: Reduction of hazardous organic solvent in sample preparation for hydrophilic pesticide residues in agricultural products with conventional liquid chromatography. PubMed: Acrylamide biodegradation ability and plant growth-promoting properties of Variovorax boronicumulans CGMCC 4969. PubMed: Does insecticide application in a winter oilseed rape field influence the abundance of pollen beetle Meligethes aeneus in nearby ornamental flowers and vegetables? PubMed: Determination of seven neonicotinoid insecticides in beeswax by liquid chromatography coupled to electrospray-mass spectrometry using a fused-core column. PubMed: Sub-lethal effects of four neonicotinoid seed treatments on the demography and feeding behaviour of the wheat aphid Sitobion avenae. PubMed: Persistence of thiacloprid residues on brinjal (Solanum melongena L.). PubMed: Impact of insecticide residue exposure on the invasive pest, Halyomorpha halys (Hemiptera: Pentatomidae): analysis of adult mobility. PubMed: Survey of neonicotinoids and fipronil in corn seeds for agriculture. PubMed: The Landau Stream Mesocosm Facility: pesticide mitigation in vegetated flow-through streams. PubMed: Dissipation and persistence of flubendiamide and thiacloprid in/on tomato and soil. PubMed: Impact of insecticide and fungicide residue contact on plum curculio, Conotrachelus nenuphar (Herbst), mobility and mortality: implications for pest management. PubMed: Efficacy of six neonicotinoid insecticides alone and in combination with deltamethrin and piperonyl butoxide against pyrethroid-resistant Aedes aegypti and Anopheles gambiae (Diptera: Culicidae). PubMed: Towards integrated pest management in red clover seed production. PubMed: Use of time-of-flight mass spectrometry for large screening of organic pollutants in surface waters and soils from a rice production area in Colombia. PubMed: Differences in the sensitivity among cryptic lineages of the Gammarus fossarum complex. PubMed: Comparative persistence of thiacloprid in Bt-transgenic cabbage (Brassica oleracea cv. capitata) vis-à-vis non-transgenic crop and its decontamination. PubMed: UHPLC-DAD method for the determination of neonicotinoid insecticides in single bees and its relevance in honeybee colony loss investigations. PubMed: Rapid and simple analysis of pesticides persisting on green pepper surfaces swabbing with solvent-moistened cotton. PubMed: Persistence behaviour of thiacloprid residues in/on green tea leaves, processed tea and tea infusion. PubMed: Insecticide resistance profiles can be misleading in predicting the survival of Myzus persicae genotypes on potato crops following the application of different insecticide classes. PubMed: Thiamethoxam acts as a target-site synergist of spinosad in resistant strains of Frankliniella occidentalis. PubMed: Thiacloprid residues and its safety evaluation in Darjeeling tea. PubMed: In vitro investigation of the genotoxic and cytotoxic effects of thiacloprid in cultured human peripheral blood lymphocytes. PubMed: Comprehensive qualitative and quantitative determination of pesticides and veterinary drugs in honey using liquid chromatography-Orbitrap high resolution mass spectrometry. PubMed: Effects of commercial formulations of deltamethrin and/or thiacloprid on thyroid hormone levels in rat serum. PubMed: The power of hyphenated chromatography/time-of-flight mass spectrometry in public health laboratories. PubMed: Evaluation of genotoxic and cytotoxic effects in human peripheral blood lymphocytes exposed in vitro to neonicotinoid insecticides news. PubMed: Reactivity of neonicotinoid insecticides with carbonate radicals. PubMed: Thiacloprid affects trophic interaction between gammarids and mayflies. PubMed: Prey consumption rates and compatibility with pesticides of four predatory mites from the family Phytoseiidae attacking Thrips palmi Karny (Thysanoptera: Thripidae). PubMed: A metabolomics based test of independent action and concentration addition using the earthworm Lumbricus rubellus. PubMed: Oligopeptides functionalized surface plasmon resonance biosensors for detecting thiacloprid and imidacloprid. PubMed: Assessment of toxicity risk of insecticides used in rice ecosystem on Trichogramma japonicum, an egg parasitoid of rice lepidopterans. PubMed: Penetrative and dislodgeable residue characteristics of 14C-insecticides in apple fruit. PubMed: Influence of pesticides on yeasts colonizing leaves. PubMed: Biotransformation of the neonicotinoid insecticide thiacloprid by the bacterium Variovorax boronicumulans strain J1 and mediation of the major metabolic pathway by nitrile hydratase. PubMed: Killing them with kindness? In-hive