buprofezin
2-tert-butylimino-3-isopropyl-5-phenyl-3,4,5,6-tetrahydro-2h-1,3,5-thiadiazin-4-one
Identification
| Name | buprofezin |
| IUPAC | (2Z)-3-isopropyl-2-[(2-methyl-2-propanyl)imino]-5-phenyl-1,3,5-thiadiazinan-4-one |
| CAS Number | 953030-84-7 |
| FDA UNII | 3B8KGI239I |
| Molecular Formula | C16 H23 N3 O S |
| Molecular Weight | 305.44451000 |
| MDL Number | MFCD01681899 |
| Nikkaji Number | J4.391E |
| Beilstein | 8625926 |
Regulatory
Physical Properties
| Appearance | white crystals (est) |
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Melting Point | 105.00 °C. @ 760.00 mm Hg |
| Boiling Point | 395.00 °C. @ 760.00 mm Hg (est) |
| Vapor Pressure | 9.400000 mmHg @ 25.00 °C. (est) |
| Flash Point | 379.00 °F. TCC ( 192.70 °C. ) (est) |
| logP (o/w) | 4.300 |
| Soluble in | water, 2.427 mg/L @ 25 °C (est) |
No sensory data available
Safety Information
| Oral/Parenteral Toxicity | Not determined |
| Dermal Toxicity | Not determined |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | herbicides / pesticides |
| Recommendation for buprofezin usage levels up to | not for fragrance use. |
| Recommendation for buprofezin flavor usage levels up to | not for flavor use. |
No supplier data available
Potential Uses
Natural Occurrence
Synonyms
(Z)-2-tert-
butylimino-3-isopropyl-5-phenyl-1,3,5-thiadiazinan-4-one
2-tert-
butylimino-3-isopropyl-5-phenyl-1,3,5-thiadiazinan-4-one
2-tert-
butylimino-3-isopropyl-5-phenyl-3,4,5,6-tetrahydro-2h-1,3,5-thiadiazin-4-one
2-tert-
butylimino-3-isopropyl-5-phenylperhydro-1,3,5-thiadiazinan-4-one
2-tert-
butylimino-5-phenyl-3-propan-2-yl-1,3,5-thiadiazinan-4-one
(Z)-2-((1,1-
dimethylethyl)imino)tetrahydro-3-(1-methylethyl)-5-phenyl-4H-1,3,5-thiadiazin-4-one
2-((1,1-
dimethylethyl)imino)tetrahydro-3-(1-methylethyl)-5-phenyl-4H-1,3,5-thiadiazin-4-one
(2ZE)-3-iso
propyl-2-[(2-methyl-2-propanyl)imino]-5-phenyl-1,3,5-thiadiazinan-4-one
4H-1,3,5-
thiadiazin-4-one, 2-((1,1-dimethylethyl)imino)tetrahydro-3-(1-methylethyl)-5-phenyl-
4H-1,3,5-
thiadiazin-4-one, 2-[(1,1-dimethylethyl)imino]tetrahydro-3-(1-methylethyl)-5-phenyl-, (2Z)-
PubMed:
Dynamic changes of bacterial community under bioremediation with Sphingobium sp. LY-6 in buprofezin-contaminated soil.
PubMed:
Characterization of Synergistic Embryotoxicity of Nickel and Buprofezin in Zebrafish.
PubMed:
Liquid chromatography-electrospray ionization tandem mass spectrometry and dynamic multiple reaction monitoring method for determining multiple pesticide residues in tomato.
PubMed:
Transfer rates of 19 typical pesticides and the relationship with their physicochemical property.
PubMed:
Sensitivity of Bemisia tabaci (Hemiptera: Aleyrodidae) to several new insecticides in china: effects of insecticide type and whitefly species, strain, and stage.
PubMed:
Analysis of airborne pesticides from different chemical classes adsorbed on Radiello® Tenax® passive tubes by thermal-desorption-GC/MS.
