dicyclopentadiene

3a,4,7,7a-tetrahydro-4,7-methanoindene

CAS: 77-73-6 C10 H12 MW: 132.20564000

Identification

Namedicyclopentadiene
CAS Number77-73-6
EINECS201-052-9
FDA UNIISearch
Molecular FormulaC10 H12
Molecular Weight132.20564000
MDL NumberMFCD00078246
Nikkaji NumberJ9.241J
Beilstein1904092

Regulatory

DG SANTE Food Contact Materialsdicyclopentadiene
FDA Mainterm (IAUFC)77-73-6 ; DICYCLOPENTADIENE

Physical Properties

Appearance colorless to pale yellow clear liquid (est)
Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Melting Point -1.00 °C. @ 760.00 mm Hg
Boiling Point 170.00 °C. @ 760.00 mm Hg
Vapor Pressure 2.000000 mmHg @ 25.00 °C. (est)
Vapor Density 4.55 ( Air = 1 )
Flash Point 116.00 °F. TCC ( 46.80 °C. ) (est)
logP (o/w) 3.300 (est)
Soluble in water, 51.88 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral Toxicityoral-cattle LD50 1200 mg/kg
Dermal Toxicityskin-rabbit LD50 5080 mg/kg
Inhalation Toxicityinhalation-dog LCLo 773 ppm/1H

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryindirect food additives: adhesives and components of coatings
Recommendation for dicyclopentadiene usage levels up tonot for fragrance use.
Recommendation for dicyclopentadiene flavor usage levels up tonot for flavor use.

Penta International Corporation

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At Penta, our products and services help businesses do business better.

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Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

