methyl formate

formic acid methyl ester formic acid, methyl ester formicacidmethylester methyl ester of formic acid methyl methanoate methylformate PubMed: Correction to "ab initio reaction kinetics of hydrogen abstraction from methyl formate by hydrogen, methyl, oxygen, hydroxyl, and hydroperoxy radicals". PubMed: Detection and Identification of the Keto-Hydroperoxide (HOOCH2OCHO) and Other Intermediates during Low-Temperature Oxidation of Dimethyl Ether. PubMed: Sonophotodeposition of Bimetallic Photocatalysts Pd-Au/TiO2 : Application to Selective Oxidation of Methanol to Methyl Formate. PubMed: Dynamical, spectroscopic and computational imaging of bond breaking in photodissociation: roaming and role of conical intersections. PubMed: Comparison of sample preparation methods for the quantitative analysis of eicosanoids and other oxylipins in plasma by means of LC-MS/MS. PubMed: Formation of complex organic molecules in methanol and methanol-carbon monoxide ices exposed to ionizing radiation--a combined FTIR and reflectron time-of-flight mass spectrometry study. PubMed: Methyl N-phenyl carbamate synthesis from aniline and methyl formate: carbon recycling to chemical products. PubMed: Addition-elimination versus Tishchenko reaction in the gas phase. PubMed: The formation of glycine and other complex organic molecules in exploding ice mantles. PubMed: Low-energy electron-induced chemistry of condensed methanol: implications for the interstellar synthesis of prebiotic molecules. PubMed: Mass spectral characterisation of a polar, esterified fraction of an organic extract of an oil sands process water. PubMed: Theoretical spectroscopic characterization at low temperatures of S-methyl thioformate and O-methyl thioformate. PubMed: Homogeneous hydrogenation of CO₂ to methyl formate utilizing switchable ionic liquids. PubMed: Electrocatalytic oxidation and adsorption rate of methanol at Pt stepped single-crystal electrodes and effect of Ru step decoration: a DEMS study. PubMed: Ag/Au mixed sites promote oxidative coupling of methanol on the alloy surface. PubMed: Accurate bond energies of biodiesel methyl esters from multireference averaged coupled-pair functional calculations. PubMed: Surface treatment with methyl formate-methyl acetate increased the shear bond strength between reline resins and denture base resin. PubMed: Molecular hydrogen formation from photocatalysis of methanol on anatase-TiO₂(101). PubMed: Roads leading to roam. Role of triple fragmentation and of conical intersections in photochemical reactions: experiments and theory on methyl formate. PubMed: The α-effect and competing mechanisms: the gas-phase reactions of microsolvated anions with methyl formate. PubMed: Variation in concentration of perfluorooctanoic acid in methanol solutions during storage. PubMed: Shape-controlled solvothermal synthesis of Bi2S3 for photocatalytic reduction of CO2 to methyl formate in methanol. PubMed: Graphene-supported Au-Pd bimetallic nanoparticles with excellent catalytic performance in selective oxidation of methanol to methyl formate. PubMed: LC-MS/MS method for rapid and concomitant quantification of pro-inflammatory and pro-resolving polyunsaturated fatty acid metabolites. PubMed: DFT investigations for the reaction mechanism of dimethyl carbonate synthesis on Pd(II)/β zeolites. PubMed: Mechanisms of lactone hydrolysis in neutral and alkaline conditions. PubMed: Mechanisms of lactone hydrolysis in acidic conditions. PubMed: Accurate treatment of two-dimensional non-separable hindered internal rotors. PubMed: Photocatalytic cross-coupling of methanol and formaldehyde on a rutile TiO2(110) surface. PubMed: An exchangeable-tip scanning probe instrument for the analysis of combinatorial libraries of electrocatalysts. PubMed: Sequential photo-oxidation of methanol to methyl formate on TiO2(110). PubMed: Influence of the O-protonation in the O═C-O-Me Z preference. A QTAIM study. PubMed: High-temperature measurements of the reactions of OH with small methyl esters: methyl formate, methyl acetate, methyl propanoate, and methyl butanoate. PubMed: Synchrotron FTIR spectroscopy of weak torsional bands: a case study of cis-methyl formate. PubMed: Ab initio reaction kinetics of hydrogen abstraction from methyl formate by hydrogen, methyl, oxygen, hydroxyl, and hydroperoxy radicals. PubMed: Spontaneous electric fields in films of cis-methyl formate. PubMed: Computational mechanistic study of the hydrogenation of carbonate to methanol catalyzed by the Ru(II)PNN complex. PubMed: Volatile compounds and sensory analysis of both harvests of