Identification

Namefruity ketal
IUPACethyl 2-(2,4-dimethyl-1,3-dioxolan-2-yl)acetate
CAS Number6290-17-1
EINECS228-536-2
FDA UNII087792Q4F6
Molecular FormulaC9 H16 O4
Molecular Weight188.22332000
MDL NumberMFCD00151819
Nikkaji NumberJ37.791K

Regulatory

JECFA Food Flavoring1715 cis- and trans-ethyl 2,4-dimethyl-1,3-dioxolane-2-acetate
DG SANTE Food Flavourings06.087 ethyl 2,4-dimethyl-1,3-dioxolane-2-acetate
FEMA Number4294
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)6290-17-1 ; CIS- AND TRANS-ETHYL 2,4-DIMETHYL-1,3-DIOXOLANE-2-ACETATE

Physical Properties

Appearance colorless clear liquid (est)
Assay 95.00 to 100.00 sum of isomers
Food Chemicals Codex Listed No
Specific Gravity 1.04800 to 1.05400 @ 25.00 °C., 1.03900 to 1.04700 @ 20.00 °C.
Pounds per Gallon - (est). 8.720 to 8.770
Pounds per Gallon - est. 8.656 to 8.722
Refractive Index 1.42500 to 1.43100 @ 20.00 °C.
Melting Point -68.00 °C. @ 760.00 mm Hg
Boiling Point 110.00 °C. @ 27.00 mm Hg
Acid Value 1.00 max. KOH/g
PH Number 6.40
Vapor Pressure 0.112000 mmHg @ 25.00 °C. (est)
Flash Point 195.00 °F. TCC ( 90.56 °C. )
logP (o/w) 1.512
Shelf Life 24.00 month(s) or longer if stored properly.
Storage store in cool, dry place in tightly sealed containers, protected from heat and light.
Soluble in alcohol
Stability alcoholic lotion

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength medium
Substantivity 12 hour(s) at 100.00 %
Odor Description
at 100.00 %.
fresh-fruity, reminiscent of apples and strawberries
A tart, fresh, anisic, fruity note reminiscent of apple, plum and strawberry
Fruity,apple, strawberry, sweet
freshly fruity, reminiscent of apples and strawberries
Fruity, Apple, Strawberry
Odor sample from Ungerer & Company, Inc.
Taste Description
fruity licorice tropical anise plum
Anisic, Sweet, Fruity, Red Apple, Fennel

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for fruity ketal usage levels up to30.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)22.00 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)ND (μg/capita/day)
Modified Theoretical Added Maximum Daily Intake (mTAMDI)9800 (μg/person/day)
Threshold of Concern90 (μg/person/day)
Structure ClassIII
baked goods10.00000
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal5.00000
cheese7.00000
chewing gum-
condiments / relishes5.00000
confectionery froastings10.00000
egg products-
fats / oils5.00000
fish products2.00000
frozen dairy7.00000
fruit ices10.00000
gelatins / puddings-
granulated sugar-
gravies20.00000
hard candy-
imitation dairy7.00000
instant coffee / tea-
jams / jellies-
meat products2.00000
milk products7.00000
nut products-
other grains5.00000
poultry2.00000
processed fruits7.00000
processed vegetables-
reconstituted vegetables-
seasonings / flavors5.00000
snack foods-
soft candy-
soups5.00000
sugar substitutes-
sweet sauces5.00000
Dairy products, excluding products of category 02.0 (01.0)7.00000
Fats and oils, and fat emulsions (type water-in-oil) (02.0)5.00000
Edible ices, including sherbet and sorbet (03.0)10.00000
Processed fruit (04.1)7.00000
Processed vegetables (incl. mushrooms & fungi, roots & tubers, pulses and legumes), and nuts & seeds (04.2)-
Confectionery (05.0)10.00000
Chewing gum (05.3)-
Cereals and cereal products, incl. flours & starches from roots & tubers, pulses & legumes, excluding bakery (06.0)5.00000
Bakery wares (07.0)10.00000
Meat and meat products, including poultry and game (08.0)2.00000
Fish and fish products, including molluscs, crustaceans and echinoderms (MCE) (09.0)2.00000
Eggs and egg products (10.0)-
Sweeteners, including honey (11.0)-
Salts, spices, soups, sauces, salads, protein products, etc. (12.0)5.00000
Foodstuffs intended for particular nutritional uses (13.0)10.00000
Non-alcoholic ("soft") beverages, excl. dairy products (14.1)5.00000
Alcoholic beverages, incl. alcohol-free and low-alcoholic counterparts (14.2)10.00000
Ready-to-eat savouries (15.0)20.00000
Composite foods (e.g. casseroles, meat pies, mincemeat) - foods that could not be placed in categories 01.0 - 15.0 (16.0)5.00000

