2,4-hexadien-1-ol

2,4-hexadienol

CAS: 111-28-4 C6 H10 O MW: 98.14490000 green fruity

Identification

Name2,4-hexadien-1-ol
CAS Number111-28-4
EINECS203-853-9
FDA UNII11CF2E3HNG
Molecular FormulaC6 H10 O
Molecular Weight98.14490000
MDL NumberMFCD00002925
CoE Number2162

Regulatory

JECFA Food Flavoring1174 2,4-hexadien-1-ol
DG SANTE Food Flavourings02.162 hexa-2,4-dien-1-ol
FEMA Number3922
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)111-28-4 ; 2,4-HEXADIEN-1-OL

Physical Properties

Appearance colorless solid (est)
Assay 98.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 0.88000 to 0.90000 @ 25.00 °C.
Pounds per Gallon - (est). 7.322 to 7.489
Refractive Index 1.49000 to 1.51000 @ 20.00 °C.
Melting Point 24.00 to 33.00 °C. @ 760.00 mm Hg
Boiling Point 90.00 °C. @ 20.00 mm Hg, 179.00 to 180.00 °C. @ 760.00 mm Hg
Vapor Pressure 0.281000 mmHg @ 25.00 °C. (est)
Vapor Density >1 ( Air = 1 )
Flash Point 160.00 °F. TCC ( 71.11 °C. )
logP (o/w) 1.083 (est)
Soluble in alcohol

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength medium ,
Substantivity > 1 hour(s) at 100.00 %
Odor Description
at 10.00 % in dipropylene glycol.
at 1.00 %.
fresh green, pineapple herbal
Taste Description
at 10.00 - 40.00 ppm.
fruity

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral Toxicityoral-rat LD50 2140 uL/kg
Dermal Toxicityskin-human TDLo 14 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavoring agents and cosmetic fragrance agents
IFRA Critical EffectInsufficient data
Recommendation for 2,4-hexadien-1-ol usage levels up toPROHIBITED: Should not be used as a fragrance ingredient.
Maximised Survey-derived Daily Intakes (MSDI-EU)0.0012 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)0.40 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI)500 (μg/person/day)
Threshold of Concern1800 (μg/person/day)
Structure ClassI
baked goods-
beverages(nonalcoholic)1.00000
beverages(alcoholic)0.50000
breakfast cereal-
cheese-
chewing gum-
condiments / relishes2.00000
confectionery froastings0.10000
egg products-
fats / oils-
fish products-
frozen dairy2.00000
fruit ices-
gelatins / puddings0.70000
granulated sugar0.07300
gravies0.30000
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies1.00000
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors0.10000
snack foods0.40000
soft candy1.00000
soups0.13000
sugar substitutes-
sweet sauces-
Dairy products, excluding products of category 02.0 (01.0)-
Fats and oils, and fat emulsions (type water-in-oil) (02.0)-
Edible ices, including sherbet and sorbet (03.0)1.00000
Processed fruit (04.1)-
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2)0.50000
Confectionery (05.0)0.50000
Chewing gum (05.3)-
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0)-
Bakery wares (07.0)-
Meat and meat products, including poultry and game (08.0)-
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0)-
Eggs and egg products (10.0)-
Sweeteners, including honey (11.0)-
Salts, spices, soups, sauces, salads, protein products, etc. (12.0)1.00000
Foodstuffs intended for particular nutritional uses (13.0)-
Non-alcoholic ("soft") beverages, excl. dairy products (14.1)1.00000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2)0.20000
Ready-to-eat savouries (15.0)0.10000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0)0.50000

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Potential Uses

FL almond FL apple FL asparagus fresh FL green FL herbal FL kiwi FL mango FL nut FL pear FL pineapple

Natural Occurrence

aloe arborescens mill. var. natalensis berger asparagus asparagus cooked asparagus naranjilla fruit soybean plant

Synonyms

hexa-2,4-dien-1-ol 2,4- hexadien-1-ol 2,4- hexadien-1-ol (sorbic alcohol) 2,4- hexadieneol 2,4- hexadienol 1- hydroxy-2,4-hexadiene mimoril sorbic alcohol sorbinic alcohol sorbyl alcohol PubMed: Synthesis of all-cis 2,5-imino-2,5-dideoxy-fucitol and its evaluation as a potent fucosidase and galactosidase inhibitor. PubMed: The acyl nitroso Diels-Alder (ANDA) reaction of sorbate derivatives: an X-ray and 15N NMR study with an application to amino-acid synthesis. PubMed: Aryl-alcohol oxidase involved in lignin degradation: a mechanistic study based on steady and pre-steady state kinetics and primary and solvent isotope effects with two alcohol substrates. PubMed: Catalytic enantioselective Diels-Alder reaction by self-assembly of the components on a Lewis acid template. PubMed: Spectral and catalytic properties of aryl-alcohol oxidase, a fungal flavoenzyme acting on polyunsaturated alcohols. PubMed: Micellar catalysis of Diels-Alder reactions: substrate positioning in the micelle. PubMed: Reactions of hydro(pero)xy derivatives of polyunsaturated fatty acids/esters with nitrite ions under acidic conditions. Unusual nitrosative breakdown of methyl 13-hydro(pero)xyoctadeca-9,11-dienoate to a novel 4-nitro-2-oximinoalk-3-enal product. PubMed: Intramolecular diels-alder reaction by self-assembly of the components on a lewis acid template PubMed: Purification and properties of methanol dehydrogenase from Methylosinus sp. WI 14. PubMed: Protective effect of topically applied conjugated hexadienes against ultraviolet radiation-induced chronic skin damage in the hairless mouse.