bicyclopentadiene biscyclopentadiene 1,3- CPD cyclopentadiene dimer 1,3- cyclopentadiene, dimer DCPD alpha- dicyclopentadiene (endo form) dicyclopentadiene [UN2048] [Flammable liquid] dicyklopentadien 4,7- methano-1H-indene, 3a,4,7,7a-tetrahydro- 4,7- methanoindene, 3a,4,7,7a-tetrahydro- prometa XP 100 3a,4,7,7a- tetrahydro-4,7-methanoindene tricyclo(5.2.1.0)-3,8-decadiene US Patents: 8,080,691 - Organoleptic compounds PubMed: Macroporous ZnO foams by high internal phase emulsion technique: synthesis and catalytic activity. US Patents: Polycyclic lactones as odor- and taste-modifying agents PubMed: Polylactic acid with improved heat deflection temperatures and self-healing properties for durable goods applications. PubMed: Chelating ruthenium phenolate complexes: synthesis, general catalytic activity, and applications in olefin metathesis polymerization. PubMed: Nanocomposite foams from iron oxide stabilized dicyclopentadiene high internal phase emulsions: preparation and bromination. PubMed: The infinite possible growth ambients that support single-wall carbon nanotube forest growth. PubMed: Controlling the femtosecond laser-driven transformation of dicyclopentadiene into cyclopentadiene. PubMed: Deterministic control over high-Z doping of polydicyclopentadiene-based aerogel coatings. PubMed: Phase separation polymerization of dicyclopentadiene characterized by in operando fluorescence microscopy. PubMed: Ring Opening Metathesis Polymerisation (ROMP) as a tool for polyHIPes with extraordinary mechanical properties. PubMed: Inverse electron demand Diels-Alder (iEDDA) functionalisation of macroporous poly(dicyclopentadiene) foams. PubMed: The use of an emulsion templated microcellular poly(dicyclopentadiene-co-norbornene) membrane as a separator in lithium-ion batteries. PubMed: Separation of cis-fatty acids from saturated and trans-fatty acids by nanoporous polydicyclopentadiene membranes. PubMed: Theoretical study on cyclopropanation of endo-dicyclopentadiene with zinc carbenoids: effects of solvent and (ICH2)2Zn. PubMed: Results of a 90-day inhalation study of dicyclopentadiene in B6C3F1 mice. PubMed: Metal-cation-based anion exchange membranes. PubMed: Homogeneous vs heterogeneous polymerization catalysis revealed by single-particle fluorescence microscopy. PubMed: Reusable biocatalytic crosslinked microparticles self-assembled from enzyme-nanoparticle complexes. PubMed: Retention of palladium and phosphine ligands using nanoporous polydicyclopentadiene thimbles. PubMed: Control of femtosecond laser driven retro-Diels-Alder-like reaction of dicyclopentadiene. PubMed: Adhesion promotion via noncovalent interactions in self-healing polymers. PubMed: Synthesis of molecularly imprinted polymers via ring-opening metathesis polymerization for solid-phase extraction of bisphenol A. PubMed: Silica-protected micron and sub-micron capsules and particles for self-healing at the microscale. PubMed: Ruthenium-indenylidene olefin metathesis catalyst with enhanced thermal stability. PubMed: Inherently reactive polyHIPE material from dicyclopentadiene. PubMed: Polymerization of monomer-based ferrofluids. PubMed: Kinetics of liquid phase catalytic hydrogenation of dicyclopentadiene over Pd/C catalyst. PubMed: A ring-opening metathesis polymerization route to alkaline anion exchange membranes: development of hydroxide-conducting thin films from an ammonium-functionalized monomer. PubMed: A room-temperature autonomically-healing PMMA bone cement: influence of composition on fatigue crack propagation rate. PubMed: Diffusion and flow across nanoporous polydicyclopentadiene-based membranes. PubMed: Assembly of organic monolayers on polydicyclopentadiene. PubMed: Study of the adsorption of organic molecules on transition metal exchanged zeolites via solid state NMR. Part 2: adsorption of organic molecules on zeolite NaX, CaX, and CaCoX. PubMed: Metal-mediated retro Diels-Alder of dicyclopentadiene derivatives: a convenient synthesis of [(Cp-R)M(CO)3] (M = 99mTc, Re) complexes. PubMed: High-load, oligomeric monoamine hydrochloride: Facile generation via ROM polymerization and application as an electrophile scavenger. PubMed: Cascade reactions using LiAlH4 and grignard reagents in the presence of water. PubMed: Cationic scandium aminobenzyl complexes. Synthesis, structure and unprecedented catalysis of copolymerization of 1-hexene and dicyclopentadiene. PubMed: A new self-healing epoxy with tungsten (VI) chloride catalyst. PubMed: Self-healing kinetics and the stereoisomers of dicyclopentadiene. PubMed: Life extension of self-healing polymers with rapidly growing fatigue cracks. PubMed: Binuclear half-sandwich cobalt(III) and rhodium(III) ortho-carboranedichalocogenolato complexes with ether chain-bridged bis(cyclopentadienyl) ligand. PubMed: Simultaneous determination of methyl tert-butyl ether, its degradation products and other gasoline additives in soil samples by closed-system purge-and-trap gas chromatography-mass spectrometry. PubMed: Photoinduced electron transfer in ionic liquids: use of 2,4,6-triphenylthiapyrylium as a photosensitizer probe. PubMed: Semi-quantitative immunohistochemical analysis of male rat-specific alpha2u-globulin accumulation for chemical toxicity evaluation. PubMed: Novel rubbers from cationic copolymerization of soybean oils and dicyclopentadiene. 