bensulfuron-methyl
benzoic acid, 2-((((((4,6-dimethoxy-2-pyrimidinyl)amino)carbonyl)amino)sulfonyl)methyl)-, methyl ester
Identification
| Name | bensulfuron-methyl |
| CAS Number | 83055-99-6 |
| FDA UNII | QWL4I737BL |
| Molecular Formula | C16 H18 N4 O7 S |
| Molecular Weight | 410.40686000 |
| MDL Number | MFCD00128064 |
| Nikkaji Number | J195.901H |
| Beilstein | 7447488 |
Regulatory
Physical Properties
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Soluble in | water, 120 mg/L @ 25 °C (exp) |
No sensory data available
Safety Information
| Oral/Parenteral Toxicity | oral-duck LD50 > 2510 mg/kg |
| Dermal Toxicity | skin-rabbit LD50 > 2000 mg/kg |
| Inhalation Toxicity | inhalation-rat LC50 > 5000 mg/m3 |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements', 'BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)\nBEHAVIORAL: ATAXIA']
Safety in Use
| Category | herbicides / pesticides |
| Recommendation for bensulfuron-methyl usage levels up to | not for fragrance use. |
| Recommendation for bensulfuron-methyl flavor usage levels up to | not for flavor use. |
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Potential Uses
Natural Occurrence
Synonyms
benzoic acid, 2-((((((4,6-dimethoxy-2-pyrimidinyl)amino)carbonyl)amino)sulfonyl)methyl)-, methyl ester
methyl alpha-(4,6-dimethoxypyrimidin-2-ylcarbamoylsulfamoyl)-o-toluate
methyl 2-[(4,6-dimethoxypyrimidin-2-yl)carbamoylsulfamoylmethyl]benzoate
PubMed:
Non-target-site resistance to ALS-inhibiting herbicides in a Sagittaria trifolia L. population.
PubMed:
Simple, cost-effective and sensitive liquid chromatography diode array detector method for simultaneous determination of eight sulfonylurea herbicides in soya milk samples.
PubMed:
Bensulfuron-Methyl Treatment of Soil Affects the Infestation of Whitefly, Aphid, and Tobacco Mosaic Virus on Nicotiana tabacum.
PubMed:
A high-throughput, modified ALS activity assay for Cyperus difformis and Schoenoplectus mucronatus seedlings.
PubMed:
Detection of three herbicide, and one metabolite, residues in brown rice and rice straw using various versions of the QuEChERS method and liquid chromatography-tandem mass spectrometry.
PubMed:
Target-site resistance to bensulfuron-methyl in Sagittaria trifolia L. populations.
PubMed:
Preparation of novel ionic-liquid-modified magnetic nanoparticles by a microwave-assisted method for sulfonylurea herbicides extraction.
PubMed:
Optimization of derivatization procedure and gas chromatography-mass spectrometry method for determination of bensulfuron-methyl herbicide residues in water.
PubMed:
Core-shell magnetic molecularly imprinted polymers as sorbent for sulfonylurea herbicide residues.
PubMed:
On-line extraction and determination of two herbicides: comparison between two modes of three-phase hollow fiber microextraction.
PubMed:
Characterization of sulfonylurea-resistant Schoenoplectus juncoides having a target-site Asp(376)Glu mutation in the acetolactate synthase.
PubMed:
Expression of sulfur uptake assimilation-related genes in response to cadmium, bensulfuron-methyl and their co-contamination in rice roots.
PubMed:
Determination of four sulfonylurea herbicides in tea by matrix solid-phase dispersion cleanup followed by dispersive liquid-liquid microextraction.
PubMed:
Cytochrome P450 CYP81A12 and CYP81A21 Are Associated with Resistance to Two Acetolactate Synthase Inhibitors in Echinochloa phyllopogon.
PubMed:
Part I: temporal and spatial distribution of multiclass pesticide residues in lake waters of Northern Greece: application of an optimized SPE-UPLC-MS/MS pretreatment and analytical method.
PubMed:
A novel rice cytochrome P450 gene, CYP72A31, confers tolerance to acetolactate synthase-inhibiting herbicides in rice and Arabidopsis.
PubMed:
Ionic-liquid-functionalized magnetic particles as an adsorbent for the magnetic SPE of sulfonylurea herbicides in environmental water samples.
PubMed:
Biodegradation of nicosulfuron by a Talaromyces flavus LZM1.