medications may inhibit xenobiotic efflux transporters and endanger honey bees. PubMed: LC-MS/MS analysis of neonicotinoid insecticides in honey: methodology and residue findings in Austrian honeys. PubMed: [Detection of chloropyridinyl neonicotinoid insecticide metabolite 6-chloronicotinic acid in the urine: six cases with subacute nicotinic symptoms]. PubMed: LC/DAD/ESI/MS method for the determination of imidacloprid, thiacloprid, and spinosad in olives and olive oil after field treatment. PubMed: Cytogenetic effects of commercial formulations of deltamethrin and/or thiacloprid on Wistar rat bone marrow cells. PubMed: Exposure to sublethal doses of fipronil and thiacloprid highly increases mortality of honeybees previously infected by Nosema ceranae. PubMed: Determination of sixteen pesticides in peppers using high-performance liquid chromatography/mass spectrometry. PubMed: Toxicities and sublethal effects of seven neonicotinoid insecticides on survival, growth and reproduction of imidacloprid-resistant cotton aphid, Aphis gossypii. PubMed: Dissipation and residue of thiacloprid in cabbage and soil. PubMed: Determination of neonicotinoid pesticides residues in agricultural samples by solid-phase extraction combined with liquid chromatography-tandem mass spectrometry. PubMed: Synthesis and insecticidal activities of novel 1,3,4-thiadiazole 5-fluorouracil acetamides derivatives: an RNA interference insecticide. PubMed: Effects of predator cues on pesticide toxicity: toward an understanding of the mechanism of the interaction. PubMed: Soil microbial degradation of neonicotinoid insecticides imidacloprid, acetamiprid, thiacloprid and imidaclothiz and its effect on the persistence of bioefficacy against horsebean aphid Aphis craccivora Koch after soil application. PubMed: Persistence of two neonicotinoid insecticides in wastewater, and in aqueous solutions of surfactants and dissolved organic matter. PubMed: Traits and stress: keys to identify community effects of low levels of toxicants in test systems. PubMed: Tools for resistance monitoring in oriental fruit moth (Lepidoptera: Tortricidae) and first assessment in Brazilian populations. PubMed: Neonicotinoid insecticides: oxidative stress in planta and metallo-oxidase inhibition. PubMed: Efficacy of several insecticides alone and with horticultural mineral oils on light brown apple moth (Lepidoptera: Tortricidae) eggs. PubMed: Pyrethroid resistance and thiacloprid baseline susceptibility of European populations of Meligethes aeneus (Coleoptera: Nitidulidae) collected in winter oilseed rape. PubMed: New analogues of (E)-β-farnesene with insecticidal activity and binding affinity to aphid odorant-binding proteins. PubMed: Pesticide adsorption in relation to soil properties and soil type distribution in regional scale. PubMed: Neonicotinoid insecticides: highlights of a symposium on strategic molecular designs. PubMed: Activity of broad-spectrum and reduced-risk insecticides on various life stages of cranberry fruitworm (Lepidoptera: Pyralidae) in highbush blueberry. PubMed: Pesticide dissipation curves in peach, pear and tomato crops in Uruguay. PubMed: Receptor structure-guided neonicotinoid design. PubMed: Plum curculio (Coleoptera: Curculionidae) adult mortality and associated fruit injury after exposure to field-aged insecticides on tart cherry branches. PubMed: Effects of binary mixtures on the life traits of Daphnia magna. PubMed: Toxicity of three binary mixtures to Daphnia magna: comparing chemical modes of action and deviations from conceptual models. PubMed: The significance of the Druckrey-Küpfmüller equation for risk assessment--the toxicity of neonicotinoid insecticides to arthropods is reinforced by exposure time. PubMed: Ecotoxicity of neonicotinoid insecticides to bees. PubMed: Discovery of imidacloprid and further developments from strategic molecular designs. PubMed: Effects of six selected orchard insecticides on Neoseiulus fallacis (Acari: Phytoseiidae) in the laboratory. PubMed: Degradation of thiacloprid in aqueous solution by UV and UV/H2O2 treatments. PubMed: Transcriptomic and proteomic effects of a neonicotinoid insecticide mixture in the marine mussel (Mytilus galloprovincialis, Lam.). PubMed: Biotransformation of thianicotinyl neonicotinoid insecticides: diverse molecular substituents response to metabolism by bacterium Stenotrophomonas maltophilia CGMCC 1.1788. PubMed: Metabolism of the Neonicotinoid insecticides acetamiprid and thiacloprid by the yeast Rhodotorula mucilaginosa strain IM-2. PubMed: Effect of dissolved ozone or ferric ions on photodegradation of thiacloprid in presence of different TiO2 