1. Synthesis and characterization. PubMed: Fate of gasoline oxygenates in conventional and multilevel wells of a contaminated groundwater table in Düsseldorf, Germany. PubMed: Identification of hydrocarbon-degrading bacteria in soil by reverse sample genome probing. PubMed: Raman spectroscopic studies of the cure of dicyclopentadiene (DCPD). PubMed: Biodegradation of C5+ hydrocarbons by a mixed bacterial consortium from a C(5+)-contaminated site. PubMed: [Hygienic standards of the occupational air quality established by the Experts on Chemical Agents, 2002]. PubMed: Synthesis, structure, and dynamics of nickelacarboranes incorporating the [nido-7,9-C(2)B(9)H(11)](2)(-) ligand. PubMed: Glycosylthiomethyl chloride: a new species for S-neoglycoconjugate synthesis. Synthesis of 1-N-glycosylthiomethyl-1,2,3-triazoles. PubMed: [Gas chromatographic detection of dicyclopentadiene in workplace air]. PubMed: In situ poly(urea-formaldehyde) microencapsulation of dicyclopentadiene. PubMed: Fate of MTBE and DCPD compounds relative to BTEX in gasoline-contaminated aquifers. PubMed: [Analysis of C5 fractions and carbonyl compounds by capillary gas chromatography]. PubMed: Preparation and cell growth inhibitory activity of [PtR(2)L(2)] (R=polyfluorophenyl, L(2)=diene, cyclohexane-1,2-diamine (chxn) or cis-(dimethyl sulfoxide)(2)) and the X-ray crystal structure of [Pt(C(6)F(5))(2)(cis-chxn)]. PubMed: Microbial community composition at an ethane pyrolysis plant site at different hydrocarbon inputs. PubMed: Allergic contact dermatitis from unsaturated polyester resin consisting of maleic anhydride, phthalic anhydride, ethylene glycol and dicyclopentadiene. PubMed: Copper(I)-catalyzed [2 + 2] photocycloadditions with tethered linkers: synthesis of syn-photodimers of dicyclopentadienes. PubMed: Composition of soil microbial communities enriched on a mixture of aromatic hydrocarbons. PubMed: Catalytic asymmetrization of racemic dicyclopentadiene derivatives by using chiral copper(II) catalyst PubMed: Biodegradation of dicyclopentadiene in the field. PubMed: [Gas chromatographic determination of dicyclopentadiene in the work area air]. PubMed: In vitro degradation of dicyclopentadiene by microbial consortia isolated from hydrocarbon-contaminated soil. PubMed: Subchronic toxicity study of dicyclopentadiene vapor in rats. PubMed: [Hygienic analysis of the experience in dicyclopentadiene production from petrochemical raw materials]. PubMed: [Twenty-eight day repeated dose toxicity test of dicyclopentadiene in F344 rat]. PubMed: [The role of construction materials as secondary sources of the air pollution of manufacturing premises with dicyclopentadiene]. PubMed: [Protection of the respiratory organs in production of dicyclopentadiene]. PubMed: [Index of functional discoordination as a criterion of hazardousness for exposure to toxic chemicals]. PubMed: Derivatives of dicyclopentadiene in ground water. PubMed: [Establishment of the maximum permissible concentrations of norbornene, norbornadiene and dicyclopentadiene in reservoir water]. PubMed: In vivo skeletal localization properties of 99mTc complexes of large phosphonate ligands. PubMed: [Gas chromatographic determination of dicyclopentadiene in the air]. PubMed: Mutagenic activity associated with by-products of drinking water disinfection by chlorine, chlorine dioxide, ozone and UV-irradiation. PubMed: Toxicologic evaluation of diisopropyl methylphosphonate and dicyclopentadiene in cattle. PubMed: Fate of dicyclopentadiene in a lactating cow. PubMed: Testing of twenty-one environmental aromatic amines or derivatives for long-term toxicity or carcinogenicity. PubMed: Biological active polycycloalkanes. 4. Phosphoric esters of trimethylenenorbornyl alcohols. PubMed: [Separate determination of indene, coumarone, styrol, cyclopentadiene and dicyclopentadiene in the air by thin-layer chromatography]. PubMed: The mammalian toxicity of dicyclopentadiene. PubMed: [Materials for substantiation of maximum permissible concentration of cyclopentadiene and of its dimer-dicyclopentadiene in the atmosphere of industrial premises]. PubMed: On the addition of formic acid to dicyclopentadiene.