isoamyl salicylate

isopentyl salicylate

CAS: 87-20-7 C12 H16 O3 MW: 208.25712000 floral green

Identification

Nameisoamyl salicylate
IUPAC3-methylbutyl 2-hydroxybenzoate
CAS Number87-20-7
EINECS201-730-4
FDA UNIIM25E4ZMR0N
Molecular FormulaC12 H16 O3
Molecular Weight208.25712000
MDL NumberMFCD00020037
Nikkaji NumberJ4.275G
Beilstein2580465
CoE Number435
XlogP34.60 (est)

Regulatory

JECFA Food Flavoring903 isoamyl salicylate
DG SANTE Food Flavourings09.751 isopentyl salicylate
FEMA Number2084
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)87-20-7 ; ISOAMYL SALICYLATE
FDA RegulationFDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION

Physical Properties

Appearance colorless clear oily liquid (est)
Assay 98.00 to 100.00 sum of isomers
Additional Assay Information sum of isoamyl and amyl salicylate
Food Chemicals Codex Listed Yes
Specific Gravity 1.04900 to 1.05500 @ 25.00 °C., 1.05000 to 1.05600 @ 20.00 °C.
Pounds per Gallon - (est). 8.729 to 8.779
Pounds per Gallon - est. 8.747 to 8.797
Refractive Index 1.50700 to 1.50900 @ 20.00 °C.
Boiling Point 277.00 to 278.00 °C. @ 760.00 mm Hg
Acid Value 1.00 max. KOH/g
Vapor Pressure 0.003000 mmHg @ 25.00 °C. (est)
Flash Point > 212.00 °F. TCC ( > 100.00 °C. )
logP (o/w) 4.370
Shelf Life 24.00 month(s) or longer if stored properly.
Storage store in cool, dry place in tightly sealed containers, protected from heat and light.
Soluble in alcohol
Insoluble in water
Stability antiperspirant
Similar Items note

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength medium
Substantivity 124 hour(s) at 100.00 %
Odor Description at 100.00 %.
Odor sample from Harrmann & Reimer Corporation
Taste Description at 20.00 ppm in water.

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Human Experience10 % solution: no irritation or sensitization.
Oral/Parenteral Toxicityoral-rat LD50 4100 mg/kg
Dermal ToxicityNot determined
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
maximum skin levels for fine fragrances2.1900 % and are based on the assumption that the fragrance mixture is used at 20% in a consumer product (IFRA Use Level Survey). (IFRA, 2002)
Recommendation for isoamyl salicylate usage levels up to14.0000 % in the fragrance concentrate.
use level in formulae for use in cosmetics4.0900 %
Dermal Systemic Exposure in Cosmetic Products0.1042 mg/kg/day (IFRA, 2002)
Maximised Survey-derived Daily Intakes (MSDI-EU)41.00 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)7.00 (μg/capita/day)
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

a suma FR aldehydic FR almond FR alpine bouquet FR amber FR angel essence FR apple blossom FR apricot FR balsam FR banana FR berry FR blue grass FR blue mist FR bluebell FR bouquet brut FR camellia canoe FR carnation FR cedar FR cherry FR cherry blossom FR christmas FR chrysanthemum FR chypre FR citrus clean FR clover FR coconut tropical coconut FR cologne FR country meadow FR currant FR cyclamen FR date FR fern fleurs de rocailles FR floral FR fresh and clean FR fresh outdoors FR fruit FR genet FR gooseberry FL grenadine FR hay new mown hay FR herbal FR honey FR hyacinth je reviens FR leather FR lemon FR lilac FR lotus lux beauty shower soap FR maja FR mimosa FR mint FR moss FR musk FR orange FR orchid FR oriental FR peach FR pine FR plum pompeia FR poppy red poppy FR potpourri FR powder FR raspberry FR root beer FR rose FR rose tea rose FR sea breeze FR spearmint FR spice FR strawberry tide FR tuberose FR vanilla FR wallflower FR woody FR ylang ylang FR zibeline

Natural Occurrence

grape rum PMC tea black tea tobacco burley tobacco

Synonyms

iso amyl o-hydroxybenzoate iso amyl ortho-hydroxybenzoate iso- amyl salicylate nat.iso amyl salicylate oxo- amyl salicylate iso amyl salicylate 1-peak iso amyl salicylate extra iso amyl salicylate natural iso amyl salicylate, natural benzoic acid, 2-hydroxy-, 3-methylbutyl ester 2- hydroxybenzoic acid 3-methyl butyl ester 2- hydroxybenzoic acid 3-methylbutyl ester 2- hydroxybenzoic acid, 3-methylbutyl ester 3- methyl butyl 2-hydroxybenzoate 3- methyl butyl o-hydroxybenzoate 3- methyl butyl ortho-hydroxybenzoate 3- methyl butyl salicylate 3- methylbutyl 2-hydroxybenzoate 3- methylbutyl o-hydroxybenzoate 3- methylbutyl salicylate iso pentyl 2-hydroxybenzoate iso pentyl o-hydroxybenzoate iso pentyl ortho-hydroxybenzoate iso pentyl salicylate iso pentyl-2-hydroxyphenyl methanoate iso pentyl-2-hydroxyphenylmethanoate rhodiaflor SiA salicylic acid isopentyl ester salicylic acid, isopentyl ester PubMed: A smelling trip into the past: the influence of synthetic materials on the history of perfumery. PubMed: Preparation of mesoporous titania solid superacid and its catalytic property. PubMed: Fragrance material review on isoamyl salicylate. PubMed: [Hygienic standardization of methyl salicylate and isoamyl salicylate in the atmospheric air of populated areas]. PubMed: [Study of toxicokinetics and cumulative properties of salicylic acid derivatives]. PubMed: Automatic antifungal activity analyzing system on the basis of dynamic growth process of a single hypha. PubMed: Evaluation of antifungal volatile compounds on the basis of the elongation rate of a single hypha. PubMed: Short-term toxicity of isoamyl salicylate in rats.