double-cut Yakima peppermint (Mentha piperita L.). PubMed: Dissociative electron-ion recombination of the interstellar species protonated glycolaldehyde, acetic acid, and methyl formate. PubMed: Transient Ru-methyl formate intermediates generated with bifunctional transfer hydrogenation catalysts. PubMed: Mechanistic investigations on dimethyl carbonate formation by oxidative carbonylation of methanol over a CuY zeolite: an operando SSITKA/DRIFTS/MS study. PubMed: Methyl 2,2'-dimethyl-4'-[2-(methyl-sulfan-yl)eth-yl]-1,3-dioxo-2,3-dihydro-1H,4'H-spiro-[isoquinoline-4,5'-oxazole]-4'-carboxyl-ate. PubMed: Carbonylation of nitrobenzene in methanol with palladium bidentate phosphane complexes: an unexpectedly complex network of catalytic reactions, centred around a Pd-imido intermediate. PubMed: Acute airway irritation of methyl formate in mice. PubMed: Quantifying temperature and flow rate effects on the performance of a fixed-bed chromatographic reactor. PubMed: Structure of complexes formed by dissolution of palladium diacetate in methanol and chloroform. In situ NMR study. PubMed: Methyl formate and its mono and difluoro derivatives: conformational manifolds, basicity, and interaction with HF theoretical investigation. PubMed: Potential energy surface and rotational cross sections for methyl formate colliding with helium. PubMed: [Spectralsignatures of nickel and vanadium supported photocatalysts and their photocatalytic properties]. PubMed: Thermal decomposition of methyl 2-azidopropionate studied by UV photoelectron spectroscopy and matrix isolation IR spectroscopy: heterocyclic intermediate vs imine formation. PubMed: Spatial distributions and interstellar reaction processes. PubMed: Effect of ionization on infrared and electronic absorption spectra of methyl and ethyl formate in the gas phase and in astrophysical H2O ice: a computational study. PubMed: Fuel-specific influences on the composition of reaction intermediates in premixed flames of three C5H10O2 ester isomers. PubMed: Molecular elimination of methyl formate in photolysis at 234 nm: roaming vs. transition state-type mechanism. PubMed: Magnetic hyperfine coupling of a methyl group undergoing internal rotation: a case study of methyl formate. PubMed: The effect of chemical surface treatments on the flexural strength of repaired acrylic denture base resin. PubMed: On the temperature dependence of flammability limits of gases. PubMed: Photocatalytic reduction of CO2 in methanol to methyl formate over CuO-TiO2 composite catalysts. PubMed: Atmospheric chemistry of C2F5CH2OCH3 (HFE-365mcf). PubMed: Elevated formic acid concentrations in putrefied post-mortem blood and urine samples. PubMed: Product study of the OH radical and Cl atom initiated oxidation of 1,3-dioxane. PubMed: A Study of Micronucleus Induction with Methyl Formate and 2-Methylbutane in Bone Marrow Cells of Male ICR Mice. PubMed: Electronic state spectroscopy of methyl formate probed by high resolution VUV photoabsorption, He(i) photoelectron spectroscopy and ab initio calculations. PubMed: Reactivity of heteropolytungstate and heteropolymolybdate metal transition salts in the synthesis of dimethyl carbonate from methanol and CO₂. PubMed: Ab initio chemical kinetics of methyl formate decomposition: the simplest model biodiesel. PubMed: Guaiane sesquiterpenes from seaweed Ulva fasciata Delile and their antibacterial properties. PubMed: Insights into the mechanistic photodissociation of methyl formate. PubMed: Nanoporous gold catalysts for selective gas-phase oxidative coupling of methanol at low temperature. PubMed: Removal of high concentration dimethyl methylphosphonate in the gas phase by repeated-batch reactions using TiO2. PubMed: Binuclear TiOMn charge-transfer chromophore in mesoporous silica. PubMed: Metabolism and cometabolism of cyclic ethers by a filamentous fungus, a Graphium sp. PubMed: Methanol electrooxidation on PtRu bulk alloys and carbon-supported PtRu nanoparticle catalysts: a quantitative DEMS study. PubMed: N-formylation of amines via the aerobic oxidation of methanol over supported gold nanoparticles. PubMed: Selectivity control in gold-mediated esterification of methanol. PubMed: Gas-phase fragmentation of protonated C60-pyrimidine derivatives. PubMed: Flow through reactors for organic chemistry: directly electrically heated tubular mini reactors as an enabling technology for organic synthesis. PubMed: Analysis of potassium formate in airport storm water runoff by headspace solid-phase microextraction and gas chromatography-mass spectrometry. PubMed: Photodissociation dynamics of methyl