PubMed:
Use of gold nanoparticle-coated sorbent materials for the selective preconcentration of sulfonylurea herbicides in water samples and determination by capillary liquid chromatography.
PubMed:
Palladium@gold bimetallic nanostructures as peroxidase mimic for development of sensitive fluoroimmunoassay.
PubMed:
Magnetic solid-phase extraction of sulfonylurea herbicides in environmental water samples by Fe3O4@dioctadecyl dimethyl ammonium chloride@silica magnetic particles.
PubMed:
[Simultaneous determination of bensulfuron-methyl and mefenacet residues in paddy field using high performance liquid chromatography].
PubMed:
Construction and analysis of an intergeneric fusant able to degrade bensulfuron-methyl and butachlor.
PubMed:
Biodegradation of bensulfuron-methyl and its effect on bacterial community in paddy soils.
PubMed:
Interaction between BSM-contaminated soils and Italian ryegrass.
PubMed:
Rapid determination of sixteen sulfonylurea herbicides in surface water by solid phase extraction cleanup and ultra-high-pressure liquid chromatography coupled with tandem mass spectrometry.
PubMed:
Development of a method for the simultaneous determination of six sulfonylurea herbicides in wheat, rice, and corn by liquid chromatography-tandem mass spectrometry.
PubMed:
Determination of some sulfonylurea herbicides in soil by a novel liquid-phase microextraction combined with sweeping micellar electrokinetic chromatography.
PubMed:
Effects of four rice paddy herbicides on algal cell viability and the relationship with population recovery.
PubMed:
Nitrous oxide and methane emission from a flooded rice field as influenced by separate and combined application of herbicides bensulfuron methyl and pretilachlor.
PubMed:
Study of biochemical pathway and enzyme involved in metsulfuron-methyl degradation by Ancylobacter sp. XJ-412-1 isolated from soil.
PubMed:
Trace analysis of pesticides in paddy field water by direct injection using liquid chromatography-quadrupole-linear ion trap-mass spectrometry.
PubMed:
Development and validation of a solid-phase extraction method coupled to high-performance liquid chromatography with ultraviolet-diode array detection for the determination of sulfonylurea herbicide residues in bovine milk samples.
PubMed:
Cloud point extraction with Triton X-114 for separation of metsulfuron-methyl, chlorsulfuron, and bensulfuron-methyl from water, soil, and rice and analysis by high-performance liquid chromatography.
PubMed:
Ecotoxicological effects of rice field waters on selected planktonic species: comparison between conventional and organic farming.
PubMed:
N-methylimidazolium ionic liquid-functionalized silica as a sorbent for selective solid-phase extraction of 12 sulfonylurea herbicides in environmental water and soil samples.
PubMed:
Comparison of extraction solvents and conditions for herbicide residues in milled rice with liquid chromatography-diode array detection analysis (LC-DAD).
PubMed:
Adsorption characteristic of bensulfuron-methyl at variable added Pb2+ concentrations on paddy soils.
PubMed:
Liquid chromatographic-diode-array detection multiresidue determination of rice herbicides in drinking and paddy-field water.
PubMed:
Phytotoxicity of four herbicides on Ceratophyllum demersum, Vallisneria natans and Elodea nuttallii.
PubMed:
Sorption behavior of bensulfuron-methyl on andisols and ultisols volcanic ash-derived soils: contribution of humic fractions and mineral-organic complexes.
PubMed:
Dispersive solid-phase extraction followed by dispersive liquid-liquid microextraction for the determination of some sulfonylurea herbicides in soil by high-performance liquid chromatography.
PubMed:
Activities of antioxidant enzymes in three bacteria exposed to bensulfuron-methyl.
PubMed:
Resistance mechanism to bensulfuron-methyl in biotypes of Scirpus mucronatus L. collected in Chilean rice fields.
PubMed:
Analysis of culturable and unculturable microbial community in bensulfuron-methyl contaminated paddy soils.
PubMed:
Cross-resistance to herbicides of five ALS-inhibiting groups and sequencing of the ALS gene in Cyperus difformis L.
PubMed:
Acute toxic effects of three pesticides on Pseudomonas putida monitored by microcalorimeter.
PubMed:
Homogeneous time-resolved fluoroimmunoassay of bensulfuron-methyl by using terbium fluorescence energy transfer.
PubMed:
Co-metabolic degradation of bensulfuron-methyl in laboratory conditions.
