Identification

Nameacetyl isovaleryl
IUPAC5-methylhexane-2,3-dione
CAS Number13706-86-0
EINECS237-241-8
FDA UNIIZI95KZ32L4
Molecular FormulaC7 H12 O2
Molecular Weight128.17104000
MDL NumberMFCD00059352
Nikkaji NumberJ64.762D
Beilstein1745751
CoE Number11148

Regulatory

JECFA Food Flavoring414 5-methyl-2,3-hexanedione
DG SANTE Food Flavourings07.093 5-methylhexan-2,3-dione
FEMA Number3190
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)13706-86-0 ; 5-METHYL-2,3-HEXANEDIONE

Physical Properties

Appearance yellow clear liquid (est)
Assay 96.00 to 100.00
Food Chemicals Codex Listed No
Specific Gravity 0.90600 to 0.91600 @ 25.00 °C.
Pounds per Gallon - (est). 7.539 to 7.622
Refractive Index 1.40600 to 1.41600 @ 20.00 °C.
Boiling Point 138.00 °C. @ 760.00 mm Hg
Vapor Pressure 6.866000 mmHg @ 25.00 °C. (est)
Flash Point 107.00 °F. TCC ( 41.67 °C. )
logP (o/w) 0.060
Soluble in alcohol
Insoluble in water
Similar Items note

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesnot used anymore

Organoleptic Properties

Odor Description
at 1.00 % in propylene glycol.
Sweet, sharp, fruity, creamy with a brown buttery nuance
Taste Description at 50.00 ppm.

Safety Information

Preferred SDSView
Human Experience0.1 % solution: no irritation or sensitization.
Oral/Parenteral Toxicityoral-rat LD50 > 5000 mg/kg
Dermal Toxicityskin-rabbit LD50 > 5000 mg/kg
Inhalation ToxicityNot determined

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']

Safety in Use

Categoryflavoring agents
IFRA Critical EffectDermal sensitization
Recommendation for acetyl isovaleryl usage levels up toPROHIBITED: Should not be used as a fragrance ingredient.
Maximised Survey-derived Daily Intakes (MSDI-EU)1.10 (μg/capita/day)
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FL banana FL cheese FL coffee FL cream FL pineapple FL rum

Natural Occurrence

coffee PMC potato chip PMC

Synonyms

acetyl isopentanoyl acetyl isovalerianyl acetyl isovaleryl acetylisovalerianyl iso butyl methyl diketone iso butyl methyl glyoxal hexane-2,3-dione, 5-methyl- 2,3- hexanedione, 5-methyl- 2- methyl hexa-4,5-dione 5- methyl hexan-2,3-dione 5- methyl hexane-2,3-dione 5- methyl-2,3-hexane dione 5- methyl-2,3-hexanedione 2- methyl-4,5-hexanedione 2- methylhexa-4,5-dione 5- methylhexan-2,3-dione 5- methylhexane-2,3-dione US Patents: 3,952,024 - Furfurylthioacetone US Patents: Certain 2,5-dimethyl-3-thiopyrazines