lilyall / methyl anthranilate schiff's base

verdantiol (Givaudan)

CAS: 91-51-0 C22 H27 N O2 MW: 337.46259000 floral

Identification

Namelilyall / methyl anthranilate schiff's base
IUPACmethyl 2-[[3-(4-tert-butylphenyl)-2-methylpropylidene]amino]benzoate
CAS Number91-51-0
EINECS202-073-6
FDA UNII3PWS757043
Molecular FormulaC22 H27 N O2
Molecular Weight337.46259000
Nikkaji NumberJ60.461E

Regulatory

Physical Properties

Appearance yellow liquid to solid (est)
Assay 98.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 1.03590 to 1.04210 @ 25.00 °C.
Pounds per Gallon - (est). 8.620 to 8.671
Refractive Index 1.53560 to 1.54290 @ 20.00 °C.
Boiling Point 471.82 °C. @ 760.00 mm Hg (est)
Vapor Pressure 0.001300 mmHg @ 20.00 °C.
Flash Point > 212.00 °F. TCC ( > 100.00 °C. )
logP (o/w) 7.660 (est)
Soluble in alcohol
Insoluble in water
Stability beauty care

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength medium ,
Substantivity 400 hour(s) at 100.00 %
Odor Description
at 50.00 % in dipropylene glycol.
neroli, orange blossom
Linden-Orange Flower
fresh floral, sweet aromatic, citrusy; notes of muguet and neroli
Floral, orange flower, lily of the valley
Odor sample from The Good Scents Company

Safety Information

European informationMost important hazard(s):
Human Experience12% in petrolatum produced no irritation or sensitization in humans.
Oral/Parenteral Toxicityoral-rat LD50 3000 mg/kg
Dermal Toxicityskin-rabbit LD50 > 5000 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryfragrance agents
RIFM Fragrance Material Safety AssessmentSearch
IFRA Critical EffectSensitization
fragrance material specificationThe IFRA Scientific Committee examined the physicochemical properties of Schiff bases and concluded that, based on the available information, these materials should be considered under contributions from other sources. By default, the stoichiometric presence of the aldehydes of the Schiff bases is taken into account assuming 100% dissociation. An indicative list of Schiff bases incorporating aldehydes covered by an IFRA Standard of restriction is reported at
Recommendation for lilyall / methyl anthranilate schiff's base usage levels up to5.0000 % in the fragrance concentrate.
Recommendation for lilyall / methyl anthranilate schiff's base flavor usage levels up tonot for flavor use.

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Potential Uses

FR floral FR frangipani plumeria FR lily FR narcissus FR neroli FR orange blossom

Natural Occurrence

not found in nature

Synonyms

anthranilic acid, N-(3-(p-tert-butylphenyl)-2-methylpropylidene)-, methyl ester benzoic acid, 2-((3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropylidene)amino)-, methyl ester p-tert- butyl-alpha-methyl hydrocinnamal / methyl anthranilate schiff base para-tert- butyl-alpha-methyl hydrocinnamal / methyl anthranilate schiff base lilanate 3275 P (Grau) lilial/ma schiffbase lilianth (IFF) liliavert (A.C.S. International) lilyall / methyl anthranilate schiff's base lilyantine maranthra methyl 2-((3-(4-(1,1-dimethyl ethyl)phenyl)-2-methyl propylidene)amino) benzoate methyl 2-((3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropylidene)amino)benzoate methyl 2-[[3-(4-tert-butylphenyl)-2-methylpropylidene]amino]benzoate methyl anthranilate / lilial methyl anthranilate / lilyall schiff's base methyl-N-(p-tert-butyl-a-methylhydrocinnamylidene) anthranilate methyl-N-(p-tert-butyl-alpha-methylhydrocinnamylidene) anthranilate methyl-N-(para-tert-butyl-alpha-methyl hydrocinnamylidene) anthranilate schiff base lilial schiff's base lilial-methyl anthranilate schiff's base lilianthral verdantiol (Givaudan) Try the PubMed Search.