Identification

Namehexyl valerate
IUPAChexyl pentanoate
CAS Number1117-59-5
EINECS214-248-4
FDA UNII4223QQU9RL
Molecular FormulaC11 H22 O2
Molecular Weight186.29474000
MDL NumberMFCD00053807
Nikkaji NumberJ184.201C
Beilstein1760230
CoE Number10696

Regulatory

DG SANTE Food Flavourings09.583 hexyl valerate

Physical Properties

Appearance colorless clear liquid (est)
Assay 98.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 0.86000 to 0.86500 @ 20.00 °C.
Pounds per Gallon - (est). 7.164 to 7.206
Refractive Index 1.41800 to 1.42400 @ 20.00 °C.
Melting Point -63.10 °C. @ 760.00 mm Hg
Boiling Point 226.00 to 227.00 °C. @ 760.00 mm Hg
Vapor Pressure 0.090000 mmHg @ 25.00 °C. (est)
Flash Point 190.00 °F. TCC ( 87.78 °C. )
logP (o/w) 4.352 (est)
Shelf Life 12.00 month(s) or longer if stored properly.
Storage store under nitrogen., refrigerate in tightly sealed containers. store under nitrogen.
Soluble in alcohol
Insoluble in water
Similar Items note

Organoleptic Properties

Odor Description oily fruity green brandy

Safety Information

Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for hexyl valerate usage levels up to4.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)0.79 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI)3900 (μg/person/day)
Threshold of Concern1800 (μg/person/day)
Structure ClassI
Dairy products, excluding products of category 02.0 (01.0)7.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0)5.00000
Edible ices, including sherbet and sorbet (03.0)10.00000
Processed fruit (04.1)7.00000
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2)-
Confectionery (05.0)10.00000
Chewing gum (05.3)-
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0)5.00000
Bakery wares (07.0)10.00000
Meat and meat products, including poultry and game (08.0)2.00000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0)2.00000
Eggs and egg products (10.0)-
Sweeteners, including honey (11.0)-
Salts, spices, soups, sauces, salads, protein products, etc. (12.0)5.00000
Foodstuffs intended for particular nutritional uses (13.0)10.00000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1)5.00000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2)10.00000
Ready-to-eat savouries (15.0)20.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0)5.00000

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Potential Uses

None Found

Natural Occurrence

lavender oil spike spain @ 0.19% Data osmanthus absolute @ trace% Data plum fruit salvia atropatana bunge oil iran @ 4.60% Data

Synonyms

hexyl n-valerate 1- hexyl N-valerate hexyl pentanoate hexyl valerianate hexyl-valerate pentanoic acid hexyl ester pentanoic acid, hexyl ester valeric acid hexyl ester valeric acid, hexyl ester PubMed: Identification of potent odourants in wine and brewed coffee using gas chromatography-olfactometry and comprehensive two-dimensional gas chromatography. PubMed: The teratogenic potencies of valproic acid derivatives and their effects on biological end-points are related to changes in histone deacetylase and Erk1/2 activities. PubMed: Comparison of volatile components in Chinese traditional pickled peppers using HS-SPME-GC-MS, GC-O and multivariate analysis. PubMed: Potent neuroprotective effects of novel structural derivatives of valproic acid: potential roles of HDAC inhibition and HSP70 induction. PubMed: Toxicities of 31 volatile low molecular weight compounds against Aedes aegypti and Culex quinquefasciatus. PubMed: A sensitive liquid chromatographic method for the analysis of isovaleric and valeric acids in urine as fluorescent derivatives. PubMed: Metabolism of sameridine to monocarboxylated products by hepatocytes isolated from the male rat. PubMed: Biosynthesis of straight-chain ester volatiles in red delicious and granny smith apples using deuterium-labeled precursors. PubMed: Enhanced sensitivity to androstenone following regular exposure to pemenone. PubMed: Substrate and inhibitor specificity of mevalonate kinase determined with substrate analogues. PubMed: Stereoselective conjugation of 2-bromocarboxylic acids and their urea derivatives by rat liver glutathione transferase 12-12 and some other isoforms. PubMed: Pharmacokinetic analysis of ester prodrugs of valproic acid. PubMed: Chain length dependency of fatty acid and carbamate binding to serum albumin. PubMed: Fatty acid omega and (omega-1)-Hydroxylation in rabbit intestinal mucosa microsomes.