thifensulfuron-methyl
2-thiophenecarboxylic acid, 3-(((((4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino)carbonyl)amino)sulfonyl)-, methyl ester
Identification
| Name | thifensulfuron-methyl |
| CAS Number | 79277-27-3 |
| FDA UNII | 5VFH25ES6F |
| Molecular Formula | C12 H13 N5 O6 S2 |
| Molecular Weight | 387.39581000 |
| MDL Number | MFCD00468118 |
| Nikkaji Number | J372.958C |
| Beilstein | 7448062 |
Regulatory
Physical Properties
| Assay | 95.00 to 100.00 |
| Food Chemicals Codex Listed | No |
| Melting Point | 176.00 °C. @ 760.00 mm Hg |
| Vapor Pressure | 1.280000 mmHg @ 25.00 °C. (est) |
| logP (o/w) | 1.560 |
| Soluble in | water, 230 mg/L @ 25 °C (exp) |
No sensory data available
Safety Information
| Preferred SDS | View |
| Oral/Parenteral Toxicity | oral-duck LD50 > 2510 mg/kg |
| Dermal Toxicity | skin-rabbit LD50 > 2000 mg/kg |
| Inhalation Toxicity | inhalation-rat LC50 > 7900 mg/m3/4H |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | herbicides / pesticides |
| Recommendation for thifensulfuron-methyl usage levels up to | not for fragrance use. |
| Recommendation for thifensulfuron-methyl flavor usage levels up to | not for flavor use. |
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Potential Uses
Natural Occurrence
Synonyms
EPA pesticide chemical code 128845
harmony 75DF
harmony GT
harmony GT-XP
methyl 3-(4-methoxy-6-methyl-1,3,5-triazin-2-ylcarbamoylsulfamoyl)-2-thenoate
methyl 3-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]thiophene-2-carboxylate
pinnacle 25DF
refine DF
thifensulfuron methyl
thifensulfuron methyl ester
thifensulfuron-methyl [ISO:BSI]
2-
thiophenecarboxylic acid, 3-(((((4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino)carbonyl)amino)sulfonyl)-, methyl ester
PubMed:
Application of liquid chromatography/electrospray ionization tandem mass spectrometry for the elucidation of hydroxyl radical oxidation of metsulfuron methyl and related sulfonylurea pesticide products: evidence for the triazine skeleton scission.
PubMed:
Biodegradation of thifensulfuron-methyl by Ochrobactrum sp. in liquid medium and soil.
PubMed:
Use of ammonium formate in QuEChERS for high-throughput analysis of pesticides in food by fast, low-pressure gas chromatography and liquid chromatography tandem mass spectrometry.
PubMed:
Rapid and sensitive on-line solid phase extraction-ultra high performance liquid chromatography-electrospray-tandem mass spectrometry analysis of pesticides in surface waters.
PubMed:
Use of gold nanoparticle-coated sorbent materials for the selective preconcentration of sulfonylurea herbicides in water samples and determination by capillary liquid chromatography.
PubMed:
Accumulation and half-lives of 13 pesticides in muscle tissue of freshwater fishes through food exposure.
PubMed:
Growth inhibition and recovery of Lemna gibba after pulse exposure to sulfonylurea herbicides.
PubMed:
Pesticide pressure and fish farming in barrage pond in Northeastern France. Part II: residues of 13 pesticides in water, sediments, edible fish and their relationships.
PubMed:
Ionic liquids supported on magnetic nanoparticles as a sorbent preconcentration material for sulfonylurea herbicides prior to their determination by capillary liquid chromatography.
PubMed:
Toxic effects of four sulphonylureas herbicides on soil microbial biomass.
PubMed:
SulE, a sulfonylurea herbicide de-esterification esterase from Hansschlegelia zhihuaiae S113.
PubMed:
Rapid determination of sixteen sulfonylurea herbicides in surface water by solid phase extraction cleanup and ultra-high-pressure liquid chromatography coupled with tandem mass spectrometry.
PubMed:
Multiresidue method for the determination of 13 pesticides in three environmental matrices: water, sediments and fish muscle.
PubMed:
Multiresidue method to quantify pesticides in fish muscle by QuEChERS-based extraction and LC-MS/MS.