PubMed:
Identification of promoter polymorphisms in the cytochrome P450â
CYP6AY1 linked with insecticide resistance in the brown planthopper, Nilaparvata lugens.
PubMed:
Effect of repeated applications of buprofezin and acephate on soil cellulases, amylase, and invertase.
PubMed:
[Exposure to persistent and non-persistent pesticides in a non-occupationally exposed population in Tenerife Island (Spain)].
PubMed:
Patterns of presence and concentration of pesticides in fish and waters of the Júcar River (Eastern Spain).
PubMed:
Toxicity of buprofezin on the survival of embryo and larvae of African catfish, Clarias gariepinus (Bloch).
PubMed:
Detection of resistance, cross-resistance, and stability of resistance to new chemistry insecticides in Bemisia tabaci (Homoptera: Aleyrodidae).
PubMed:
Pesticide management and their residues in sediments and surface and drinking water in the Mekong Delta, Vietnam.
PubMed:
Genomic insights into the glutathione S-transferase gene family of two rice planthoppers, Nilaparvata lugens (Stål) and Sogatella furcifera (Horváth) (Hemiptera: Delphacidae).
PubMed:
[Determination of eight pesticide residues in tea by liquid chromatography-tandem mass spectrometry and its uncertainty evaluation].
PubMed:
Effects of pyriproxyfen and buprofezin on immature development and reproduction in the stable fly.
PubMed:
Acute and chronic toxicity of buprofezin on Daphnia magna and the recovery evaluation.
PubMed:
Baseline susceptibility of Planococcus ficus (Hemiptera: Pseudococcidae) from California to select insecticides.
PubMed:
Alteration of leaf metabolism in Bt-transgenic rice (Oryza sativa L.) and its wild type under insecticide stress.
PubMed:
Effects of buprofezin and diflubenzuron on various developmental stages of Asian citrus psyllid, Diaphorina citri.
PubMed:
Identification and expression profiles of nine glutathione S-transferase genes from the important rice phloem sap-sucker and virus vector Laodelphax striatellus (Fallén) (Hemiptera: Delphacidae).
PubMed:
Biodegradation of buprofezin by Rhodococcus sp. strain YL-1 isolated from rice field soil.
PubMed:
Simultaneous analysis of pesticides from different chemical classes by using a derivatisation step and gas chromatography-mass spectrometry.
PubMed:
Development of a gas chromatography-mass spectrometry method for the determination of pesticides in gaseous and particulate phases in the atmosphere.
PubMed:
Cross-resistance of bisultap resistant strain of Nilaparvata lugens and its biochemical mechanism.
PubMed:
Optimization of detection conditions and single-laboratory validation of a multiresidue method for the determination of 135 pesticides and 25 organic pollutants in grapes and wine by gas chromatography time-of-flight mass spectrometry.
PubMed:
Isolation of a buprofezin co-metabolizing strain of Pseudomonas sp. DFS35-4 and identification of the buprofezin transformation pathway.
PubMed:
Extraordinary resistance to insecticides reveals exotic Q biotype of Bemisia tabaci in the New World.
PubMed:
Development and validation of a multiresidue method for determination of 37 pesticides in soil using GC-NPD.
PubMed:
Rate of loss of insecticides during soil solarization and soil biosolarization.
PubMed:
Evaluation of alternative rice planthopper control by the combined action of oil-formulated Metarhizium anisopliae and low-rate buprofezin.
PubMed:
Degradation and adsorption of pesticides in compost-based biomixtures as potential substrates for biobeds in southern Europe.
PubMed:
Screening of agrochemicals in foodstuffs using low-temperature plasma (LTP) ambient ionization mass spectrometry.
PubMed:
Evaluation of a modified QuEChERS method for the extraction of pesticides from agricultural, ornamental and forestal soils.
