dimethyl anthranilate
methyl N-methylanthranilate
Identification
| Name | dimethyl anthranilate |
| IUPAC | methyl 2-methylaminobenzoate |
| CAS Number | 85-91-6 |
| EINECS | 201-642-6 |
| FDA UNII | 5Z37T562P9 |
| Molecular Formula | C9 H11 N O2 |
| Molecular Weight | 165.19207000 |
| MDL Number | MFCD00017183 |
| Nikkaji Number | J2.411B |
| Beilstein | 0607217 |
| CoE Number | 756 |
| XlogP3 | 2.30 (est) |
Regulatory
| JECFA Food Flavoring | 1545 methyl N-methylanthranilate |
| DG SANTE Food Flavourings | 09.781 methyl N-methylanthranilate |
| FEMA Number | 2718 |
| FDA | No longer provide for the use of these seven synthetic flavoring substances |
| FDA Mainterm (SATF) | 85-91-6 ; METHYL N-METHYLANTHRANILATE |
| FDA Regulation | FDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION |
Physical Properties
| Appearance | pale yellow to amber clear liquid to solid (est) |
| Assay | 98.00 to 100.00 sum of isomers |
| Food Chemicals Codex Listed | Yes |
| Specific Gravity | 1.12500 to 1.13000 @ 25.00 °C. |
| Pounds per Gallon - (est). | 9.361 to 9.403 |
| Refractive Index | 1.57900 to 1.58100 @ 20.00 °C. |
| Melting Point | 17.00 to 19.00 °C. @ 760.00 mm Hg |
| Boiling Point | 255.00 to 256.00 °C. @ 760.00 mm Hg, 130.00 to 131.00 °C. @ 13.00 mm Hg |
| Congealing Point | 12.00 °C. |
| Acid Value | 1.00 max. KOH/g |
| Vapor Pressure | 0.007000 mmHg @ 25.00 °C. (est) |
| Vapor Density | >1 ( Air = 1 ) |
| Flash Point | > 230.00 °F. TCC ( > 110.00 °C. ) |
| logP (o/w) | 2.531 (est) |
| Shelf Life | 24.00 month(s) or longer if stored properly. |
| Storage | store in cool, dry place in tightly sealed containers, protected from heat and light. |
| Soluble in | alcohol |
| Insoluble in | glycerin |
| Stability | bath foam |
Organoleptic Properties
| Odor Strength | medium |
| Substantivity | 48 hour(s) at 100.00 % |
| Odor Description |
at 100.00 %. Sweet, fruity anthranilate-like with a clean fresh floral nuance Orange blossom and grape-like Orange flower, Mandarine, Neroli
|
| Odor sample from | Harrmann & Reimer Corporation |
| Taste Description |
at 10.00 ppm. fruity grape musty fruity grape berry citrus mandarin
|
Safety Information
| Preferred SDS | View |
| European information | Most important hazard(s): |
| Human Experience | 10 % solution: no irritation or sensitization. |
| Oral/Parenteral Toxicity | oral-rat LD50 3380 mg/kg |
| Dermal Toxicity | skin-rabbit LD50 5000 mg/kg |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements', 'U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#07000', 'U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#07000']
Safety in Use
| Category | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment | Search |
| IFRA Critical Effect | Phototoxicity and potential for nitrosam |
| fragrance material specification | For applications on areas of the skin exposed to sunlight, excluding bath preparations, soaps and other wash-off products, limit to 10% in the finished cosmetic product. Based on the phototoxic potential and on the observed no-effect level of approximately 2 mg/cm2 of the hairless mouse (Food and Chemical Toxicology 17, 273 (1979)). The material has been identified for having the potential of forming nitrosamines in nitrosating systems. Downstream users therefore have to be notified of the presence of the material and its potential to be able to consider adequate protective measures. |
| IFRA RESTRICTION LIMITS IN THE FINISHED PRODUCT (%) | Category 1: Products applied to the lips |
| Notes | IFRA FLAVOR REQUIREMENTS: |
| Maximised Survey-derived Daily Intakes (MSDI-EU) | 51.00 (μg/capita/day) |
| Maximised Survey-derived Daily Intakes (MSDI-USA) | 120.00 (μg/capita/day) |
| Threshold of Concern | 1800 (μg/person/day) |
| baked goods | - |
| beverages(nonalcoholic) | - |
| beverages(alcoholic) | - |
| breakfast cereal | - |
| cheese | - |
| chewing gum | - |
| condiments / relishes | - |
| confectionery froastings | - |
| egg products | - |
| fats / oils | - |
| fish products | - |
| frozen dairy | - |
| fruit ices | - |
| gelatins / puddings | - |
| granulated sugar | - |
| gravies | - |
| hard candy | - |
| imitation dairy | - |
| instant coffee / tea | - |
| jams / jellies | - |
| meat products | - |
| milk products | - |
| nut products | - |
| other grains | - |
| poultry | - |
| processed fruits | - |
| processed vegetables | - |
| reconstituted vegetables | - |
| seasonings / flavors | - |
| snack foods | - |
| soft candy | - |
| soups | - |
| sugar substitutes | - |
| sweet sauces | - |
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