methyl anthranilate
benzoic acid, 2-amino-, methyl ester
Identification
| Name | methyl anthranilate |
| IUPAC | methyl 2-aminobenzoate |
| CAS Number | 134-20-3 |
| EINECS | 205-132-4 |
| FDA UNII | 981I0C1E5W |
| Molecular Formula | C8 H9 N O2 |
| Molecular Weight | 151.16513000 |
| MDL Number | MFCD00007710 |
| Nikkaji Number | J2.018D |
| Beilstein | 0606965 |
| CoE Number | 250 |
| XlogP3 | 1.90 (est) |
Regulatory
| JECFA Food Flavoring | 1534 methyl anthranilate |
| DG SANTE Food Flavourings | 09.715 methyl anthranilate |
| FEMA Number | 2682 |
| FDA | No longer provide for the use of these seven synthetic flavoring substances |
| FDA Mainterm (SATF) | 134-20-3 ; METHYL ANTHRANILATE |
| FDA Regulation | FDA PART 182 -- SUBSTANCES GENERALLY RECOGNIZED AS SAFE |
Physical Properties
| Appearance | pale yellow to dark yellow clear liquid to solid (est) |
| Assay | 99.00 to 100.00 |
| Food Chemicals Codex Listed | Yes |
| Specific Gravity | 1.16100 to 1.16900 @ 25.00 °C. |
| Pounds per Gallon - (est). | 9.661 to 9.727 |
| Refractive Index | 1.57900 to 1.59200 @ 20.00 °C. |
| Melting Point | 23.00 to 24.50 °C. @ 760.00 mm Hg |
| Boiling Point | 238.00 to 241.00 °C. @ 760.00 mm Hg, 163.00 to 164.00 °C. @ 50.00 mm Hg |
| Congealing Point | 23.80 °C. |
| Saponification Value | 98.00 to 102.00 |
| Vapor Pressure | 0.016000 mmHg @ 25.00 °C. (est) |
| Vapor Density | 5.2 ( Air = 1 ) |
| Flash Point | 220.00 °F. TCC ( 104.44 °C. ) |
| logP (o/w) | 1.880 |
| Shelf Life | 12.00 month(s) or longer if stored properly. |
| Storage | store in cool, dry place in tightly sealed containers, protected from heat and light. |
| Soluble in | alcohol |
| Insoluble in | paraffin oil |
| Stability | alcoholic lotion |
Cosmetic Information
| CosIng | cosmetic data |
| Cosmetic Uses | fragrance |
Organoleptic Properties
| Odor Strength | medium |
| Substantivity | 88 hour(s) at 100.00 % |
| Odor Description |
at 100.00 %. Fruity, concord grape, musty with a floral powdery nuance Characteristic concord grape, orange blossom aroma Floral, Neroli, Warm, Sweet floreal, flowers of orange, fruity grape orangeflower neroli orangeflower sweet fruity tangerine grape-note Musty-fruity Dry, floral-neroli, grapes, Orangeblossom. Tenacious
|
| Odor sample from | Berje Inc. |
| Taste Description |
at 25.00 ppm. sweet fruity sweet fruity concord grape musty berry fruity, sweet
|
Safety Information
| Preferred SDS | View |
| European information | Most important hazard(s): |
| Human Experience | 10 % solution: no irritation or sensitization. |
| Oral/Parenteral Toxicity | oral-rat LD50 2910 mg/kg |
| Dermal Toxicity | skin-rabbit LD50 > 5000 mg/kg |
| Inhalation Toxicity | Not determined |
GHS Classification
['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements']
Safety in Use
| Category | flavor and fragrance agents |
| RIFM Fragrance Material Safety Assessment | Search |
| Recommendation for methyl anthranilate usage levels up to | 10.0000 % in the fragrance concentrate. |
| Maximised Survey-derived Daily Intakes (MSDI-EU) | 686.00 (μg/capita/day) |
| Maximised Survey-derived Daily Intakes (MSDI-USA) | 3764.00 (μg/capita/day) |
| Threshold of Concern | 1800 (μg/person/day) |
| baked goods | 38.00000 |
| beverages(nonalcoholic) | 40.00000 |
| beverages(alcoholic) | 0.20000 |
| breakfast cereal | - |
| cheese | - |
| chewing gum | 200.00000 |
| condiments / relishes | - |
| confectionery froastings | - |
| egg products | - |
| fats / oils | - |
| fish products | - |
| frozen dairy | 40.00000 |
| fruit ices | 40.00000 |
| gelatins / puddings | 20.00000 |
| granulated sugar | - |
| gravies | - |
| hard candy | 80.00000 |
| imitation dairy | - |
| instant coffee / tea | - |
| jams / jellies | 6.00000 |
| meat products | - |
| milk products | - |
| nut products | - |
| other grains | - |
| poultry | - |
| processed fruits | - |
| processed vegetables | - |
| reconstituted vegetables | - |
| seasonings / flavors | - |
| snack foods | - |
| soft candy | 80.00000 |
| soups | - |
| sugar substitutes | - |
| sweet sauces | - |
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