PubMed:
Multi-residue analysis of 30 currently used pesticides in fine airborne particulate matter (PM 2.5) by microwave-assisted extraction and liquid chromatography-tandem mass spectrometry.
PubMed:
Evaluation of multi-walled carbon nanotubes as solid-phase extraction adsorbents of pesticides from agricultural, ornamental and forestal soils.
PubMed:
Evaluation of pesticide toxicities with differing mechanisms using Caenorhabditis elegans.
PubMed:
Insecticide resistance status of Bemisia tabaci Q-biotype in south-eastern Spain.
PubMed:
Daily variation of pesticides in surface water of a small river flowing through paddy field area.
PubMed:
Multiresidue analysis of 83 pesticides and 12 dioxin-like polychlorinated biphenyls in wine by gas chromatography-time-of-flight mass spectrometry.
PubMed:
Determination of four heterocyclic insecticides by ionic liquid dispersive liquid-liquid microextraction in water samples.
PubMed:
Desorption electrospray ionization mass spectrometry for trace analysis of agrochemicals in food.
PubMed:
Degradation kinetics and safety evaluation of buprofezin residues in grape (Vitis vinifera L.) and three different soils of India.
PubMed:
Multi-walled carbon nanotubes as efficient solid-phase extraction materials of organophosphorus pesticides from apple, grape, orange and pineapple fruit juices.
PubMed:
Multiwalled carbon nanotubes as solid-phase extraction materials for the gas chromatographic determination of organophosphorus pesticides in waters.
PubMed:
Susceptibility to neonicotinoids and risk of resistance development in the brown planthopper, Nilaparvata lugens (Stål) (Homoptera: Delphacidae).
PubMed:
Response of citrus peelminer Marmara gulosa Guillén and Davis (Lepidoptera: Gracillariidae) stages to various insecticides.
PubMed:
Buprofezin susceptibility survey, resistance selection and preliminary determination of the resistance mechanism in Nilaparvata lugens (Homoptera: Delphacidae).
PubMed:
Comparison of hollow fiber liquid phase microextraction and dispersive liquid-liquid microextraction for the determination of organosulfur pesticides in environmental and beverage samples by gas chromatography with flame photometric detection.
PubMed:
Optimization of separation and detection conditions for the multiresidue analysis of pesticides in grapes by comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry.
PubMed:
Ecotoxicological effects of buprofezin on fecundity, growth, development, and predation of the wolf spider Pirata piratoides (Schenkel).
PubMed:
MSPD procedure for determining buprofezin, tetradifon, vinclozolin, and bifenthrin residues in propolis by gas chromatography-mass spectrometry.
PubMed:
Toxicity of seven foliar insecticides to four insect parasitoids attacking citrus and cotton pests.
PubMed:
Utilizing the assassin bug, Pristhesancus plagipennis (Hemiptera: Reduviidae), as a biological control agent within an integrated pest management programme for Helicoverpa spp. (Lepidoptera: Noctuidae) and Creontiades spp. (Hemiptera: Miridae) in cotton.
PubMed:
Capabilities of different liquid chromatography tandem mass spectrometry systems in determining pesticide residues in food. Application to estimate their daily intake.
PubMed:
Effect of Zohar LQ-215, a biorational surfactant, on the sweetpotato whitefly Bemisia tabaci (biotype b).
PubMed:
Use of liquid chromatography coupled to quadrupole time-of-flight mass spectrometry to investigate pesticide residues in fruits.
PubMed:
Buprofezin inhibits acetylcholinesterase activity in B-biotype Bemisia tabaci.
PubMed:
Effect of insecticides on mealybug destroyer (Coleoptera: Coccinellidae) and parasitoid Leptomastix dactylopii (Hymenoptera: Encyrtidae), natural enemies of citrus mealybug (Homoptera: Pseudococcidae).
PubMed:
Pheromone-based mating disruption of Planococcus ficus (Hemiptera: Pseudococcidae) in California vineyards.
