isobutyryl shikonin

propanoic acid, 2-methyl-, 1-(1,4-dihydro-5,8-dihydroxy-1,4-dioxo-2-naphthalenyl)-4-methyl-3-penten-1-yl ester

CAS: 52438-12-7 C20 H22 O6 MW: 358.39054000

Identification

Nameisobutyryl shikonin
CAS Number52438-12-7
FDA UNIISearch
Molecular FormulaC20 H22 O6
Molecular Weight358.39054000
Nikkaji NumberJ256.587K

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Boiling Point 561.89 °C. @ 760.00 mm Hg (est)
Flash Point 389.00 °F. TCC ( 198.40 °C. ) (est)
logP (o/w) 3.563 (est)
Soluble in water, 0.4429 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categorynatural substances and extractives
Recommendation for isobutyryl shikonin usage levels up tonot for fragrance use.
Recommendation for isobutyryl shikonin flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

gromwell purple gromwell

Synonyms

iso butyrylshikonin 1-(5,8- dihydroxy-1,4-dioxo-1,4-dihydronaphthalen-2-yl)-4-methylpent-3-en-1-yl 2-methylpropanoate [1-(5,8- dihydroxy-1,4-dioxonaphthalen-2-yl)-4-methylpent-3-enyl]2-methylpropanoate propanoic acid, 2-methyl-, 1-(1,4-dihydro-5,8-dihydroxy-1,4-dioxo-2-naphthalenyl)-4-methyl-3-penten-1-yl ester PubMed: Effect of l-phenylalanine on PAL activity and production of naphthoquinone pigments in suspension cultures of Arnebia euchroma (Royle) Johnst. PubMed: In vitro and in vivo anticancer effects of Lithospermum erythrorhizon extract on B16F10 murine melanoma. PubMed: Identification of shikonin and its ester derivatives from the roots of Echium italicum L. PubMed: Naturally-occurring shikonin analogues--a class of necroptotic inducers that circumvent cancer drug resistance. PubMed: Shikonins attenuate microglial inflammatory responses by inhibition of ERK, Akt, and NF-kappaB: neuroprotective implications. PubMed: Human ACAT inhibitory effects of shikonin derivatives from Lithospermum erythrorhizon. PubMed: The shikonin derivatives and pyrrolizidine alkaloids in hairy root cultures of Lithospermum canescens (Michx.) Lehm. PubMed: Immunomodulatory effect of shikonin derivatives isolated from Lithospermum canescens on cellular and humoral immunity in Balb/c mice. PubMed: Shikonin production by p-fluorophenylalanine resistant cells of Lithospermum erythrorhizon.