PubMed:
Preparation of molecularly imprinted solid phase extraction using bensulfuron-methyl imprinted polymer and clean-up for the sulfonylurea-herbicides in soybean.
PubMed:
Catalase and superoxide dismutase activities in a Stenotrophomonas maltophilia WZ2 resistant to herbicide pollution.
PubMed:
[Determination of six pesticides in milk using cloud point extraction-high performance liquid chromatography].
PubMed:
Effect of allelopathic rice varieties combined with cultural management options on paddy field weeds.
PubMed:
[Effects of solution pH and simulated acid rain on the behavior of two sulfonylurea herbicides in soil].
PubMed:
Behavior of bensulfuron-methyl in an agricultural alkaline soil.
PubMed:
Optimisation of the separation of herbicides by linear gradient high performance liquid chromatography utilising artificial neural networks.
PubMed:
Effects of three pesticides on the growth, photosynthesis and photoinhibition of the edible cyanobacterium Ge-Xian-Mi (Nostoc).
PubMed:
Determination of commonly used polar herbicides in agricultural drainage waters in Australia by HPLC.
PubMed:
Effects of five rice herbicides on the growth of two threatened aquatic ferns.
PubMed:
Predicting herbicides concentrations in paddy water and runoff to the river basin.
PubMed:
[Simultaneous determination of ten sulfonylurea herbicide residues in soybeans by high performance liquid chromatography].
PubMed:
Evaluation of resistance in Cyperus difformis populations to ALS inhibiting herbicides.
PubMed:
Effects of humic substances on photodegradation of bensulfuron-methyl on dry soil surfaces.
PubMed:
Effects of pesticides on soil biochemical characteristics of a paddy soil.
PubMed:
Photodegradation of bensulfuron-methyl on soil surface.
PubMed:
Rapid degradation of bensulfuron-methyl upon repeated application in paddy soils.
PubMed:
Cross-resistance pattern and alternative herbicides for Cyperus difformis resistant to sulfonylurea herbicides in Korea.
PubMed:
Photostabilization of the herbicide bensulfuron-methyl by using organoclays.
PubMed:
Sulfonylurea herbicide-resistant Monochoria vaginalis in Korean rice culture.
PubMed:
[Adsorption of bensulfuron-methyl in soils].
PubMed:
Trace analysis of sulfonylurea herbicides in water by on-line continuous flow liquid membrane extraction--C18 precolumn liquid chromatography with ultraviolet absorbance detection.
PubMed:
[Determination of active components in caoyiguang wettable powder by reversed-phase high performance liquid chromatography].
PubMed:
Determination of ten sulfonyl urea herbicides in unpolished rice by solid-phase extraction cleanup and LC-diode array detection.
PubMed:
Effects of bensulfuron-methyl and cinosulfuron on growth of four freshwater species of phytoplankton.
PubMed:
Development of an immunoassay for the residues of the herbicide bensulfuron-methyl.
PubMed:
Microbial response to bensulfuron-methyl treatment in soil.
PubMed:
Combined effects of two sulfonylurea herbicides on soil microbial biomass and N-mineralization.
PubMed:
Involvement of cytochrome P-450 enzyme activity in the selectivity and safening action of pyrazosulfuron-ethyl.
PubMed:
Synthesis of a terbium fluorescent chelate and its application to time-resolved fluoroimmunoassay.
PubMed:
Behavior of four sulfonylurea herbicides in the presence of hydroxy compounds.
PubMed:
Enantioselective Relieving Activity of α-Methylbenzylphenylureas toward Bensulfuron-methyl Injury to Rice (Oryza sativa).
PubMed:
A kinetic study of the methanolysis of the sulfonylureas bensulfuron methyl and sulfometuron methyl using capillary electrophoresis.
PubMed:
Multiresidue determination of sulfonylurea herbicides by capillary electrophoresis for hydrolysis studies in water and sediments.
PubMed:
Acceptance Criteria for Ultratrace HPLC-Tandem Mass Spectrometry:â Quantitative and Qualitative Determination of Sulfonylurea Herbicides in Soil.
PubMed:
Capillary electrophoretic behavior of seven sulfonylureas.
PubMed:
Mechanism of Safening Action of Dymuron and Its Two Monomethyl Analogues against Bensulfuron-methyl Injury to Rice (Oryza sativa)
PubMed:
Environmental fate of rice pesticides in California.
PubMed:
Bensulfuron methyl dissipation in California rice fields, and residue levels in agricultural drains and the Sacramento River.