PubMed:
Study of biochemical pathway and enzyme involved in metsulfuron-methyl degradation by Ancylobacter sp. XJ-412-1 isolated from soil.
PubMed:
Development and validation of a solid-phase extraction method coupled to high-performance liquid chromatography with ultraviolet-diode array detection for the determination of sulfonylurea herbicide residues in bovine milk samples.
PubMed:
Chemiluminescence sensor for sulfonylurea herbicide using molecular imprinted microspheres as recognition element.
PubMed:
Class-specific molecularly imprinted polymers for the selective extraction and determination of sulfonylurea herbicides in maize samples by high-performance liquid chromatography-tandem mass spectrometry.
PubMed:
Trace level determination of selected sulfonylurea herbicides in wetland sediment by liquid chromatography electrospray tandem mass spectrometry.
PubMed:
N-methylimidazolium ionic liquid-functionalized silica as a sorbent for selective solid-phase extraction of 12 sulfonylurea herbicides in environmental water and soil samples.
PubMed:
Leaching of three sulfonylurea herbicides during sprinkler irrigation.
PubMed:
Mass spectrometry of the photolysis of sulfonylurea herbicides in Prairie waters.
PubMed:
The study of the interactions between heavy metals with sulfonylurea herbicides using ACE.
PubMed:
Impact of basic soil parameters on pesticide disappearance investigated by multivariate partial least square regression and statistics.
PubMed:
HPLC-UV and HPLC-MSn multiresidue determination of amidosulfuron, azimsulfuron, nicosulfuron, rimsulfuron, thifensulfuron methyl, tribenuron methyl and azoxystrobin in surface waters.
PubMed:
Possibilities of chemical weed control in Lupinus albus and Lupinus luteus-screening of herbicides.
PubMed:
Chemical cotton stalk destruction for maintenance of host-free periods for the control of overwintering boll weevil in tropical and subtropical climates.
PubMed:
Persistence of the sulfonylurea herbicides thifensulfuron-methyl, ethametsulfuron-methyl, and metsulfuron-methyl in farm dugouts (ponds).
PubMed:
[Simultaneous determination of ten sulfonylurea herbicide residues in soybeans by high performance liquid chromatography].
PubMed:
Physiological and biochemical characterization of quinclorac resistance in a false cleavers (Galium spurium L.) biotype.
PubMed:
Effects of insecticides and defoliants applied alone and in combination for control of overwintering boll weevil (Anthonomus grandis; Coleoptera: Curculionidae)--laboratory and field studies.
PubMed:
Toxicovigilance: new biochemical tool used in sulfonylurea herbicides toxicology studies.
PubMed:
Selective trace analysis of sulfonylurea herbicides in water and soil samples based on solid-phase extraction using a molecularly imprinted polymer.
PubMed:
Mineralisation studies of 14C-labelled metsulfuron-methyl, tribenuron-methyl, chlorsulfuron and thifensulfuron-methyl in one Danish soil and groundwater sediment profile.
PubMed:
Screening Method for Nine Sulfonylurea Herbicides in Soil and Water by Liquid Chromatography with Ultraviolet Detection.
PubMed:
Coupling of size-exclusion chromatography to liquid chromatography/mass spectrometry for determination of trace levels of thifensulfuron-methyl and tribenuron-methyl in cottonseed and cotton gin trash.
PubMed:
Determination of sulfonylurea degradation products in soil by liquid chromatography-ultraviolet detection followed by confirmatory liquid chromatography-tandem mass spectrometry.
PubMed:
A kinetic study of the methanolysis of the sulfonylureas bensulfuron methyl and sulfometuron methyl using capillary electrophoresis.
PubMed:
Multiresidue determination of sulfonylurea herbicides by capillary electrophoresis for hydrolysis studies in water and sediments.
PubMed:
Acceptance Criteria for Ultratrace HPLC-Tandem Mass Spectrometry:â Quantitative and Qualitative Determination of Sulfonylurea Herbicides in Soil.
PubMed:
Capillary electrophoretic behavior of seven sulfonylureas.
PubMed:
Determination of sulfonylurea herbicides in grains by capillary electrophoresis.