para-acetanisole

acetanisole

CAS: 100-06-1 C9 H10 O2 MW: 150.17710000 anisic anisic

Identification

Namepara-acetanisole
IUPAC1-(4-methoxyphenyl)ethanone
CAS Number100-06-1
EINECS202-815-9
FDA UNII0IRH2BR587
Molecular FormulaC9 H10 O2
Molecular Weight150.17710000
MDL NumberMFCD00008745
Nikkaji NumberJ5.163B
Beilstein0742313
CoE Number570
XlogP31.70 (est)

Regulatory

JECFA Food Flavoring810 acetanisole
DG SANTE Food Flavourings07.038 4-methoxyacetophenone
FEMA Number2005
FDANo longer provide for the use of these seven synthetic flavoring substances
FDA Mainterm (SATF)100-06-1 ; ACETANISOLE
FDA RegulationFDA PART 172 -- FOOD ADDITIVES PERMITTED FOR DIRECT ADDITION TO FOOD FOR HUMAN CONSUMPTION

Physical Properties

Appearance white to pale yellow crystals (est)
Assay 97.00 to 100.00 sum of isomers
Additional Assay Information sum of o,m,p isomers
Heavey Metals <40.00 ppm; <10.00 ppm Pb
Halogens passes test for chlorinated compounds
Food Chemicals Codex Listed Yes
Melting Point 37.00 to 40.00 °C. @ 760.00 mm Hg
Boiling Point 152.00 to 154.00 °C. @ 26.00 mm Hg, 256.00 °C. @ 760.00 mm Hg
Congealing Point 33.50 °C.
Vapor Pressure 0.006000 mmHg @ 25.00 °C.
Flash Point > 230.00 °F. TCC ( > 110.00 °C. )
logP (o/w) 1.740
Soluble in alcohol
Insoluble in glycerin
Stability non-discoloring in most media
Similar Items note

Cosmetic Information

CosIngcosmetic data
Cosmetic Usesperfuming agents

Organoleptic Properties

Odor Strength medium
Substantivity 251 hour(s) at 10.00 % in dipropylene glycol
Odor Description
at 100.00 %.
Sweet, anisic, vanilla-like, with powdery balsamic and benzaldehyde nuances
intensive sweet, somewhat rough, hay-like with floral note, hawthorn, acacia, mimosa, similar to anisaldehyde
butter; caramel; nutty; fruity; sweet; vanilla
aromatic floral, spicy (bitter almond- and hay-like)
ANISEED, SWEET, VANILLA, POWDERY
Sweet, floral-hawthorn, cyclamen, anisic, powdery, balsamic, acacia
Odor sample from Harrmann & Reimer Corporation
Taste Description
at 10.00 ppm.
hay-, coumarin- and vanilla-like
sweet anisic fruity cherry powdery vanilla
sweet aromatic; anisic, vanilla-like, balsamic and benzaldehyde notes

Safety Information

Preferred SDSView
European informationMost important hazard(s):
Oral/Parenteral Toxicityoral-rat LD50 1720 mg/kg
Dermal Toxicityskin-rabbit LD50 > 5000 mg/kg
Inhalation Toxicityinhalation-human TCLo 1700 ug/m3/39W

GHS Classification

['GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)', 'GHS Label elements, including precautionary statements', 'CARDIAC: PULSE RATE INCREASE WITHOUT FALL IN BP\nVASCULAR: BP ELEVATION NOT CHARACTERIZED IN AUTONOMIC SECTION']

Safety in Use

Categoryflavor and fragrance agents
RIFM Fragrance Material Safety AssessmentSearch
Recommendation for para-acetanisole usage levels up to5.0000 % in the fragrance concentrate.
Maximised Survey-derived Daily Intakes (MSDI-EU)130.00 (μg/capita/day)
Maximised Survey-derived Daily Intakes (MSDI-USA)84.00 (μg/capita/day)
Threshold of Concern1800 (μg/person/day)
Structure ClassI
baked goods-
beverages(nonalcoholic)-
beverages(alcoholic)-
breakfast cereal-
cheese-
chewing gum-
condiments / relishes-
confectionery froastings-
egg products-
fats / oils-
fish products-
frozen dairy-
fruit ices-
gelatins / puddings-
granulated sugar-
gravies-
hard candy-
imitation dairy-
instant coffee / tea-
jams / jellies-
meat products-
milk products-
nut products-
other grains-
poultry-
processed fruits-
processed vegetables-
reconstituted vegetables-
seasonings / flavors-
snack foods-
soft candy-
soups-
sugar substitutes-
sweet sauces-

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Potential Uses

FR acacia FR almond FR balsam FR castoreum FR cherry FR clover FR dahlia FR fern FR hawthorn FR hay new mown hay FR heliotrope FR lilac FR linden flower FR mimosa FR peru balsam FR spice FR tobacco FR tonka bean FR tuberose FR vanilla

Natural Occurrence

acacallis superba ancistrochilus rothschildianus brassavola digbyana castoreum PMC catasetum viridiflavum cattleya bicolor caularthron bicornutum celery seed oil egypt @ 0.48% Data cirrhopetalum robustum coryanthes leucocorys dendrobium brymerianum dracula chestertonii encyclia fragrans gongora armeniaca huntleya heteroclita liparis viridiflora masdevallia striatella meat neofinetia falcata nigritella nigra odontoglossum pendulum oncidium ornithorhynchum passiflora galbana peppermint leaf pescatorea dayana polystachya campyloglossa pyrola grandiflora pyrola rotundifolia ssp. maritima rodriguezia refracta stanhopea oculata tomato trixspermum arachnites vanda denisoniana zygopetalum crinitum

Synonyms

acetanisol acetanisole p- acetanisole acetanisole cryst. acetanisole crystals 4- acetyl anisole p- acetyl anisole para- acetyl anisole 4- acetylanisole p- acetylanisole para- acetylanisole castoreum anisole ethanone, 1-(4-methoxyphenyl)- linarodin para- methoxy acetophenone methoxyacetophenone 4- methoxyacetophenone 4'- methoxyacetophenone p- methoxyacetophenone para- methoxyacetophenone 4- methoxyphenyl methyl ketone p- methoxyphenyl methyl ketone para- methoxyphenyl methyl ketone 1-(4- methoxyphenyl) ethanone 1-(4- methoxyphenyl)-ethanone 1-(4- methoxyphenyl)ethan-1-one 1-(4- methoxyphenyl)ethanon (4- methoxyphenyl)ethanone 1-(4- methoxyphenyl)ethanone 4- methoxyphenylmethyl ketone p- methoxyphenylmethyl ketone para- methoxyphenylmethyl ketone methyl 4-methoxyphenyl ketone methyl p-methoxyphenyl ketone methyl para-methoxyphenyl ketone novatone vananote PubMed: Chemical composition of the essential oil of Stachys menthifolia Vis. PubMed: Volatile compounds of flowers and leaves of Sideritis italica (Miller) Greuter et Burdet (Lamiaceae), a plant used as mountain tea. PubMed: Antimicrobial activity of Mitracarpus scaber extract and isolated constituents. PubMed: Pheromonal activity of single castoreum constituents in beaver,Castor canadensis.