tau-fluvalinate
D-valine, N-[2-chloro-4-(trifluoromethyl)phenyl]-, cyano(3-phenoxyphenyl)methyl ester
Identification
| Name | tau-fluvalinate |
| CAS Number | 102851-06-9 |
| FDA UNII | R533F643E8 |
| Molecular Formula | C26 H22 Cl F3 N2 O3 |
| Molecular Weight | 502.92014960 |
| MDL Number | MFCD00871307 |
| Nikkaji Number | J59.569A |
| Beilstein | 8092907 |
Regulatory
Physical Properties
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Boiling Point | 566.20 °C. @ 760.00 mm Hg (est) |
| Flash Point | 565.00 °F. TCC ( 296.20 °C. ) (est) |
| logP (o/w) | 7.310 (est) |
| Soluble in | water, 0.0005691 mg/L @ 25 °C (est) |
No sensory data available
Safety Information
| Oral/Parenteral Toxicity | Not determined |
| Dermal Toxicity | Not determined |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | herbicides / pesticides |
| Recommendation for tau-fluvalinate usage levels up to | not for fragrance use. |
| Recommendation for tau-fluvalinate flavor usage levels up to | not for flavor use. |
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Potential Uses
Natural Occurrence
Synonyms
(2R)-2-[2-
chloro-4-(trifluoromethyl)anilino]-3-methylbutanoic acid [cyano-(3-phenoxyphenyl)methyl] ester
N-[2-
chloro-4-(trifluorométhyl)phényl]-D-valinate de cyano(3-phénoxyphényl)méthyle
N-[2-
chloro-4-(trifluoromethyl)phenyl]-D-valine cyano(3-phenoxyphenyl)methyl ester
cyano-(3-phenoxyphenyl)methyl] (2R)-2-[[2-chloranyl-4-(trifluoromethyl)phenyl]amino]-3-methyl-butanoate
cyano-(3-phenoxyphenyl)methyl] (2R)-2-[2-chloro-4-(trifluoromethyl)anilino]-3-methylbutanoate
(RS)-a-
cyano-3-phenoxybenzyl N-(2-chloro-a,a,a-trifluoro-p-tolyl)-D-valinate
cyano(3-phenoxyphenyl)methyl (2R)-2-{[2-chloro-4-(trifluoromethyl)phenyl]amino}-3-methylbutanoate
cyano(3-phenoxyphenyl)methyl N-[2-chloro-4-(trifluoromethyl)phenyl]-D-valinate
fluvarol
fluwarol
D-
valine, N-[2-chloro-4-(trifluoromethyl)phenyl]-, cyano(3-phenoxyphenyl)methyl ester
PubMed:
Xenobiotic effects on intestinal stem cell proliferation in adult honey bee (Apis mellifera L) workers.
PubMed:
Target-site resistance to pyrethroid insecticides in German populations of the cabbage stem flea beetle, Psylliodes chrysocephala L. (Coleoptera: Chrysomelidae).
PubMed:
An amino acid substitution (L925V) associated with resistance to pyrethroids in Varroa destructor.
PubMed:
Molecular and functional characterization of CYP6BQ23, a cytochrome P450 conferring resistance to pyrethroids in European populations of pollen beetle, Meligethes aeneus.
PubMed:
Point mutations in the sodium channel gene conferring tau-fluvalinate resistance in Varroa destructor.
PubMed:
Field-level sublethal effects of approved bee hive chemicals on Honey Bees (Apis mellifera L).
PubMed:
The impact of insecticides applied in apple orchards on the predatory mite Kampimodromus aberrans (Acari: Phytoseiidae).
PubMed:
Currently used pesticides and their mixtures affect the function of sex hormone receptors and aromatase enzyme activity.
PubMed:
The development of an economic threshold for Nasonovia ribisnigri (Hemiptera: Aphididae) on lettuce in central Spain.
PubMed:
Fate of dermally applied miticides fluvalinate and amitraz within honey bee (Hymenoptera: Apidae) bodies.
PubMed:
Effects of fluvalinate on honey bee learning, memory, responsiveness to sucrose, and survival.
PubMed:
Acaricide, fungicide and drug interactions in honey bees (Apis mellifera).
PubMed:
Proteolysis on the body surface of pyrethroid-sensitive and resistant Varroa destructor.
PubMed:
Comparative toxicity of acaricides to honey bee (Hymenoptera: Apidae) workers and queens.
PubMed:
Incidence of pyrethroid-resistant oilseed rape pests in Germany.
PubMed:
Immune-related gene expression in nurse honey bees (Apis mellifera) exposed to synthetic acaricides.
PubMed:
Simultaneous determination of pesticides and 5-hydroxymethylfurfural in honey by the modified QuEChERS method and liquid chromatography coupled to tandem mass spectrometry.
PubMed:
Effects of a naturally occurring and a synthetic synergist on toxicity of three insecticides and a phytochemical to navel orangeworm (Lepidoptera: Pyralidae).
PubMed:
Estimation of measurement uncertainty associated to the determination of pesticide residues: a case study.
PubMed:
Identification of mutations associated with pyrethroid resistance in the voltage-gated sodium channel of the tomato leaf miner (Tuta absoluta).
PubMed:
Using video-tracking to assess sublethal effects of pesticides on honey bees (Apis mellifera L.).