formate at 193.3 nm: Branching ratios, kinetic-energy distributions, and angular anisotropies of products. PubMed: Molecular dynamics prediction of the mechanism of ester hydrolysis in water. PubMed: Photochemical study of the transport properties of gases in polymer films. PubMed: A study on flammability limits of fuel mixtures. PubMed: Biodiesel production by supercritical process with crude bio-methanol prepared by wood gasification. PubMed: Improved efficiency of focal point conformational analysis with truncated correlation consistent basis sets. PubMed: Catalytic oxidation of methanol on Pd metal and oxide clusters at near-ambient temperatures. PubMed: The relationship of methanol and formate concentrations in fatalities where methanol is detected. PubMed: Methanol oxidation using ozone on titania-supported vanadia catalyst. PubMed: Towards predictive inhibitor design for the EGFR autophosphorylation activity. PubMed: Carbon dioxide fixation into chemicals (methyl formate) at high yields by surface coupling over a Pd/Cu/ZnO nanocatalyst. PubMed: Conformational equilibria in formic acid and the adduct of formic acid and hexafluoroacetone, HCO2C(CF3)2OH. PubMed: Solvent type affects the number, distribution, and relative quantities of volatile compounds found in sweet whey powder. PubMed: Sevoflurane breakdown produces flammable concentrations of hydrogen. PubMed: Structures and properties of zirconia-supported ruthenium oxide catalysts for the selective oxidation of methanol to methyl formate. PubMed: On gas phase alpha-effects. 1. The gas-phase manifestation and potential SET character. PubMed: Interferometric observations of large biologically interesting interstellar and cometary molecules. PubMed: Photocatalytic oxidation of methyl ethyl ketone over sol-gel and commercial TiO2 for the improvement of indoor air. PubMed: Active control of methanol carbonylation selectivity over Au/carbon anode by electrochemical potential. PubMed: Collision-energy-resolved penning ionization electron spectroscopy of HCOOH, CH3COOH, and HCOOCH3 by collision with He*(2(3)S) metastable atoms. PubMed: Extended Le Chatelier's formula for carbon dioxide dilution effect on flammability limits. PubMed: Recognition of small polar molecules with an ionic crystal of alpha-Keggin-type polyoxometalate with a macrocation. PubMed: Solvent effects on the structural and formyl substrate reactivity properties of a nitrogen/sulfur-ligated zinc hydroxide complex. PubMed: Production of methyl-oxonium ion and its complexes in the core-excited (HC(O)OCH3)n clusters: H/H+ transfer from the alpha carbonyl. PubMed: Mechanism of the aminolysis of methyl benzoate: a computational study. PubMed: Dimethyl ether oxidation at elevated temperatures (295-600 K). PubMed: Some basic parameters of microspheres fabricated from a branched oligoester by a rapid procedure. PubMed: Multiple isotope effect study of the acid-catalyzed hydrolysis of methyl formate. PubMed: Electrochemical oxidation of methanol using dppm-bridged Ru/Pd, Ru/Pt and Ru/Au catalysts. PubMed: [Hygienic standards of the occupational air quality established by the Experts on Chemical Agents, 2002]. PubMed: Synthesis of porritoxin. PubMed: Alcohol dehydrogenases that catalyse methyl formate synthesis participate in formaldehyde detoxification in the methylotrophic yeast Candida boidinii. PubMed: Effect of oil substitution in chiral microemulsion electrokinetic chromatography. PubMed: [Diagnostic importance of formic acid detection in methyl alcohol poisoning]. PubMed: Photocatalytic oxidation of gaseous 2-chloroethyl ethyl sulfide over TiO2. PubMed: Mechanistic study of the gas-phase decomposition of methyl formate. PubMed: Post-mortem analysis of formic acid disposition in acute methanol intoxication. PubMed: In situ FTIR studies on the effect of temperature on the electro-oxidation of small organic molecules at the Ru(0001) electrode. PubMed: Metal-catalyzed silacyclopropanation of mono- and disubstituted alkenes. PubMed: A theoretical analysis of the free-energy profile of the different pathways in the alkaline hydrolysis of methyl formate in aqueous solution. PubMed: Hydroxide as general base in the saponification of ethyl acetate. PubMed: Methyl rotational barriers in amides and thioamides. PubMed: Ellipsometric study of undersaturated critical adsorption. PubMed: Synthesis, structure, and reactions of (acylimino)triaryl-lambda(5)-bismuthanes: first comparative study of the (acylimino)pnictorane series. PubMed: Barriers to rotation in methyl formate by dynamic NMR spectroscopy and barriers to 1,3 