ethyl methyl-para-tolyl glycidate

ethyl methyl-p-tolylglycidate

CAS: 74367-97-8 C13 H16 O3 MW: 220.26812000 fruity fruity

Identification

Nameethyl methyl-para-tolyl glycidate
IUPACethyl 3-methyl-3-(4-methylphenyl)oxirane-2-carboxylate
CAS Number74367-97-8
EINECS277-844-3
FDA UNII24HU805Y6Y
Molecular FormulaC13 H16 O3
Molecular Weight220.26812000
Nikkaji NumberJ318.963E
CoE Number11707

Regulatory

JECFA Food Flavoring1578 ethyl methyl-p-tolylglycidate
DG SANTE Food Flavourings16.040 ethyl 2,3-epoxy-3-methyl-3-p-tolylpropionate
FEMA Number3757
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)74367-97-8 ; ETHYL METHYL-P-TOLYLGLYCIDATE

Physical Properties

Appearance colorless to pale yellow clear viscous liquid (est)
Assay 96.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 1.08100 to 1.08700 @ 20.00 °C.
Pounds per Gallon - (est). 9.005 to 9.055
Refractive Index 1.52300 to 1.52900 @ 20.00 °C.
Boiling Point 123.00 to 125.00 °C. @ 760.00 mm Hg
Acid Value 2.00 max. KOH/g
Vapor Pressure 0.002000 mmHg @ 25.00 °C. (est)
Flash Point 246.00 °F. TCC ( 118.89 °C. )
logP (o/w) 2.887 (est)
Soluble in alcohol
Insoluble in water

Organoleptic Properties

Odor Description
at 10.00 % in dipropylene glycol.
Floral, green, fruity, sweet, berry- and cherry-like with powdery nuances
Taste Description at 25.00 ppm.

Safety Information

Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for ethyl methyl-para-tolyl glycidate usage levels up to8.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)20.00 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)0.009 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI)ND (μg/person/day)
Threshold of Concern90 (μg/person/day)
Structure ClassIII
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FR almond FR berry FR cherry FL fruit tropical fruit FR raspberry FR strawberry FR vanilla

Natural Occurrence

not found in nature

Synonyms

ethyl 2,3-epoxy-3-(4-methylphenyl)butanoate ethyl 2,3-epoxy-3-methyl-3-p-tolyl propionate ethyl 2,3-epoxy-3-methyl-3-p-tolylpropionate ethyl 2,3-epoxy-3-methyl-3-para-tolyl propionate ethyl 2,3-epoxy-3-p-tolylbutyrate ethyl 3-methyl-3-(4-methyl phenyl) oxirane carboxylate ethyl 3-methyl-3-(4-methylphenyl)oxirane-2-carboxylate ethyl 3-methyl-3-(4-methylphenyl)oxiranecarboxylate ethyl 3-methyl-3-(p-tolyl) glycidate ethyl 3-methyl-3-(p-tolyl)glycidate ethyl 3-methyl-3-(para-tolyl) glycidate ethyl methyl p-tolylglycidate ethyl methyl-p-methylphenylglycidate ethyl methyl-p-tolyl glycidate ethyl methyl-p-tolylglycidate ethyl methyl-para-methyl phenyl glycidate ethylmethyl-p-methylphenylglycidate ethylmethyl-para-methylphenylglycidate oxiranecarboxylic acid, 3-methyl-3-(4-methylphenyl)-, ethyl ester Info: epoxides