chlorodiphenyl phosphine

diphenylchlorophosphine

CAS: 1079-66-9 C12 H10 Cl P MW: 220.63746200

Identification

Namechlorodiphenyl phosphine
CAS Number1079-66-9
EINECS214-093-2
FDA UNIIWO975PJK1Y
Molecular FormulaC12 H10 Cl P
Molecular Weight220.63746200
MDL NumberMFCD00000529
Nikkaji NumberJ24.880K
Beilstein512032

Regulatory

Physical Properties

Assay 95.00 to 100.00
Food Chemicals Codex Listed No
Boiling Point 320.00 °C. @ 760.00 mm Hg (est)
Flash Point 297.00 °F. TCC ( 147.30 °C. ) (est)
logP (o/w) 5.330 (est)
Soluble in water, 12.67 mg/L @ 25 °C (est)

No sensory data available

Safety Information

Preferred SDSView
Oral/Parenteral ToxicityNot determined
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categorypharmaceuticals / chemical synthisis
Recommendation for chlorodiphenyl phosphine usage levels up tonot for fragrance use.
Recommendation for chlorodiphenyl phosphine flavor usage levels up tonot for flavor use.

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Potential Uses

None Found

Natural Occurrence

not found in nature

Synonyms

chloro(diphenyl)phosphane chlorodiphenylphosphine diphenylchlorophosphine diphenylphosphine chloride diphenylphosphinous chloride phosphine, chlorodiphenyl- phosphinous chloride, diphenyl- phosphinous chloride, P,P-diphenyl- PubMed: Synthesis and investigation of cobalt chalcogenide clusters with thienyl phosphine ligands as new acceptor materials for P3HT. PubMed: Regioselective pivaloylation of N-phthaloylchitosan: a promising soluble intermediate for chitosan chemistry. PubMed: Imidazoliophosphines are true N-heterocyclic carbene (NHC)-phosphenium adducts. PubMed: Enantioselective synthesis of planar-chiral 1,n-dioxa[n]paracyclophanes via catalytic asymmetric ortho-lithiation. PubMed: Bis(diphenylphosphino)acetonitrile: synthesis, ligand properties and application in catalytic carbon-carbon coupling. PubMed: Expedient synthesis of substituted (diphenylphosphinoylmethyl)benzenes. PubMed: Efficient methods for the preparation of alkyl-aryl and symmetrical or unsymmetrical dialkyl ethers between alcohols and phenols or two alcohols by oxidation-reduction condensation. PubMed: Preparation of ferrocene-containing phosphinamine ligands possessing central and planar chirality and their application in palladium-catalyzed asymmetric allylic alkylation. PubMed: ROMPgel-supported triphenylphosphine with potential application in parallel synthesis. PubMed: Convenient synthesis of 3,3,3-trifluoropropenyl compounds from aromatic aldehydes by means of the TBAF-mediated Horner reaction. PubMed: O-Methylephedrine: a versatile and highly efficient ortho-directing group. Synthesis of enantiopure 1,2-disubstituted ferrocene derivatives. PubMed: Ortho-Directed Lithiation of omega-Phenoxy Alcohols. PubMed: Synthesis of Chiral C(2)-Symmetric Bisferrocenyldiamines. X-ray Crystal Structure of Ru(2)Cl(2).2CHCl(3) (2 = N1,N2-Bis{(R)-1-[(S)-2-(diphenylphosphino)]ferrocenylethyl}- N1,N2-dimethyl-1,2-ethanediamine).