(Z)-3-hexen-1-yl isobutyrate

cis-3-hexenyl isobutyrate

CAS: 41519-23-7 C10 H18 O2 MW: 170.25186000 fruity fruity

Identification

Name(Z)-3-hexen-1-yl isobutyrate
IUPAC[(Z)-hex-3-enyl] 2-methylpropanoate
CAS Number41519-23-7
EINECS255-424-0
FDA UNIIR84N0RD251
Molecular FormulaC10 H18 O2
Molecular Weight170.25186000
MDL NumberMFCD00036529
Nikkaji NumberJ183.044I
Beilstein1759547
CoE Number11783

Regulatory

JECFA Food Flavoring1275 cis-3-hexenyl isobutyrate
DG SANTE Food Flavourings09.563 hex-3(cis)-enyl isobutyrate
FEMA Number3929
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)41519-23-7 ; (Z)-3-HEXENYL ISOBUTYRATE

Physical Properties

Appearance colorless clear liquid (est)
Assay 98.00 to 100.00 sum of isomers
Food Chemicals Codex Listed No
Specific Gravity 0.88200 to 0.88500 @ 25.00 °C., 0.87900 to 0.88900 @ 20.00 °C.
Pounds per Gallon - (est). 7.339 to 7.364
Pounds per Gallon - est. 7.323 to 7.406
Refractive Index 1.42400 to 1.43200 @ 20.00 °C.
Boiling Point 80.00 °C. @ 30.00 mm Hg, 73.00 °C. @ 6.00 mm Hg
Acid Value 1.00 max. KOH/g
Vapor Pressure 0.182000 mmHg @ 25.00 °C. (est)
Vapor Density 5.8 ( Air = 1 )
Flash Point 152.00 °F. TCC ( 66.67 °C. )
logP (o/w) 3.263 (est)
Soluble in alcohol
Insoluble in water
Stability acid cleaner

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength high ,
Substantivity > 8 hour(s) at 100.00 %
Odor Description
at 10.00 % in dipropylene glycol.
at 1.00 %.
Green, fruity, cut grass, apple-like
potent fruity green; character of cut grass
GREEN, APPLE, FRUITY, CUT GRASS
Powerful fruity, winey, green odor, very diffusive
Odor sample from Bedoukian Research, Inc.
Taste Description
sweet fruity spicy apple pear green asparagus green bean guava
at 1.00 - 5.00 ppm.
Fresh, green, fruity notes
green, fruity, apple-like

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral Toxicitygavage-rat LD50 [sex: M/F] > 25000 mg/kg
Dermal Toxicityskin-rabbit LD50 > 5000 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for (Z)-3-hexen-1-yl isobutyrate usage levels up to2.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)12.00 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)18.00 (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI)ND (μg/person/day)
Threshold of Concern1800 (μg/person/day)
Structure ClassI
baked goods16.00000
beverages(nonalcoholic)2.00000
beverages(alcoholic)4.00000
breakfast cereal-
cheese-
chewing gum15.00000
condiments / relishes5.00000
confectionery froastings5.00000
egg products-
fats / oils-
fish products-
frozen dairy7.00000
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy5.00000
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products2.00000
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

ACS International GmbH

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Augustus Oils Ltd

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Azelis UK Ltd.

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Bedoukian Research, Inc.

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Berje Inc.

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FCI SAS

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FRUTAROM USA INC,

Flavor & Specialty Ingredients

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Indukern, S.A. F&F Ingredients Division

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Idukern F&F Ingredients is your partner for the fragrance and flavor ingredients.

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Lluch Essence S.L.

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M&U International LLC

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Penta International Corporation

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Prodasynth

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Sigma-Aldrich

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SRS Aromatics Ltd

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Synerzine, Inc.

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Taytonn ASCC Pte Ltd

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The Lermond Company

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Ernesto Ventós S.A.

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Vigon International

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WholeChem, LLC

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Potential Uses

FR apple FR floral FL fruit tropical fruit grass FR green FR herbal FR lavender FR lemon FR melon FR mint natural FL nut FR orange FR pear FR pineapple FR privet

Natural Occurrence

guava fruit quince peel chinese spearmint oil scotch

Synonyms

iso butyric acid (Z)-hex-3-en-1-yl ester (3Z)- hex-3-en-1-yl 2-methylpropanoate (Z)- hex-3-enyl 2-methyl propanoate (Z)- hex-3-enyl isobutyrate [(Z)- hex-3-enyl] 2-methylpropanoate hex-3(cis)-enyl isobutyrate (Z)-3- hexen-1-yl 2-methyl propionate cis-3- hexen-1-yl 2-methyl propionate beta,gamma- hexen-1-yl isobutanoate (Z)-3- hexen-1-yl isobutyrate cis-3- hexen-1-yl isobutyrate hexenyl cis-3 isobutyrate natural cis-3- hexenyl i-butyrate cis-3- hexenyl iso butyrate cis-3- hexenyl iso-butyrate (Z)-3- hexenyl isobutyrate C3 hexenyl isobutyrate cis-3- hexenyl isobutyrate cis-3- hexenyl isobutyrate, no antioxidant hexenyl-cis-3-iso-butyrate (Z)-2- methyl propanoic acid 3-hexen-1-yl ester (Z)-2- methylpropanoic acid 3-hexenyl ester propanoic acid, 2-methyl-, (3Z)-3-hexen-1-yl ester propanoic acid, 2-methyl-, (3Z)-3-hexenyl ester propanoic acid, 2-methyl-, 3-hexenyl ester, (Z)- verdural B extra (IFF) Try the PubMed Search.