2-methyl-2-pentenoic acid

strawberiff (IFF)

CAS: 3142-72-1 C6 H10 O2 MW: 114.14410000 acidic sour

Identification

Name2-methyl-2-pentenoic acid
IUPAC2-methylpent-2-enoic acid
CAS Number3142-72-1
EINECS221-552-0
FDA UNIISearch
Molecular FormulaC6 H10 O2
Molecular Weight114.14410000
MDL NumberMFCD00002655
CoE Number11680

Regulatory

JECFA Food Flavoring1210 2-methyl-2-pentenoic acid
DG SANTE Food Flavourings08.055 2-methyl-2-pentenoic acid
FEMA Number3195
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)3142-72-1 ; 2-METHYL-2-PENTENOIC ACID

Physical Properties

Appearance colorless to pale yellow liquid to crystalline solid (est)
Assay 98.00 to 100.00
Food Chemicals Codex Listed Yes
Specific Gravity 0.97800 to 0.98600 @ 25.00 °C., 0.97900 to 0.98700 @ 20.00 °C.
Pounds per Gallon - (est). 8.138 to 8.205
Pounds per Gallon - est. 8.156 to 8.222
Refractive Index 1.45700 to 1.46200 @ 20.00 °C.
Melting Point 24.00 to 26.00 °C. @ 760.00 mm Hg
Boiling Point 123.00 to 125.00 °C. @ 30.00 mm Hg, 112.00 °C. @ 12.00 mm Hg
Vapor Pressure 0.055000 mmHg @ 25.00 °C. (est)
Vapor Density >1 ( Air = 1 )
Flash Point 226.00 °F. TCC ( 107.78 °C. )
logP (o/w) 1.586 (est)
Shelf Life 12.00 month(s) or longer if stored properly.
Storage refrigerate in tightly sealed containers.
Soluble in alcohol
Insoluble in water
Stability alcoholic lotion

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength medium ,
Substantivity 380 hour(s) at 100.00 %
Odor Description
at 10.00 % in dipropylene glycol.
Sour, acidic, sweaty and fruity with a jammy, woody nuance
sweet strawberry jam
strongly fruity sour juicy slightly fatty
Fruity odor with a burnt sugar background
Odor sample from International Flavors & Fragrances Inc.
Taste Description
at 50.00 ppm.
Sharp, acidic, slightly cheesy, with jammy strawberry back notes
Fruity, geranium, mango, strawberry jam

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral Toxicityoral-rat LD50 5000 mg/kg
Dermal Toxicityskin-rabbit LD50 5000 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for 2-methyl-2-pentenoic acid usage levels up to1.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)36.00 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)20.00 (μg/capita/day)
Threshold of Concern1800 (μg/person/day)
Structure ClassI
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FL cheese FR fruit FR raspberry FR strawberry FL tropical

Natural Occurrence

heteromorpha trifoliata snake fruit strawberry wild strawberry fruit

Synonyms

methyl 2 pentenoic acid (extra) 2- methyl 2-pentenoic acid 2- methyl pent-2-enoic acid 2- methyl-2-butyric acid 2- methyl-2-pentenoic acid 2- methyl-2-pentenoic acid BRI 2- methyl-2-pentenoic acid natural 2- methyl-2-pentenoic acid synthetic 2- methyl-2-pentenoic acid, natural 2- methylpent-2-en-1-oic acid 2- methylpent-2-enoic acid pent-2-enoic acid, 2-methyl- 2- pentenoic acid, 2-methyl- strawberiff (IFF) strawberriff (IFF) vertofraise (A.C.S. International) US Patents: 3,931,293 - Processes for producing cis alkyl-2-methyl-3-pentenoates and isomer mixtures containing high proportions of cis alkyl-2-methyl-3-pentenoates PubMed: Metabolism of propionic acid to a novel acyl-coenzyme A thioester by mammalian cell lines and platelets. US Patents: 3,976,801 - Flavoring compositions containing alkyl esters of 2-methyl-4-pentenoic acid PubMed: Behavioral and electrophysiological responses of Aedes albopictus to certain acids and alcohols present in human skin emanations. PubMed: The effect of valproic acid in alleviating early death in burn shock. PubMed: In situ ATR-IR study of prochiral 2-methyl-2-pentenoic acid adsorption on Al2O3 and Pd/Al2O3. PubMed: Identification and characterization of the pyridomycin biosynthetic gene cluster of Streptomyces pyridomyceticus NRRL B-2517. PubMed: Hepatoprotection and lethality rescue by histone deacetylase inhibitor valproic acid in fatal hemorrhagic shock. PubMed: Green butyryl-coenzyme A dehydrogenase. An enzyme-acyl-coenzyme A complex.