PubMed:
Ecologically appropriate xenobiotics induce cytochrome P450s in Apis mellifera.
PubMed:
The effect of a piperonyl butoxide/tau-fluvalinate mixture on pollen beetle (Meligethes aeneus) and honey bees (Apis mellifera).
PubMed:
Direct effect of acaricides on pathogen loads and gene expression levels in honey bees Apis mellifera.
PubMed:
Killing them with kindness? In-hive medications may inhibit xenobiotic efflux transporters and endanger honey bees.
PubMed:
Acaricide treatment affects viral dynamics in Varroa destructor-infested honey bee colonies via both host physiology and mite control.
PubMed:
Simultaneous analysis of pesticides from different chemical classes by using a derivatisation step and gas chromatography-mass spectrometry.
PubMed:
CYP9Q-mediated detoxification of acaricides in the honey bee (Apis mellifera).
PubMed:
Fluorinated monolithic column for CEC.
PubMed:
Acaricides and their residues in Spanish commercial beeswax.
PubMed:
A rapid and sensitive analytical method for the determination of 14 pyrethroids in water samples.
PubMed:
Synergistic interactions between in-hive miticides in Apis mellifera.
PubMed:
Study of the degradation products of bromopropylate, chlordimeform, coumaphos, cymiazole, flumethrin and tau-fluvalinate in aqueous media.
PubMed:
New multiresidue method using solid-phase extraction and gas chromatography-micro-electron-capture detection for pesticide residues analysis in royal jelly.
PubMed:
Residual effectiveness of three pyrethroids on vegetation against adult Aedes albopictus and Culex quinquefasciatus in screened field cages.
PubMed:
Determination of 23 pesticide residues in leafy vegetables using gas chromatography-ion trap mass spectrometry and analyte protectants.
PubMed:
Application of solid-phase microextraction for determination of pyrethroids in groundwater using liquid chromatography with post-column photochemically induced fluorimetry derivatization and fluorescence detection.
PubMed:
Solid-phase microextraction (SPME) for the determination of pyrethroids in cucumber and watermelon using liquid chromatography combined with post-column photochemically induced fluorimetry derivatization and fluorescence detection.
PubMed:
Pesticide residues in beeswax samples collected from honey bee colonies (Apis mellifera L.) in France.
PubMed:
Efficacy of various pyrethroid structures against a highly metabolically resistant isogenic strain of Helicoverpa armigera (Lepidoptera: Noctuidae) from China.
PubMed:
Efficacy of strips coated with Metarhizium anisopliae for control of Varroa destructor (Acari: Varroidae) in honey bee colonies in Texas and Florida.
PubMed:
Mediation of pyrethroid insecticide toxicity to honey bees (Hymenoptera: Apidae) by cytochrome P450 monooxygenases.
PubMed:
A survey of pesticide residues in pollen loads collected by honey bees in France.
PubMed:
Determination of nine pyrethroid insecticides by high-performance liquid chromatography with post-column photoderivatization and detection based on acetonitrile chemiluminescence.
PubMed:
Determination of acaricide residues in saudi arabian honey and beeswax using solid phase extraction and gas chromatography.
PubMed:
Comparative sublethal toxicity of nine pesticides on olfactory learning performances of the honeybee Apis mellifera.
PubMed:
[Determination of tau-fluvalinate residue in honey by GC].
PubMed:
Field trials using the fungal pathogen, Metarhizium anisopliae (Deuteromycetes: Hyphomycetes) to control the ectoparasitic mite, Varroa destructor (Acari: Varroidae) in honey bee, Apis mellifera (Hymenoptera: Apidae) colonies.
PubMed:
Effects of methoxyfenozide, indoxacarb, and other insecticides on the beneficial egg parasitoid Trichogramma nr. brassicae (Hymenoptera: Trichogrammatidae) under laboratory and field conditions.
PubMed:
Insecticide-resistant pollen beetles (Meligethes aeneus F) found in Danish oilseed rape (Brassica napus L) fields.
PubMed:
Biological monitoring of workers after the application of insecticidal pyrethroids.
PubMed:
Application of solid-phase microextraction for the determination of pyrethroid residues in vegetable samples by GC-MS.
PubMed:
Study of acaricide stability in honey. Characterization of amitraz degradation products in honey and beeswax.
PubMed:
Study of tau-fluvalinate persistence in honey.
PubMed:
A veterinary approach to the European honey bee (Apis mellifera)
PubMed:
Field evaluation of neem and canola oil for the selective control of the honey bee (Hymenoptera: Apidae) mite parasites Varroa jacobsoni (Acari: Varroidae) and Acarapis woodi (Acari: Tarsonemidae).
PubMed:
Comparative laboratory toxicity of neem pesticides to honey bees (Hymenoptera: Apidae), their mite parasites Varroa jacobsoni (Acari: Varroidae) and Acarapis woodi (Acari: Tarsonemidae), and brood pathogens Paenibacillus larvae and Ascophaera apis.
PubMed:
Laboratory evaluation of miticides to control Varroa jacobsoni (Acari: Varroidae), a honey bee (Hymenoptera: Apidae) parasite.
PubMed:
First detection in Israel of fluvalinate resistance in the varroa mite using bioassay and biochemical methods.
PubMed:
Clean-up of aqueous acetone vegetable extracts by solid-matrix partition for pyrethroid residue determination by gas chromatography-electron-capture detection.