myrtine
Identification
| Name | myrtine |
| CAS Number | 66835-10-7 |
| FDA UNII | Search |
| Molecular Formula | C10 H17 N O |
| Molecular Weight | 167.25169000 |
| Nikkaji Number | J19.966D |
Regulatory
Physical Properties
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Soluble in | water, 8.109e+004 mg/L @ 25 °C (est) |
No sensory data available
Safety Information
| Oral/Parenteral Toxicity | Not determined |
| Dermal Toxicity | Not determined |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | natural substances and extractives |
| Recommendation for myrtine usage levels up to | not for fragrance use. |
| Recommendation for myrtine flavor usage levels up to | not for flavor use. |
No supplier data available
Potential Uses
Natural Occurrence
Synonyms
(4R,9aR)-4-
methyl-1,3,4,6,7,8,9,9a-octahydroquinolizin-2-one
PubMed:
Polymer-supported (-)-8-phenylmenthyl Auxiliary as an Effective Solidphase Chiral Inductor in the Addition of Nucleophiles to N-acyliminium Ions.
PubMed:
Electrochemical access to 8-(1-phenyl-ethyl)-1,4-dioxa-8-aza-spiro[4.5]decane-7-carbonitrile. Application to the asymmetric syntheses of (+)-myrtine and alkaloid (+)-241D.
PubMed:
Stereoselective synthesis of 2,6-cis- and 2,6-trans-piperidines through organocatalytic aza-Michael reactions: a facile synthesis of (+)-myrtine and (-)-epimyrtine.
PubMed:
Catalytic asymmetric synthesis of the alkaloid (+)-myrtine.
PubMed:
A convenient allylsilane-N-acyliminium route toward indolizidine and quinolizidine alkaloids.
PubMed:
Asymmetric synthesis of ring functionalized trans-2,6-disubstituted piperidines from N-sulfinyl delta-amino beta-keto phosphonates. total synthesis of (-)-myrtine.
PubMed:
Indolizidine and quinolizidine alkaloids.
PubMed:
Synthesis of the quinolizidine alkaloids (-)-lasubine II and (+/-)-myrtine by conjugate addition and intramolecular acylation of amino esters with acetylenic sulfones.