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Jiangyin Healthway International Trade Co., Ltd

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PerfumersWorld Ltd.

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Sigma-Aldrich

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Taytonn ASCC Pte Ltd

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The Good Scents Company

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The John D. Walsh Company, Inc

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The Lermond Company

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Ernesto Ventós S.A.

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WholeChem, LLC

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Potential Uses

FR apple FR apple blossom FR crabapple FR apple green apple FR apple red apple FR apricot FL arrack FR banana FR bark FR berry jam blossom tropical blossom FR bramble arctic bramble blackberry FL brandy FL cheese romano cheese FL cheese swiss cheese FR cherry black cherry FR cherry blossom FR citronella FL cloudberry bakeapple FR crabapple blossom FL/FR currant bud absolute replacer FR date FR eglantine FR elder berry FR foliage FR gingergrass FR gooseberry FR grape FL grape white grape FR grapefruit FR green grass FR hibiscus FR iris blossom FL jackfruit FR kiwi FR kiwi blossom FR kumquat FR licorice FR lychee FR mandarin FR mango FL/FR marigold FR melon FR myrtle oil replacer FL necterine FR orange FR osmanthus FR papaya FR passion fruit FR peach FR peach blossom FR pear FL pear bartlett pear FR pear blossom FL pear emperor pear FR pineapple FR plum FR plum blossom FL plum greengage plum FR plum mirabelle plum FR plum blossom FR pomegranate rose wild rose FL/FR rue FL rum butter FL sarsaparilla FR spearmint FR stephanotis FR tangerine FL tea FL tea black tea FL tropical FL/FR valerian FR wine FR wintergreen FL/FR yerba mate

Natural Occurrence

not found in nature

Synonyms

acetoacetic acid, ethyl ester, 1,2-propylene ketal dimethyl dioxolan dimethyl dioxolane 2,4- dimethyl-1,3-dioxolane-2-acetic acid ethyl ester 2,4- dimethyl-1,3-dioxolane-2-ethyl acetate dimethyldioxolan 1,3- dioxolane-2-acetic acid, 2,4-dimethyl-, ethyl ester ethyl (2,4-dimethyl-1,3-dioxolan-2-yl)acetate ethyl 2-(2,4-dimethyl-1,3-dioxolan-2-yl)acetate ethyl 2, 4-dimethyl-1,3-dioxolane-2-acetate ethyl 2,4-dimethyl-1,3-dioxolane-2-acetate cis- and trans- ethyl 2,4-dimethyl-1,3-dioxolane-2-acetate ethyl aceto acetate PG acetal ethyl acetoacetate propylene glycol ketal ethyl acetoacetate propyleneglycol ketal ethyl dimethyl dioxolane acetate ethyl dimethyl dioxolane-2-acetate ethyl-2,4-dimethyl-1,3-dioxolane-2-acetate (Z+E)- ethyl-2,4-dimethyl-1,3-dioxolane-2-acetate fragolane (Symrise) fraisberry (Tadimety) fraistone (IFF) fructone B fruity ketal methyl fragolan propyl fruitat strawberry ketal Try the PubMed Search.