PubMed:
Effectiveness of two insect growth regulators against Bemisia tabaci (Gennadius) (Homoptera: Aleyrodidae) and Helicoverpa armigera (Hübner) (Lepidoptera: Noctuidae) and their impact on population densities of arthropod predators in cotton in Pakistan.
PubMed:
Role of two insect growth regulators in integrated pest management of citrus scales.
PubMed:
Hazards and uptake of chitin synthesis inhibitors in bumblebees Bombus terrestris.
PubMed:
Compatibility of the entomopathogenic fungus Lecanicillium muscarium and insecticides for eradication of sweetpotato whitefly, Bemisia tabaci.
PubMed:
Selective insecticide-induced stimulation on fecundity and biochemical changes in Tryporyza incertulas (Lepidoptera: Pyralidae).
PubMed:
Routine application using single quadrupole liquid chromatography-mass spectrometry to pesticides analysis in citrus fruits.
PubMed:
Comparison of liquid chromatography using triple quadrupole and quadrupole ion trap mass analyzers to determine pesticide residues in oranges.
PubMed:
[Determination of buprofezin, methamidophos, acephate, and triazophos residues in Chinese tea samples by gas chromatography].
PubMed:
Conservation of natural enemies in cotton: comparative selectivity of acetamiprid in the management of Bemisia tabaci.
PubMed:
Effect of buprofezin on survival of immature stages of Harmonia axyridis, Stethorus punctum picipes (Coleoptera: Coccinellidae), Orius tristicolor (Hemiptera: Anthocoridae), and Geocoris spp. (Hemiptera: Geocoridae).
PubMed:
Effect of pH on the persistence behavior of the insecticide buprofezin in water under laboratory conditions.
PubMed:
Conserving vedalia beetle, Rodolia cardinalis (Mulsant) (Coleoptera: Coccinellidae), in citrus: a continuing challenge as new insecticides gain registration.
PubMed:
Rapid pesticide analysis, in post-harvest plants used as animal feed, by low-pressure gas chromatography-tandem mass spectrometry.
PubMed:
[Effects of rice cleaning and cooking process on the residues of flutolanil, fenobucarb, silafluofen and buprofezin in rice].
PubMed:
Novaluron (Rimon), a novel IGR--mechanism, selectivity and importance in IPM programs.
PubMed:
Simple method for the determination of trace levels of pesticides in honeybees using matrix solid-phase dispersion and gas chromatography.
PubMed:
Action threshold for applying insect growth regulators to tomato for management of irregular ripening caused by Bemisia argentifolii (Homoptera: Aleyrodidae).
PubMed:
[Insecticide resistance of different populations of white-backed planthopper, Sogatella furcifera (Horváth) (Homoptera:Delphacidae)].
PubMed:
New developments in insecticide resistance in the glasshouse whitefly (Trialeurodes vaporariorum) and the two-spotted spider mite (Tetranychus urticae) in the UK.
PubMed:
Inter-regional differences in baseline toxicity of Bemisia argentifolii (Homoptera: Aleyrodidae) to the two insect growth regulators, buprofezin and pyriproxyfen.
PubMed:
Acephate and buprofezin residues in olives and olive oil.
PubMed:
Multi-residue methodology for pesticide screening in wines.
PubMed:
Effects of applaud on the growth of silkworm (Lepidoptera: Bombycidae).
PubMed:
Effects of the chitin synthesis inhibitor buprofezin on survival and development of immatures of Chrysoperla rufilabris (Neuroptera: Chrysopidae).
PubMed:
Genotoxicity evaluation of buprofezin, petroleum oil and profenofos in somatic and germ cells of male mice.
PubMed:
The insecticide buprofezin induces morphological transformation and kinetochore-positive micronuclei in cultured Syrian hamster embryo cells in the absence of detectable DNA damage.
PubMed:
Effects of buprofezin on the ultrastructure of the third instar cuticle of the insect Trialeurodes vaporariorum.