catalysts. PubMed: Integrated management of phytoplasma diseases in pome fruit: an overview of efficacy results of IPM insecticides against pear Psylla (Cacopsylla pyri). PubMed: Assessing toxicity of the insecticide thiacloprid on Chironomus riparius (Insecta: Diptera) using multiple end points. PubMed: Curative activity of insecticides on Rhagoletis pomonella (Diptera: Tephritidae) in apples. PubMed: Curative activity of insecticides against plum curculio (Coleoptera: Curculionidae) in tart cherries. PubMed: Comparative toxicity of pesticides to stingless bees (Hymenoptera: Apidae: Meliponini). PubMed: Risk assessment for side-effects of neonicotinoids against bumblebees with and without impairing foraging behavior. PubMed: Reactivity of hydroxyl radicals with neonicotinoid insecticides: mechanism and changes in toxicity. PubMed: Residues of Pesticides in honeybee (Apis mellifera carnica) bee bread and in pollen loads from treated apple orchards. PubMed: Multiresidue analysis of neonicotinoids by solid-phase extraction technique using high-performance liquid chromatography. PubMed: Hydroxylation of thiacloprid by bacterium Stenotrophomonas maltophilia CGMCC1.1788. PubMed: Enzymes and inhibitors in neonicotinoid insecticide metabolism. PubMed: Multiresidue analysis of pesticides with hydrolyzable functionality in cooked vegetables by liquid chromatography tandem mass spectrometry. PubMed: Effect of seven new orchard pesticides on Galendromus occidentalis in laboratory studies. PubMed: Chemistry of polyhalogenated nitrobutadienes, 8: Nitropolychlorobutadienes--precursors for insecticidal neonicotinoids. PubMed: Influence of avian reproduction ecotoxicological endpoints in the assessment of plant protection products. PubMed: The selectivity in the time of thiacloprid (Calypso 480 SC) applied at preblossom on the further Anthocoris nemoralis population build up in pears. PubMed: Neonicotinoids as seed potato treatments to control wireworms. PubMed: Desorption electrospray ionization mass spectrometry for trace analysis of agrochemicals in food. PubMed: Risk assessment of thiacloprid and its chemical decontamination on eggplant, Solanum melongena L. PubMed: On-line monitoring imidacloprid and thiacloprid in celery juice using quartz crystal microbalance. PubMed: Determination of neonicotinoid insecticides residues in bovine milk samples by solid-phase extraction clean-up and liquid chromatography with diode-array detection. PubMed: Variability of pesticide exposure in a stream mesocosm system: macrophyte-dominated vs. non-vegetated sections. PubMed: Correlated responses to neonicotinoid insecticides in clones of the peach-potato aphid, Myzus persicae (Hemiptera: Aphididae). PubMed: Long-term stream invertebrate community alterations induced by the insecticide thiacloprid: effect concentrations and recovery dynamics. PubMed: Measuring and modelling mixture toxicity of imidacloprid and thiacloprid on Caenorhabditis elegans and Eisenia fetida. PubMed: Susceptibility to neonicotinoids and risk of resistance development in the brown planthopper, Nilaparvata lugens (Stål) (Homoptera: Delphacidae). PubMed: Aquatic passive sampling of a short-term thiacloprid pulse with the Chemcatcher: impact of biofouling and use of a diffusion-limiting membrane on the sampling rate. PubMed: Applied aspects of neonicotinoid uses in crop protection. PubMed: Atomic interactions of neonicotinoid agonists with AChBP: molecular recognition of the distinctive electronegative pharmacophore. PubMed: Effect of light on the degradation of two neonicotinoids viz acetamiprid and thiacloprid in soil. PubMed: Acute and delayed effects of the neonicotinoid insecticide thiacloprid on seven freshwater arthropods. PubMed: Temperature-dependent effects of the pesticides thiacloprid and diazinon on the embryonic development of zebrafish (Danio rerio). PubMed: Atypical nicotinic agonist bound conformations conferring subtype selectivity. PubMed: Potential of 11 pesticides to initiate downstream drift of stream macroinvertebrates. PubMed: Insecticidal resistance and cross-resistance in populations of Cydia pomonella (Lepidoptera: Tortricidae) in central Europe. PubMed: Residual dynamics of thiacloprid in medical herbs marjoram, thyme, and camomile in soil. PubMed: Diversity of insecticide resistance mechanisms and spectrum in European populations of the codling moth, Cydia pomonella. PubMed: Novel life stage targets against plum curculio, Conotrachelus nenuphar (Herbst), in apple integrated pest management. PubMed: Agonist actions of neonicotinoids on nicotinic acetylcholine receptors expressed by cockroach neurons. PubMed: Ovicidal