oxygen-to-oxygen migration in methyl formate and trifluoromethyl formate by ab initio calculations. PubMed: Verification of NEXAFS assignments by a comparison of fragmentation between gaseous and condensed methyl formate. PubMed: Multiple isotope effects on the acyl group transfer reactions of amides and esters. PubMed: Formate species in the low-temperature oxidation of dimethyl ether. PubMed: The gas-phase reaction between hydroxide ion and methyl formate: a theoretical analysis of the energy surface and product distribution. PubMed: Solvent effects on oxygen-17 chemical shifts in methyl formate: linear solvation shift relationships. PubMed: Isopropanol and methylformate exposure in a foundry: exposure data and neurobehavioural measurements. PubMed: Toxicokinetic modelling of methyl formate exposure and implications for biological monitoring. PubMed: Branched oligoester microspheres fabricated by a rapid emulsion solvent extraction method. PubMed: Urinary methanol and formic acid as indicators of occupational exposure to methyl formate. PubMed: Experimental exposure to methylformate and its neurobehavioral effects. PubMed: Substitutes for methylene chloride as dental softening agent. PubMed: Growth of Candida boidinii on methanol and the activity of methanol-degrading enzymes as affected from formaldehyde and methylformate. PubMed: Analysis of methanol or formic acid in body fluids by headspace solid-phase microextraction and capillary gas chromatography. PubMed: Hemiacetal dehydrogenation activity of alcohol dehydrogenases in Saccharomyces cerevisiae. PubMed: Ester synthesis by NAD(+)-dependent dehydrogenation of hemiacetal: production of methyl formate by cells of methylotrophic yeasts. PubMed: Purification and properties of methyl formate synthase, a mitochondrial alcohol dehydrogenase, participating in formaldehyde oxidation in methylotrophic yeasts. PubMed: Oxidative cleavage of esters and amides to carbonyl products by cytochrome P450. PubMed: A novel formaldehyde oxidation pathway in methylotrophic yeasts: methylformate as a possible intermediate. PubMed: Insertion reactions of metal carbonyl anions with methyl formate in the gas phase as revealed by (13)C- and D-labeling. PubMed: The spectrum of Orion-KL at 2 millimeters (150-160 GHz). PubMed: Interferometric observations for oxygen-containing organic molecules toward Orion-KL. PubMed: Dye-linked dehydrogenase activities for formate and formate esters in Amycolatopsis methanolica. Characterization of a molybdoprotein enzyme active with formate esters and aldehydes. PubMed: Determination of prostaglandins in human seminal fluid by solid-phase extraction, pyridinium dichromate derivatization and high-performance liquid chromatography. PubMed: Observations of some oxygen-containing and sulfur-containing organic molecules in cold dark clouds. PubMed: In vivo enzymology: a deuterium NMR study of formaldehyde dismutase in Pseudomonas putida F61a and Staphylococcus aureus. PubMed: Seed Dormancy in Red Rice : VII. Structure-Activity Studies of Germination Stimulants. PubMed: Gas chromatographic analysis of methyl formate and application in methanol poisoning cases. PubMed: Rapid quantification of 11 prostanoids by combined capillary column gas chromatography and negative ion chemical ionization mass spectrometry: application to prostanoids released from normal human embryonic lung fibroblasts WI38 in a culture medium. PubMed: Polymerization of phenols catalyzed by peroxidase in nonaqueous media. PubMed: Determination of 2,3-dinor-6-ketoprostaglandin F1 alpha in urine samples by liquid chromatography and radioimmunoassay. PubMed: Studies on the decomposition of the oxime HI 6 in aqueous solution. PubMed: Peroxidases depolymerize lignin in organic media but not in water. PubMed: Proposed structure for the noncovalently associated heme prosthetic group of dissimilatory nitrite reductases. Configuration of substituents of acrylochlorin. PubMed: Simultaneous extraction and preparation for high-performance liquid chromatography of prostaglandins and phospholipids. PubMed: Measurement of human venous plasma prostacyclin and metabolites by radioimmunoassay: a reappraisal. PubMed: Factors influencing the resistance of biological monitors to ethylene oxide. PubMed: Rapid extraction of oxygenated metabolites of arachidonic acid from biological samples using octadecylsilyl silica. PubMed: Gas chromatographic head-space assay of formic acid as methyl formate in biologic fluids: potential application to methanol poisoning. PubMed: Sorption processes in gas sterilization in the medical sector.