and larvicidal effectiveness of insecticides applied by dipping apples on the small fruit tortrix Grapholita lobarzewskii. PubMed: Safe apples for baby-food production: survey of pesticide treatment regimes leaving minimum residues. PubMed: Mapping the elusive neonicotinoid binding site. PubMed: Use of residue profile analysis to identify modes of insecticide activity contributing to control of plum curculio in apples. PubMed: Unique and common metabolites of thiamethoxam, clothianidin, and dinotefuran in mice. PubMed: Effects of spinosad, spinosad bait, and chloronicotinyl insecticides on mortality and control of adult and larval western cherry fruit fly (Diptera: Tephritidae). PubMed: A nicotinic acetylcholine receptor mutation (Y151S) causes reduced agonist potency to a range of neonicotinoid insecticides. PubMed: Immunoassay for acetamiprid detection: application to residue analysis and comparison with liquid chromatography. PubMed: Chloropyridinyl neonicotinoid insecticides: diverse molecular substituents contribute to facile metabolism in mice. PubMed: Field evaluations of systemic insecticides for control of Anoplophora glabripennis (Coleoptera: Cerambycidae) in China. PubMed: Development, oviposition, and mortality of Neoseiulus fallacis (Acari: Phytoseiidae) in response to reduced-risk insecticides. PubMed: Toxicity of Bacillus thuringiensis var. israelensis formulations, spinosad, and selected synthetic insecticides to Chironomus tepperi larvae. PubMed: Application of solid-phase extraction and liquid chromatography-mass spectrometry to the determination of neonicotinoid pesticide residues in fruit and vegetables. PubMed: Role of neonicotinyl insecticides in Washington apple integrated pest management. Part II. Nontarget effects on integrated mite control. PubMed: Role of neonicotinyl insecticides in Washington apple integrated pest management. Part I. Control of lepidopteran pests. PubMed: Selectivity of pesticides used on cotton (Gossypium hirsutum) to Trichogramma pretiosum reared on two laboratory-reared hosts. PubMed: Analysis of nicotinoid insecticides residues in honey by solid matrix partition clean-up and liquid chromatography-electrospray mass spectrometry. PubMed: Resistance and cross-resistance to neonicotinoid insecticides and spinosad in the Colorado potato beetle, Leptinotarsa decemlineata (Say) (Coleoptera: Chrysomelidae). PubMed: Sorption of pesticides in tropical and temperate soils from Australia and the Philippines. PubMed: The intrinsic toxicity of several neonicotinoids to Lygus lineolaris and Hyaliodes vitripennis, a phytophagous and a predacious mirid. PubMed: Quantitation and accurate mass analysis of pesticides in vegetables by LC/TOF-MS. PubMed: Neonicotinoid insecticide toxicology: mechanisms of selective action. PubMed: Simultaneous determination of imidacloprid, thiacloprid, and thiamethoxam in soil and water by high-performance liquid chromatography with diode-array detection. PubMed: Effects of neonicotinoid insecticides on the bionomics of twospotted spider mite (Acari: Tetranychidae). PubMed: Comparative analysis of neonicotinoid binding to insect membranes: I. A structure-activity study of the mode of [3H]imidacloprid displacement in Myzus persicae and Aphis craccivora. PubMed: Field and laboratory tests of new insecticides against the apple maggot, Rhagoletis pomonella (Walsh) (Diptera: Tephritidae). PubMed: Determination of neonicotinoid pesticide residues in vegetables and fruits with solid phase extraction and liquid chromatography mass spectrometry. PubMed: Field relevance of a synergistic effect observed in the laboratory between an EBI fungicide and a chloronicotinyl insecticide in the honeybee (Apis mellifera L, Hymenoptera). PubMed: Selective toxicity of neonicotinoids attributable to specificity of insect and mammalian nicotinic receptors. PubMed: Analgesic and toxic effects of neonicotinoid insecticides in mice. PubMed: Development of an ELISA for the detection of the residues of the insecticide imidacloprid in agricultural and environmental samples. PubMed: Neonicotinoid insecticides: molecular features conferring selectivity for insect versus mammalian nicotinic receptors. PubMed: Imidacloprid, thiacloprid, and their imine derivatives up-regulate the alpha 4 beta 2 nicotinic acetylcholine receptor in M10 cells. PubMed: Insect nicotinic acetylcholine receptor: conserved neonicotinoid specificity of [(3)H]imidacloprid binding site. PubMed: Characterization of nicotinic acetylcholine receptors from the insects Aphis craccivora, Myzus persicae, and Locusta migratoria by radioligand binding assays: relation to thiamethoxam action.